• Title/Summary/Keyword: electron heat capacity

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Measurement and Prediction of Damage Threshold of Gold Films During Femtosecond Laser Ablation

  • Balasubramani, T.;Kim, S.H.;Jeong, S.H.
    • Laser Solutions
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    • v.11 no.4
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    • pp.13-20
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    • 2008
  • The damage threshold measurement of gold films is carried out with ultrashort-pulse laser. An enhanced two temperature model is developed to encounter the limitation of linear modeling during ultrashort pulse laser ablation. In which the electron heat capacity is calculated using a quantum mechanical approach based on a Fermi-Dirac distribution, temperature-dependent electron thermal conductivity valid beyond the Fermi temperature is adopted, and reflectivity and absorption coefficient are estimated by applying a temperature-dependent electron relaxation time. The predicted damage threshold using the proposed enhanced modelclosely agreed with experimental results, demonstrating the importance of considering transient thermal and optical properties in the modeling of ultrashort pulse laser ablation.

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Effect of Coagulation Heat Capacity on the PVDF Membrane via TIPS Method (열유도상분리법을 이용한 응고조의 열용량에 따른 PVDF 분리막의 구조 분석)

  • Lee, Jeong Woo;Nam, Sang Yong
    • Membrane Journal
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    • v.27 no.4
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    • pp.350-357
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    • 2017
  • In this study, we used TIPS (thermally induced phase separation) for the application of water treatment membrane, and observed the change in morphology of separation membrane due to the change of solidification temperature and heat capacity. For manufactured membrane, PVDF and silica with excellent mechanical properties and chemical resistance were used, and DOP (dioctyl phthalate), DBP (dibutyl phthalate) were used as the diluent. Using the SEM (scanning electron microscope), the morphology of each different coagulation solutions of heat capacity change was observed. As the heat capacity increased, the crystallization rate of PVDF was decreased and showed large pore. In contrast, It also confirmed that the smaller heat capacity, the faster the crystallization rate and make smaller pores.

Damping Capacity of Mg-Al Casting Alloy Refined by Aluminum Carbide Particles (알루미늄 카바이드 입자로 미세화된 Mg-Al 주조합금의 진동감쇠능)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.6
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    • pp.293-298
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    • 2007
  • Influences of aluminum carbide ($Al_4C_3$) addition on microstructure and damping capacity of Mg-3%Al casting alloy have been investigated based on experimental results of optical micrography, scanning electron microscopy with energy-dispersive spectrometry analysis and damping capacity measurement at RT. The addition of $Al_4C_3$ particles results in an efficient grain refinement. The damping capacity shows an increasing tendency with an increase in $Al_4C_3$ content. The damping value associated with $Al_4C_3$ particles is linearly dependent on the volume fraction of $Al_4C_3$ particles to the 2/3 power, $f_{2/3}$, which corresponds to the total surface area of the particles.

The World's Thinnest Graphene Light Source (세상에서 가장 얇은 그래핀 발광 소자)

  • Kim, Young Duck
    • Vacuum Magazine
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    • v.4 no.3
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    • pp.16-20
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    • 2017
  • Graphene has emerged as a promising material for optoelectronic applications including as ultrafast and broadband photodetector, optical modulator, and nonlinear photonic devices. Graphene based devices have shown the feasibility of ultrafast signal processing for required for photonic integrated circuits. However, on-chip monolithic nanoscale light source has remained challenges. Graphene's high current density, thermal stability, low heat capacity and non-equilibrium of electron and lattice temperature properties suggest that graphene as promising thermal light source. Early efforts showed infrared thermal radiation from substrate supported graphene device, with temperature limited due to significant cooling to substrate. The recent demonstration of bright visible light emission from suspended graphene achieve temperature up to ~3000 K and increase efficiency by reducing the heat dissipation and electron scattering. The world's thinnest graphene light source provides a promising path for on-chip light source for optical communication and next-generation display module.

A Study on Thermal Behaviors of Expanded Graphite/Erythritol Composites (팽창흑연/에리스리톨 복합체의 열적거동에 관한 연구)

  • Choi, Bo-Kyung;Choi, Woong-Ki;Kuk, Yun-Su;Kim, Hong-Gun;Seo, Min-Kang
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.463-467
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    • 2014
  • In this paper, the thermal behaviors of expanded graphite(EG)/erythritol composites with different contents of EG were studied. The surface and structure properties of the composites were determined by using scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD), respectively. The thermal properties were investigated by differential scanning calorimetry (DSC) and thermal conductivity (TC). As experimental results, the thermal conductivity of the composites increased with increasing the EG content. However, the latent heat was somewhat decreased in the presence of EG. We could concluded that EG was highly promising materials for improving the heat transfer enhancement and energy storage capacity of phase change materials (PCMs).

Synthesis and Electrochemical Properties of FexNbS2/C Composites as an Anode Material for Li Secondary Batteries

  • Kim, Yunjung;Kim, Jae-Hun
    • Corrosion Science and Technology
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    • v.21 no.4
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    • pp.250-257
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    • 2022
  • Transition metal sulfide materials have emerged as a new anode material for Li secondary batteries owing to their high capacity and rate capability facilitated by fast Li-ion transport through the layered structure. Among these materials, niobium disulfide (NbS2) has attracted much attention with its high electrical conductivity and high theoretical capacity (683 mAh g-1). In this study, we propose a facile synthesis of FexNbS2/C composite via simple ball milling and heat treatment. The starting materials of FeS and Nb were reacted in the first milling step and transformed into an Fe-Nb-S composite. In the second milling step, activated carbon was incorporated and the sulfide was crystallized into FexNbS2 by heat treatment. The prepared materials were characterized by X-ray diffraction, electron spectroscopies, and X-ray photoelectron spectroscopy. The electrochemical test results reveal that the synthesized FexNbS2/C composite electrode demonstrates a high reversible capacity of more than 600 mAh g-1, stable cycling stability, and excellent rate performance for Li-ion battery anodes.

Chilling Tolerance of Photosynthesis in Plants is Dependent on the Capacity to Enhance the Levels of the Xanthophyll Cycle Pigments in Response to Cold Stress

  • Kim, Hyun-Ju;Kang, In-Soon;Lee, Chin-Bum;Lee, Choon-Hwan;Cho, Sung-Ho;Moon, Byoung-Yong
    • Journal of Photoscience
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    • v.12 no.1
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    • pp.33-39
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    • 2005
  • Plants possess the ability to dissipate the excitation energy for the protection of photosynthetic apparatus from absorbed excess light. Heat dissipation is regulated by xanthophyll cycle in thylakoid membranes of chloroplasts. We investigated the mechanistic aspects of xanthophyll cycle-dependent photoprotection against low-temperature photoinhibition in plants. Using barley and rice as chilling-resistant species and sensitive ones, respectively, chilling-induced chlorophyll fluorescence quenching, composition of xanthophyll cycle pigments and mRNA expression of the zeaxanthin epoxidase were examined. Chilled barley plants exhibited little changes in chlorophyll fluorescence quenching either of photochemical or non-photochemical nature and in the photosynthetic electron transport, indicating low reduction state of PS II primary electron acceptor. In contrast to the barley, chilled rice showed a marked decline in those parameters mentioned above, indicating the increased reduction state of PS II primary electron acceptor. In addition, barley plants were shown to have a higher capacity to elevate the pool size of xanthophyll cycle pigments in response to cold stress compared to rice plants. Such species-dependent regulation of xanthophyll cycle activity was correlated with the gene expression level of cold-induced zeaxanthin epoxidase. Chilled rice plants depressed the gene expression of zeaxanthin epoxidase, whereas barley increased its expression in response to cold stress. We suggest that chilling-induced alterations in the pool size of xanthophyll cycle pigments related to its capacity would play an important role in regulating plant's sensitivity to chilling stress.

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Characterization of EVA/PCM/Silica Compound using Silica

  • Kim, Tae-Hyun;Choi, Kyung-Man;Lee, Jong-Hwan;Choi, Myeon-Cheon;Kim, Han-Seong
    • Elastomers and Composites
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    • v.56 no.2
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    • pp.72-78
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    • 2021
  • A phase-change material (PCM) is a material that has the ability to delay heat transfer by absorbing heat from its environment or releasing heat to its environment while its phase changes from solid to liquid or liquid to solid at a specific temperature. As it is applied, it can contribute to environmental conservation such as energy savings and carbon dioxide emission reduction. In order for a PCM to store and release heat, the volume change during its phase transition should be large, and thus a phase transition space is required. When a PCM is used as a polymer additive, it is confined within the polymer, and there is no phase transition space; thus, its ability to absorb and release heat is significantly reduced. Therefore, in this study, porous silica was used to provide EVA/PCM compounds with sufficient space for their phase transition, and to improve the compatibility between the EVA and PCM, modified silica is used: surface-modified 5 wt% silica with 3-methacryloxypropyltrimethoxysilane. The compound was prepared and compared with the silica compound. The presence or absence of the modified silica surface modification was confirmed using Fourier-transform infrared spectroscopy and thermogravimetric analysis, the heat capacity of the compound was evaluated based on a differential scanning calorimetry analysis, and its mechanical strength and morphology were determined using scanning electron microscopy.

Heat treatment characteristics of medium carbon steel by CW Nd:YAG Laser (CW Nd:YAG 레이저를 이용한 중탄소강의 열처리특성)

  • Shin H.J.;Yoo Y.T.;Ahn D.G.;Im K.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.438-443
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    • 2005
  • Laser surface hardening is an effective technique used to improve the tribological properties and also to increase the service life of automobile components such as camshafts, crankshatfs, lorry brake drums and gears. High power CO2 lasers and Nd:YAG lasers are employed for localized hardening of materials and hence are of potential application in the automobile industries. The heat is conducted rapidly into the bulk of the specimen causing self-quenching to occur and the formation of martensitic structure. In this investigation, the microstructure features occurring in Nd:YAG laser hardening SM45C steel are discussed with the use of optical microscopic and scanning electron microscopic analysis. Moreover, This paper describes the optimism of the processing parameters for maximum hardened depth of SM45C steel specimens of 3mm thickness by using CW Nd:YAG laser. Travel speed was varied from 0.6m/min to 1.0m/min. The maximum hardness and case depth fo SM45C steel are 780Hv and 0.4mm by laser hardening.

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Dynamic heat capacity of perovskite manganites: calorimetric evidence for a first order transition and its implication to the magnetocaloric effect

  • Kim, Y. B.;Y. H. Jeong
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.40-40
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    • 2003
  • Finding a solid material with a large value of the magnetocaloric effect near room temperature is of exceeding importance, since this would lead to the development of more compact and environmentally safer cooling systems. Recently, manganites become the focus of attention due to its large magnetocaloric effect. We demonstrate, via dynamic calorimetric measurements, that the large magnetocaloric effect in perovskite manganites stems from the first-order nature of the magnetic transition. Our results offer a clue in search for ideal magnetocaloric materials working in the vicinity of room temperature.

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