• 제목/요약/키워드: electronic equilibrium

검색결과 186건 처리시간 0.026초

관행열기건조(慣行熱氣乾操)와 고온건조(高溫乾燥) 침엽수재(針葉樹材)의 함수율(含水率) 측정법(測定法)에 의한 평형함수율(平衡含水率) 비교(比較) (Comparison of Equilibrium Moisture Contents for Conventional Kiln Dried- and High Temperature Dried Softwood Lumber by Moisture Content Determination)

  • 정희석;윌리암 비 스미스
    • Journal of the Korean Wood Science and Technology
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    • 제22권4호
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    • pp.37-42
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    • 1994
  • The adsorption of water vapor and equilibrium moisture content(EMC) of the specimens for four softwood species dried by conventional- and high temperature method and equilibrated to 15% of the target EMC condition at 25$^{\circ}C$ were determined by oven drying method and with moisture meters. The amount of adsorption for high temperature dried red pine was significantly higher than that of conventional kiln dried wood, while those of eastern white pine, eastern hemlock and Norway spruce were not significantly different between drying methods. EMCs of these four species determined by oven drying method and with capacitive admittance moisture meter were not significantly different between drying methods. EMC of high temperature dried red pine determined with resistance moisture meter was significantly higher than that of conventional kiln dried wood. But EMCs of other species did not show significant difference between drying methods. EMCs of conventional and high-temperature dried wood determined with electronic moisture meters, especially in the case of the capacitive-admittance moisture meter measurement, were lower than that determined by oven drying method.

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Theoretical Studies of the Low-Lying Electronic States of Diazirine and 3,$3^{\prime} $-Dimenthyldiazirine

  • 한민수;조한국;정병서
    • Bulletin of the Korean Chemical Society
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    • 제20권11호
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    • pp.1281-1287
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    • 1999
  • The low-lying electronic states of diazirine and 3,3'-dimethyldiazirine have been studied by high level ab initio quantum chemical methods. The equilibrium geometries of the ground state and the first excited singlet and triplet states have been optimized using the Hartree-Fock (HF) and complete active space SCF (CASSCF) methods, as well as using the Møller-Plesset second order perturbation (MP2) theory and the single configuration interaction (CIS) theory. It was found that the first excited singlet state is of 1 B1 symmetry resulting from the n- π* transition, while the first excited triplet state is of 3 B2 symmetry resulting from the π- π* transition. The harmonic vibrational frequencies have been calculated at the optimized geometry of each electronic state, and the scaled frequencies have been compared with the experimental frequencies available. The adiabatic and vertical transition energies from the ground electronic state to the low-lying electronic states have been estimated by means of multireference methods based on the CASSCF wavefunctions, i.e., the multiconfigurational quasidegenerate second order perturbation (MCQDPT2) theory and the CASSCF second-order configuration interaction (CASSCF-SOCI) theory. The vertical transition energies have also been calculated by the CIS method for comparison. The computed transition energies, particularly by MCQDPT2, agree well with the experimental observations, and the electronic structures of the molecules have been discussed, particularly in light of the controversy over the existence of the so-called second electronic state.

Competitive Resource Sharing Based on Game Theory in Cooperative Relay Networks

  • Zhang, Guopeng;Cong, Li;Zhao, Liqiang;Yang, Kun;Zhang, Hailin
    • ETRI Journal
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    • 제31권1호
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    • pp.89-91
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    • 2009
  • This letter considers the problem of resource sharing among a relay and multiple user nodes in cooperative transmission networks. We formulate this problem as a sellers' market competition and use a noncooperative game to jointly consider the benefits of the relay and the users. We also develop a distributed algorithm to search the Nash equilibrium, the solution of the game. The convergence of the proposed algorithm is analyzed. Simulation results demonstrate that the proposed game can stimulate cooperative diversity among the selfish user nodes and coordinate resource allocation among the user nodes effectively.

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NANOCAD Framework for Simulation of Quantum Effects in Nanoscale MOSFET Devices

  • Jin, Seong-Hoon;Park, Chan-Hyeong;Chung, In-Young;Park, Young-June;Min, Hong-Shick
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제6권1호
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    • pp.1-9
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    • 2006
  • We introduce our in-house program, NANOCAD, for the modeling and simulation of carrier transport in nanoscale MOSFET devices including quantum-mechanical effects, which implements two kinds of modeling approaches: the top-down approach based on the macroscopic quantum correction model and the bottom-up approach based on the microscopic non-equilibrium Green’s function formalism. We briefly review these two approaches and show their applications to the nanoscale bulk MOSFET device and silicon nanowire transistor, respectively.

Synthesis and Equilibria of Octahedral and Tetrahedral Complexes of Cobalt (II) 2,2'-Dipyridylamine

  • Paik Suh Myunghyun;Oh Young-Hee
    • Bulletin of the Korean Chemical Society
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    • 제3권1호
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    • pp.5-9
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    • 1982
  • Reactions of cobalt(II) chloride with 2,2'-dipyridylamine (dpa) in alcoholic solutions afford the complex of octahedral $Co(dpa)_2Cl_2{\cdot}CH_3OH$. The octahedral complex is converted to tetrahedral $Co(dpa)Cl_2$ in certain solvents or at the elevated temperature, and the tetrahedral complex is changed to the octahedral one with added dpa. The electronic spectra of the complexes in DMF, measured with various concentrations of 2,2'-dipyridylamine, establish the equilibrium; $td-Co(dpa)Cl_2+dpa_\rightleftarrows^Koh-Co(dpa)_2Cl_2$. The equilibrium constants determined by the analysis of the visible spectra are 6.4, 3.6 and 2.0 $M^{-1}$, respectively, at 25.5, 38.0 and $49.0^{\circ}C,\;with\;{\Delta}H^{\circ}\;and\;{\Delta}S^{\circ}$being -9.5 kcal/mole and -28 eu.

Resource Allocation in Spectrum Sharing ad-hoc Cognitive Radio Networks Based on Game Theory: An Overview

  • Abdul-Ghafoor, Omar B.;Ismail, Mahamod;Nordin, Rosdiadee;El-Saleh, Ayman Abd
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제7권12호
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    • pp.2957-2986
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    • 2013
  • The traditional approach of fixed spectrum allocation to licensed networks has resulted in spectrum underutilisation. Cognitive radio technology is envisioned as a promising solution that can be used to resolve the ineffectiveness of the fixed spectrum allocation policy by accessing the underutilised spectrum of existing technologies opportunistically. The implementation of cognitive radio networks (CRNs) faces distinct challenges due to the fact that two systems (i.e., cognitive radio (CR) and primary users (PUs)) with conflicting interests interact with each other. Specially, in self-organised systems such as ad-hoc CRNs (AHCRNs), the coordination of spectrum access introduces challenges to researchers due to rapid utilisation changes in the available spectrum, as well as the multi-hop nature of ad-hoc networks, which creates additional challenges in the analysis of resource allocation (e.g., power control, channel and rate allocation). Instead, game theory has been adopted as a powerful mathematical tool in analysing and modelling the interaction processes of AHCRNs. In this survey, we first review the most fundamental concepts and architectures of CRNs and AHCRNs. We then introduce the concepts of game theory, utility function, Nash equilibrium and pricing techniques. Finally, we survey the recent literature on the game theoretic analysis of AHCRNs, highlighting its applicability to the physical layer PHY, the MAC layer and the network layer.

$Pt/H_2SO_4$ 전해질 계면에서 교류임피던스 측정과 위상이동 방법에 의한 Langmuir 흡착등온식 해석 (Analysis on the Langmuir adsorption isotherm at the $Pt/H_2SO_4$ electrolyte interface using the ac impedance measurement and phase-shift method)

  • 천장호;조성칠;손광철
    • 전기화학회지
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    • 제2권1호
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    • pp.23-26
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    • 1999
  • 백금$(Pt)/0.1M\;H_2SO_4$, 전해질 계면에서 교류임피던스 측정과 위상이동 방법을 사용하여 Langmuir 흡착등온식을 정성적으로 해석하였다. 위상이동$(\phi)$은 음전위(E<0)와 주파수(f)에 따르며, Pt 일전극(음극)에 흡착된 수소원자$(H_{ads})$의 표면피복율$(\theta)$에 반비례한다. 중간주파수대$(1\~100 Hz)$에서 위상이동 변화$(\phi\;vs.\;E)$는 Langmuir 흡착등온식$(\theta\;vs.\;E)$의 계산과 해석에 사용할 수 있는 실험적인 방법이다. $Pt/0.1M\;H_2SO_4$ 전해질 계면에서 흡착평형상수(K)와 표준자유에너지$({\Delta}G_{ads})$는 각각 $3\times10^{_4}$와 20.1kJ/mol이다.

Design of Fuzzy Output Feedback Controller for The Nonlinear Systems with Time -Delay

  • Shin, Hyun-Seok;Kim, Eun-Tai;Park, Mignon
    • 한국지능시스템학회논문지
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    • 제12권6호
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    • pp.559-564
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    • 2002
  • This Paper Proposes a design method of a fuzzy output feedback controller for the nonlinear systems with the unknown time- delay. Recently, Cao et ai. proposed a stabilization method for the nonlinear time-delay systems using a fuzzy controller when the time-delay is known. However, the time-delay is likely to be unknown in practical. We represent the nonlinear systems with the unknown time-delay by Takagi-Sugeno (T-5) fuzzy model and design the fuzzy observer and the parallel distributed compensation (PDC) law based on this observer. By applying Lyapunov-Krasovskii theorem to the closed-loop system, the sufficient condition for the asymptotic stability of the equilibrium Point is derived and converted into the linear matrix inequality (LMI) Problem.

Electronic Structures, Magnetic, and Superconducting Properties of bcc Ni and V-doped Ni (Ni16-xVx)

  • Kim, Bong-Jae;Choi, Hong-Chul;Kim, Kyoo;Min, B.I.
    • Journal of Magnetics
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    • 제13권4호
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    • pp.128-131
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    • 2008
  • We have investigated the electronic structures and magnetic properties of both undoped and doped bcc Ni using the full-potential linearized augmented plane wave (FLAPW) band method. A ferromagnetic ground state is obtained at the equilibrium volume of bcc Ni. When the system is under strain, the nonmagnetic ground state is stabilized. When the Ni is doped with V, the $Ni_{16-x}V_x$ material loses its magnetic properties when x > 2. We have also discussed the possible superconducting properties of $Ni_{16-x}V_x$.

Transport properties of boron/nitrogen/phosphorus binary doped graphene nanoribbons: An ab initio study

  • Kim, Seong Sik;Kim, Han Seul
    • EDISON SW 활용 경진대회 논문집
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    • 제2회(2013년)
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    • pp.273-277
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    • 2013
  • We apply a density functional theory (DFT) and DFT-based non-equilibrium Green's function approach to study the electronic and transport properties of graphene nanoribbons (GNRs) co-doped with boron-nitrogen, nitrogen-phosphorus and boron-phosphorus. We analyze the structures and charge transport properties of co-doped GNRs and particularly focus on the novel effects that are absent for the single N-, B-, or P-doped GNRs. It is found that co-doped GNRs tend to be doped at the edges and the electronic structures of co-doped GNRs are very sensitive to the doping sites. Also, in case of B-N and B-P co-doped GNRs, conductance dips of single-doped GNRs disappeared with the disappearance of localized states associated with doped atoms. This may lead to a possible method of band engineering of GNRs and benefit the design of graphene electronic devices.

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