• 한국조명전기설비학회:학술대회논문집
• /
• 한국조명전기설비학회 2008년도 추계학술대회 논문집
• /
• pp.293-296
• /
• 2008

In this paper, we carried out an comparative analysis on ground impedance of single copper-, three linked copper- and single carbon- electrodes by the application of various current sources such as sine, square, and surge with fast risetime. Impedance of single-copper electrode was the highest among them and was affected as the amplitude and the frequency of applied current. However, impedance characteristics of the three linked copper- and the single carbon- electrodes showed a similar tendency.

• 대한기계학회논문집A
• /
• 제31권10호
• /
• pp.986-992
• /
• 2007

This paper presents the fabrication and characterization of carbon films pyrolyzed with various photoresists for bioMEMS applications. To verify the usefulness of pyrolyzed carbon films as an electrode material in an electrochemical biosensor developed by the authors, interactions between avidin and biotin on the pyrolyzed carbon film were studied via electrochemical impedance spectroscopy based on electrostatic interactions between avidin and negatively-charged ferricyanide. The pyrolyzed carbon films were characterized using a surface profiler, a precision semiconductor parameter analyzer, a nanoindentor, scanning electron microscopy, and atomic force microscopy. Amine conjugated biotin was immobilized on the electrode using EDC/NHS as crosslinkers after $O_2$ plasma treatment to enhance functional groups on the carbon electrode pyrolyzed at $1000^{\circ}C$ with AZ9260. The detection of avidin binding with different concentrations in a range of 0.75 nM to $7.5\;{\mu}M$ to the pyrolyzed carbon electrode modified with biotin was carried out by measuring the electrochemical impedance change. The results show that avidin binds to the biotin on the electrode not by non-specific interaction but by specific interaction, and that EIS successfully detects this binding event. Pyrolyzed carbon films are a promising material for miniaturization, integration, and low-cost fabrication in electrochemical biosensors.

• Transactions on Electrical and Electronic Materials
• /
• 제6권5호
• /
• pp.238-242
• /
• 2005

The Pt counter electrode of a dye-sensitized solar cell (DSSC) plays a role in helping redox reaction of iodine ions in electrolyte, also, transferring electrons into electrolyte. In this case, it is expected that characteristics of Pt electrodes strongly depend on fabrication process and its surface condition. In this study, Pt electrodes were prepared by a electro-deposition and a RF magnetron sputtering. Electrochemical behavior of Pt electrodes was compared using cyclic-voltammetry and impedance spectroscopy. Surface morphology of Pt electrodes was investigated by FE-SEM and AFM. I-V characteristics of DSSC were measured and discussed in association with the surface properties of counter electrode. As a result, electrochemical properties of electro-deposited Pt electrode were superior to that of sputtered Pt electrode. This is likely that enlarged area of surface in electro-deposited Pt electrode in comparison with the case of sputtered Pt electrode playa role in enhancing such electrochemical properties.

• 한국전기전자재료학회논문지
• /
• 제13권6호
• /
• pp.520-525
• /
• 2000

Glucose oxidase was immobilized in polypyrrole by electrosynthesis. The enzyme had an influence on the redox properties of a complex enzyme electrode. In the cyclic voltammograms of the enazyme electrode new peaks were appeared at the potential around 0.7V vs. Ag/AgCl in additional to the typical peaks for polypyrrole. The more immobilized the stronger the peaks became. During the cycling the pH of electrolyte solution was decreased to about 4.4 The reason for that is to be the proton released from the carboxyl in the glucose oxidase in order to keep on a charge neutrality of the oxidized enzyme. This fact suggests that the new peaks in the voltammograms are caused by the redox of glucose oxidase. In the AC impedance spectrum analysis of the electrode the diffusion of electrolyte anion was limited because of chained structure of the enzyme. The faradic impedance was large since the glucose oxidase is an insulator. Therefore when glucose oxidase is entrapped the enzyme should be limited in amount. Because the growth of the polypyrrole is accompanied both charge transfer and mass transport. For the traditional electrosynthesis that means amount of enzyme present in the electrode is limited to as much as film growable.

• 전기화학회지
• /
• 제2권1호
• /
• pp.38-45
• /
• 1999

Electrochemical lithium intercalation into a PECVD (plasma enhanced chemical vapour deposited) carbon film electrode was investigated in 1 M $LiPF_6-EC$ (ethylene carbonate) and DEC (diethyl carbonate) solution during lithium intercalation and deintercalation, by using cyclic voltammetry supplemented with ac-impedance spectroscopy. The size of the graphitic crystallite in the a- and c-axis directions obtained from the carbon film electrode was much smaller than those of the graphite one, indicating less-developed crystalline structure with hydrogen bonded to carbon, from the results of AES (Auger electron spectroscopy), powder XRD (X-ray diffraction) method, and FTIR(Fourier transform infra-red) spectroscopy. It was shown from the cyclic voltammograms and ac-impedance spectra of carbon film electrode that a threshold overpotential was needed to overcome an activation barrier to entrance of lithium into the carbon film electrode, such as the poor crystalline structure of the carbon film electrode showing disordered carbon and the presence of residual hydrogen in its structure. The experimental results were discussed in terms of the effect of host carbon structure on the lithium intercalation capability.

• 전자공학회논문지A
• /
• 제32A권2호
• /
• pp.96-110
• /
• 1995

Traveling-wave electrodes for the high-speed Ti:LiNbO$_{3}$ modulators are designed. For a solution to the problems of 1) phase-velocity mismatching between the optical wave and the Modulating M/W, 2) M/W electrode characteristic impedance mismateching, we assume devices with 1$\mu$m thick SiO$_{2}$ buffer layer between the electrode and the Ti:LiNbO$_{3}$ substrate. The electrode analyses are performed by the FEM using the second-order triangular elements. The optimum design parameters to satisfy the phase-velocity matching and the characteristic impedance matching are sought for. By use of the analyses' results, a Mach-Zehnder optical modulator with a CPW electrode is designed as an example. the band-width estimation is also illustrated.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2009년도 제40회 하계학술대회
• /
• pp.1491_1492
• /
• 2009

The impedance of a vertical grounding electrode is not lowered by expanding the dimension of the grounding electrode, and the length of thr vertical grounding electrode which shows the minimum value of the grounding impedance for each condition of frequency and soil characteristics is existent, and it is defined as Critical length. In this paper, the critical lengths for the vertical grounding electrodes are calculated by using the distributed parameter circuit model. The adequacy of the simulations has been confirmed by comparing the simulated results with the measured results.

• 전기화학회지
• /
• 제17권3호
• /
• pp.179-186
• /
• 2014

Methanol electro oxidation on the surface of carbon paste modified by $NiCl_2/6H_2O$ was studied in 1M NaOH by potentiostatic and potentiodynamic methods. Ni/C catalyst by the concentration of 5% Ni showed about twice higher electro catalytic activity than Ni metal. The amount of monolayer's on the surface of electrode is almost one order higher for Ni/C than Ni electrode. The kinetic parameters and the diffusion coefficient of methanol were derived from chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) measurements.

• 전기학회논문지
• /
• 제62권7호
• /
• pp.974-979
• /
• 2013

$TiO_2$ thin films are fabricated using R.F.sputtering method. $TiO_2$ thin films are coated on $Al_2O_3$ substrate printed IDE(interdigitated electrode). Impedance of thin films decreases according to increase relative humidity and it increases according to decrease measuring frequency. When substrate temperature is room temperature, impedance of thin films is from 45.68[MHz] to 37.76[MHz] within the limits from 30[%RH] to 75[%RH] at 1[kHz]. Whereas when substrate temperature is 100[$^{\circ}C$], impedance of thin films is from 692[kHz] to 539[kHz] within the limits from 30[%RH] to 75[%RH] at 1[kHz]. Impedance variation of thin films is bigger in low frequency regions than in high frequency regions. When substrate temperature is 100[$^{\circ}C$], impedance of thin films is lower than that of room temperature.

• 조명전기설비학회논문지
• /
• 제27권3호
• /
• pp.36-42
• /
• 2013

This paper deals with the frequency-dependent ground impedance of ground grids combined with the carbon ground electrodes. Ground grids are generally valid for multipurpose grounding systems as well as lightning protection systems. The carbon ground electrodes may be supplementarily used to reduce the high frequency ground impedance and to improve the transient response to surge currents. The frequency-dependent ground impedances of ground grids combined with or without the carbon ground electrodes were measured and their simulations with due regard to frequency-dependent soil resistivity were implemented by using EMTP program and Matlab modeling. As a consequence, the ground impedance of ground grids combined with the carbon ground electrodes is significantly reduced when the test current is injected at the terminal of the carbon ground electrode. The measured and simulated data for the test ground grids fairly agree with each other. It was found that the proposed method of simulating the frequency-dependent ground impedance is distinguished. The simulation techniques of predicting accurately the ground impedances without actual measurements can be used in the design of grounding systems based on ground grids and the carbon ground electrodes.