• 제목/요약/키워드: electrolytic treatment

검색결과 166건 처리시간 0.022초

마이크로 아크 산화 표면처리 기술을 활용한 치과도재 소부용 티타늄 인공치아 결합강도 연구 (A Study on the Bonding Strength of Titanium Artificial Teeth for Baking Dental Ceramics using Micro-arc Oxidation Surface Treatment Technology)

  • 송종법;박종민;김종순;정효경;최원식
    • 한국산업융합학회 논문집
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    • 제25권2_2호
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    • pp.309-314
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    • 2022
  • The bonding strength [ISO22674] test was conducted by firing a dedicated ceramic powder on the surface of the dental titanium material treated with micro-arc oxidation. In the test group, an average result value of 34.34 MPa was obtained, and in the control group, a result value of 21.53 MPa was obtained. The bonding strength of the test group was higher than that of the control group by 12.81 MPa, resulting in a 37% improvement in durability of the dental artificial tooth ceramic restoration.

Changes in Antioxidant Enzyme Activities of Two Contrasting Ecotypes of Arundinella hirta to Drought Stress

  • Chang Woo Min;Yun-Hee Kim;Byung-Hyun Lee
    • 한국초지조사료학회지
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    • 제43권2호
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    • pp.67-74
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    • 2023
  • To understand antioxidant enzyme response of two contrasting Arundinella hirta ecotypes to drought stress, drought-tolerant Youngduk and drought-sensitive Jinju-1, were comparatively analyzed changes in the enzymatic activities of peroxidase (POD), ascorbate peroxidase (APX), catalase (CAT), superoxide dismutase (SOD), and glutathione reductase (GR). Two ecotypes, drought-tolerant Youngduk and drought-sensitive Jinju-1 were subjected to drought stress by withholding water for 12 days. ROS accumulation level and electrolytic leakage were significantly increased in both A. hirta ecotypes by drought stress treatment but less in Youngduk than Jinju-1. The RWC significantly decreased in both the drought stress-treated ecotypes as compared to control, but less in Youngduk than Jinju-1. Soluble sugar and protein content were increased more in drought stress-treated Youngduk as compared to Jinju-1. The activities of antioxidant enzymes such as SOD, CAT, POD, APX, and GR increased significantly in both the drought stress-treated ecotypes Youngduk and Jinju-1 as compared to control. The increase in antioxidant enzyme activity level was more prominent in drought stress-treated Youngduk as compared to Jinju-1. Taken together, these results suggest that Youngduk was more tolerant to drought stress than Jinju-1, and seem to indicate that tolerance of A. hirta to drought stress is associated with increased activity of antioxidant enzymes.

직접 전기분해식 선박평형수 처리장치 개발과 시험에 관한 연구 (Development of the Electrolysis Ballast Water Treatment System and Test)

  • 박옥열;문장;박준모;공길영
    • 한국항해항만학회지
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    • 제41권3호
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    • pp.79-86
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    • 2017
  • 선박의 항해 안전성을 유지하기 위하여 평형수 탱크에 주입 배출되는 선박평형수는 그 안에 포함되어 있는 각종 수중생물로 인하여 지역 해양 환경에 부정적인 영향을 주고 있다. 국제해사기구(IMO)는 선박평형수를 통한 수중생물의 이동을 막기 위해, 2004년 선박평형수와 침전물 통제 및 관리를 위한 국제협약을 채택하고 2016년 9월에 발효하여, 2017년 9월 이후 정기검사가 도래하는 모든 선박은 선박평형수 처리장치를 설치하도록 하였다. 선박평형수 처리 방식에는 활성물질을 이용하여 처리하는 전기분해식, 오존식, 약품식과 물리적인 처리방식인 필터, 자외선식 등으로 나누어 지며, 두 가지 방식을 혼용하여 사용하기도 한다. 일반적으로 비용과 효율 면에서 전기분해방식이 우수한 것으로 알려져 있다. 본 논문에서는 직접식 전기분해 선박평형수 처리장치의 기본 원리, 구성 요소, 육상 시험 내용을 고찰하였다. 육상시험은 정부시험 시설이 설치되어 있는 KIOST 거제분원에서 $300m^3/h$ 처리 용량의 장치로 수행하였다. 이 육상시험을 통해 직접식 전기분해 선박평형수 처리장치가 IMO에서 제시하고 있는 기준을 만족하고 다른 방식에 비해 효율적인 것을 확인하였다.

유기용매 전해조를 이용한 리튬이차박막전지용 Sn 음극의 제조 (Preparation and Characterization of a Sn-Anode Fabricated by Organic-Electroplating for Rechargeable Thin-Film Batteries)

  • 김동훈;도칠훈;이정훈;이덕준;하경화;진봉수;김현수;문성인;황영기
    • 전기화학회지
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    • 제11권4호
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    • pp.284-288
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    • 2008
  • 박막 리튬이차전지의 고용량 음극을 개발하기 위하여, Sn(II) 아세테이트를 포함한 유기전해조 도금법을 이용하여 Sn 박막전극을 제조하였다. $Li^+$$Sn^{2+}$를 포함한 전해조에 대한 순환전위전류시험 결과 3종류의 환원 반응이 나타났으며, $2.0{\sim}2.5\;V$ 영역이 Ni 집전체 표면에 대한 Sn의 석출 반응에 해당한다. 수계전해액에 대한 $Sn^{2+}$의 표준환원전위는 2.91 V vs. $Li^+/Li^{\circ}$ 인데 반해 유기전해조에서는 보다 낮은 전위에서 환원반응이 일어났다. 이는 유기전해질의 고저항과 $Sn^{2+}$의 낮은 농도에 기인한 과전위의 결과로 생각된다. 제조한 전극의 물리적 특성 및 전기화학적 특성을 연구하였다. 석출한 Sn 전극을 $150^{\circ}C$로 열처리하여 보다 높은 결정성을 얻을 수 있었고, 이를 Sn/Li 전지로 구성하여 전기화학적 실험을 한 결과 0.25 V와 0.75 V에서 각각 합금화-탈합금화 과정을 확인 할 수 있었다. 제조한 전극의 두께를 전기량을 통하여 계산한 바 $7.35{\mu}m$였으며, 가역용량은 $400{\mu}Ah/cm^2$을 얻었다.

Cr-free 코팅액에 의한 아연도금강판의 건조시간에 따른 내식특성 (Evaluation of the Corrosion Resistance of Steel Coated with Zinc Using a Cr-free Coating Solution as a Function of Heat Treatment Time)

  • 서현수;문희준;김종순;안석환;문창권;남기우
    • 한국해양공학회지
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    • 제24권5호
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    • pp.67-74
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    • 2010
  • Chromate conversion coating is a coating technique used to passivate aluminum, zinc, cadmium, copper, silver, magnesium, tin, and their alloys to slow corrosion. The process uses various toxic chromium compounds, which may include hexavalent chromium. The industry is developing less toxic alternatives in order to comply with substance restriction legislation, such as RoHS. One alternative is to develop a Cr-free coating solution. In this study, eco-friendly, Cr-free solutions (urethane solution S-700, organic/inorganic solution with Si LRO-317) were used. Test specimens were dried in a drying oven at $190^{\circ}C$ for 3, 5, 7, and 9 minutes. Corrosion resistance was evaluated using a salt spray test for 72 hours. The results show that the optimum corrosion resistance was achieved at $190^{\circ}C$ for five minutes for EGI and three or five minutes for HDGI, respectively. The adhesive properties of the two types of coating solutions were superior regardless of drying time.

Cr-free 코팅액에 의한 아연도금강판의 열처리 온도에 따른 내식특성 (Evaluation of the Corrosion Resistance of Zn-Coated Steel as a Function of the Temperature of the Cr-free Solution Used to Coat the Steel)

  • 서현수;문희준;김종순;안석환;문창권;남기우
    • 한국해양공학회지
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    • 제24권5호
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    • pp.60-66
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    • 2010
  • Zinc has a number of characteristics that make it well suited for use as a coating to protecting iron and steel products from corrosion. Its excellent corrosion resistance in most environments accounts for its successful use as a protective coating on a variety of products and in many exposure conditions. The excellent field performance of zinc coatings results from their ability to form dense, adherent films that corrode at a rate that ranges from 1% to 10% of the corrosion rate of ferrous materials, depending on the environment. Recently, EU RoHS and EU ELV prohibited the use of materials that adversely affect the environment, such as Pb, Hg, Cd, and $Cr^{+6}$. In this study, environmentally-friendly, Cr-free solutions (epoxy solution, acrylic solution, and urethane solution S-700) and organic/inorganic solution with Si; LRO-317) were used to evaluate the corrosion resistance of zinc-coated steel subjected to a saltwater spray for 72 hours. The coating of urethane solution (S-700) was best among the three kinds of solution with heat treatment during five minutes at $190^{\circ}F$. Test specimens with S-700 and LRO-317 coating were heat treated in a drying oven at 170, 180, 190, 200, and $210^{\circ}C$ for five minutes. The results show that the optimum corrosion resistance was $190^{\circ}C$ in EGI and $170^{\circ}C$ in HDGI, respectively.

Effect of Panax ginseng on Latency of Passive Avoidance Response and Neuronal Damage of Hippocampus

  • Cho, So-Hyun;Choi, Sang-Hyun;Choi, Jae-Won;Kim, Dong-Hoon;Shin, Kyung-Ho;Chun, Yeon-Sook;Chun, Boe-Gwun
    • The Korean Journal of Physiology and Pharmacology
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    • 제1권4호
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    • pp.345-353
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    • 1997
  • The effects of crude saponin (SAP) and alkaloid (ALK) fractions of Panax ginseng C.A. Meyer on the detrimental effects of electroconvulsive shock (ECS) and scopolamine on passive avoidance response (PAR) were studied in male Sprague-Dawley rats, referring their effects on the neuronal injury and plasticity of hippocampus in response to electrolytic lesion of left entorhinal cortex (ECL). The detrimental ECS effect on PAR was attenuated by pre- and post-treatments with SAP and ALK, respectively, or by pretreatment with aminoguanidine (AG), an inhibitor of diamine oxidase and NO synthase. And the detrimental scopolamine effect on PAR was also inhibited by pre-treatment with ALK or AG, and by post- treatment with SAP or ALK, respectively. On the 7th day after ECL, the brain sections stained by cresyl violet and by acetylcholinesterase (AChE) histochemistry, respectively, showed the chromatolysis and numeral decrease of neurons and the reduction of AChE reactivity in the hippocampus CA1 area and to a lesser extent, in the dentate gyrus. The neuronal cell death of the CA1 area was significantly reduced by SAP, ALK, or AG, and the reduction of AChE reactivity was significantly attenuated by SAP or ALK and to a lesser extent by AG. These results suggests that the protective effect of ginseng SAP and ALK fractions on ECS- or scopolamine-induced impairment of PAR may be ascribed in part to preservation of hippocampal neurons, particularly cholinergic neurons.

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삼음교(三陰交), 음릉천(陰陵泉), 방광유(膀胱兪) 단독(單獨) 및 배혈(配穴) 애구(艾灸) 시술(施術)이 Uranyl Acetate에 의하여 유발(誘發)된 백서(白鼠)의 급성신부전(急性腎不全)에 미치는 영향(影響) (Effects of Moxibustion on Zusanli(SP6), Yinlingquan(SP9) and Pangguangshu(BL28) at Experimental Acute renal failure in rats.)

  • 윤대환;박종승;김용성;김정상;나창수
    • Korean Journal of Acupuncture
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    • 제20권2호
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    • pp.55-66
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    • 2003
  • Objectives : The aim of this experiment is to investigate the effects of moxibustion on SP6, Sp9 and BL28 in uranyl acetate-induced acute renal failure in rats. Methods : To induce experimental acute renal failure, uranyl acetate was intraperitoneally injected to rats by 5mg/kg. 3 days later moxibustion treatment was done at SP6, Sp9 and BL28 bilaterally of the rats. And then 4 days later, we measured rats' body weight, kidney weight, serum BUN, creatinine and serum electrolytic levels(Na, K and Cl). Results : In the SP6 group, serum BUN were significantly decreased (p<0.01). In the BL28 group, serum Na level were significantly decreased (p<0.05). In the $SP6{\cdot}SP9$ group, serum creatinine level were significantly increased but serum Na level, serum Cl level were significantly decreased(p<0.05). In the $SP6{\cdot}BL28$ group, hypertrophy index of kidney and serum creatinine level were significantly decreased(p<0.01) and serum BUN were marginally significantly decreased (0.1

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ATO 처리후, 플라즈마 전해 산화 처리된 Ti-6Al-4V 합금의 표면 형태 (Surface Morphology of PEO-treated Ti-6Al-4V Alloy after Anodic Titanium Oxide Treatment)

  • Kim, Seung-Pyo;Choe, Han-Cheol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.75-75
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    • 2018
  • Commercially pure titanium (CP-Ti) and Ti-6Al-4V alloys have been widely used in implant materials such as dental and orthopedic implants due to their corrosion resistance, biocompatibility, and good mechanical properties. However, surface modification of titanium and titanium alloys is necessary to improve osseointegration between implant surface and bone. Especially, when titanium oxide nanotubes are formed on the surface of titanium alloy, cell adhesion is greatly improved. In addition, plasma electrolytic oxide (PEO) coatings have a good safety for osseointegration and can easily and quickly form coatings of uniform thickness with various pore sizes. Recently, the effects of bone element such as magnesium, zinc, strontium, silicon, and manganese for bone regeneration are researching in dental implant field. The purpose of this study was researched on the surface morphology of PEO-treated Ti-6Al-4V alloy after anodic titanium oxide treatmentusing various instruments. Ti-6Al-4V ELI disks were used as specimens for nanotube formation and PEO-treatment. The solution for the nanotube formation experiment was 1 M $H_3PO_4$ + 0.8 wt. % NaF electrolyte was used. The applied potential was 30V for 1 hours. The PEO treatment was performed after removing the nanotubes by ultrasonics for 10 minutes. The PEO treatment after removal of the nanotubes was carried out in the $Ca(CH_3)_2{\cdot}H_2O+(CH_3COO)_2Mg{\cdot}4H_2O+Mn(CH_3COO)_2{\cdot}4H_2O+Zn(CH_3CO_2)_2Zn{\cdot}2H_2O+Sr(CH_2COO)_2{\cdot}0.5H_2O+C_3H_7CaO_6P$ and $Na_2SiO_3{\cdot}9H_2O$ electrolytes. And the PEO-treatment time and potential were 3 minutes at 280V. The morphology changes of the coatings on Ti-6Al-4V alloy surface were observed using FE-SEM, EDS, XRD, AFM, and scratch tester. The morphology of PEO-treated surface in 5 ion coating solution after nanotube removal showed formation or nano-sized mesh and micro-sized pores.

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Template 방법을 이용한 Hybrid Supercapacitor 전극용 알루미늄 분말 디스크 제조와 에칭 조건 연구 (Fabrication of Aluminum Powder Disk by a Template Method and Its Etching Condition for an Electrode of Hybrid Supercapacitor)

  • 진창수;이용성;신경희;김종휘;윤수길
    • 전기화학회지
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    • 제6권2호
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    • pp.145-152
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    • 2003
  • 전해 캐패시터와 supercapacitor의 특성을 함께 가지는 하이브리드 캐패시터의 용량은 표면이 산화물로 피복된 양극에 의해서 좌우된다 본 연구에서는 고전압 하이브리드 슈퍼캐패시터의 제조를 위해 양극의 용량 최적화를 수행하였다. $40{\mu}m$의 입자경을 갖는 알루미늄 분말과 NaCl분말을 4:1의 무게비로 혼합하여 디스크 형태의 전극을 만들고 열처리를 하였다. 열처리 후 $50^{\circ}C$의 증류수에서 NaCl을 용해시켜 열처리 온도에 따른 용량과 저항을 비교하였다. 최적의 열처리 과정을 거친 후 electropolishing 및 화학처리, 1차 및 2차 에칭을 단계별로 행하였고 각각의 단계에서 최적의 조건을 조사하였다 각각의 단계에서의 용량과 저항은 ac impedance analyzer를 사용하여 측정하였으며 전극의 표면은 SEM을 이용하여 관찰하였다. 2차 에칭 후 내전압이 300V급인 전극으로 만들기 위하여 365V로 양극산화 시켰으며, 산화된 알루미늄 디스크 전극을 사용하여 단위 셀을 제조하여 주파수에 따른 용량과 저항 특성을 기존의 300V급 알루미늄 전해 캐패시터와 비교하였다.