• Title/Summary/Keyword: electrode impedance

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Improvement of Charge Transfer Efficiency of Dye-sensitized Solar Cells by Blocking Layer Coatings (차단막 코팅에 의한 염료 태양전지의 전하전송효율 개선에 관한 연구)

  • Choi, Woo-Jin;Kim, Kwang-Tae;Kwak, Dong-Joo;Sung, Youl-Moon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.344-348
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    • 2011
  • A layer of $TiO_2$ thin film less than ~200nm in thickness, as a blocking layer, was deposited by 13.56 MHz radio frequency magnetron sputtering method directly onto the anode electrode to be isolated from the electrolyte in dye-sensitized solar cells (DSCs). This is to prevent the electrons from back-transferring from the electrode to the electrolyte ($I^-/{I_3}^-$). The presented DSCs were fabricated with working electrode of F:$SnO_2$(FTO) glass coated with blocking $TiO_2$ layer, dye-attached nanoporous $TiO_2$ layer, gel electrolyte and counter electrode of Pt-deposited FTO glass. The effects of blocking layer were studied with respect to impedance and conversion efficiency of the cells. The, electrochemical impedances of DSCs using this electrode were $R_1$: 13.9, $R_2$: 15.0, $R_3$: 10.9 and $R_h$: $82{\Omega}$. The $R_2$ impedance related by electron movement from nanoporous $TiO_2$ to TCO showed lower than that of normal DSCs. The photo-conversion efficiency of prepared DSCs was 5.97% ($V_{oc}$: 0.75V, $J_{sc}$: 10.5 mA/$cm^2$, ff: 0.75) and approximately 1% higher than general DSCs sample.

Impedance Spectroscopy Analysis of Hydration in Ordinary Portland Cements Involving Chemical Mechanical Planarization Slurry

  • Hwang, Jin-Ha
    • Journal of the Korean Ceramic Society
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    • v.49 no.3
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    • pp.260-265
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    • 2012
  • Impedance spectroscopy was used to monitor the hydration in the electrical/dielectric behaviors of chemical mechanical planarization (CMP)-blended cement mixtures. The electrical responses were analyzed using their equivalent circuit models, leading to the separation of the bulk and electrode based responses. The role of the CMP slurry was monitored as a function of the relative compositions of the CMP-blended cements, i.e. water, CMP slurry, and ordinary Portland cement. The presence of $Al_2O_3$ nanocrystals in the CMP slurries appeared to accelerate the hydration process, along with a more tortuous microstructure in the hydration, with enhanced hydration products. The frequency-dependent impedance spectroscopy was proven to be a highly efficient approach for evaluating the electrical/dielectric monitoring of the change in the pore structure evolution that occurs in CMP-blended cements.

Characteristics of Transient Ground Impedance of a Scaled Grounding Grid on the High Current Impulse (대전류 임펄스에 대한 소규모 메쉬전극의 과도접지임피던스 특성)

  • Lee, Tae-Hyung;Cho, Sung-Chul;Eom, Ju-Hong;Yoo, Yang-Woo;Lee, Bok-Hee
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1418_1419
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    • 2009
  • This paper presents the transient impedance when high current impulse up to 5 kA is applied to a scaled grounding grid in test field. For a realistic analysis of transient impedance on the high current impulse in the ground systems, grounding electrode installed outdoors and impulse current generator was used. The results were discussed based on its voltage and current trace, impulse impedance and V-I curve.

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Modeling of Impedance Characteristics of Grounding Electrode for Distribution Line Pole (배전전주의 봉상 접지전극 형태별 임피던스 특성의 모델링)

  • Shim, Keon-Bo;Kim, Kyung-Chul;Lee, Hyung-Soo;Park, Jae-Duck;Choi, Jong-Kee;Park, Sang-Man
    • Proceedings of the KIEE Conference
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    • 2005.07a
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    • pp.694-696
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    • 2005
  • Although DC ground resistance is a good index of grounding performance for grounding electrodes, it does not reflect the grounding performance during transient state. Besides, impulse ground impedance, which is defined by a ratio of the peak value of transient ground potential rise to the peak value of impulse current, cannot be an absolute index due to its dependence on impulse current shape. In this paper, ground impedance characteristics of ground electrodes has been measured in frequency domain ranging from 1 Hz to hundreds of kHz. Equivalent circuit models and transfer function models of the ground rod have been identified from the measured values of ground impedance in frequency domain.

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The influence of impedance on micro electrochemical machining (마이크로 전해가공에서 임피던스의 영향)

  • 강성일;주종길;박규열;전종업
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1893-1896
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    • 2003
  • This research aimed to fabricate a micro structure using micro electrochemical machining (${\mu}$-ECM). with a view to that the theory of ${\mu}$-ECM is established accurately in a different way of conventional electrochemical machining. In details, if the impedance is existed in the system, it is difficult to analyze the micro electrochemical reaction efficiently in polarization curve using a potentiodynamic test. Hence, this research investigates the relationships between impedance and electric current measuring with a potentiostatic test applying to a pair or electrode as a constant potential. And this paper examines the influence of temperature of electrolyte on polarization curve for the quantitative analysis of electrochemical reactions.

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Comparison between a differential and a non-differential amplifier system with two electrodes in bio-potential measurement (생체 전위 측정에서 2-전극 차동 증폭 시스템과 2-전극 비차동 증폭 시스템의 비교)

  • Kang, Dae-Hun;Lee, Chung-Keun;Lee, Sang-Joon;Lee, Myoung-Ho
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1977-1978
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    • 2008
  • In this paper, we compare performance of common-mode rejection between a differential and a non-differential amplifier system with two electrodes. A differential amplifier system is constant for common-mode rejection ratio(CMRR) on the frequency domain. But a non-differential amplifier's CMRR is determined by $Z_{FB}/Z_e$ ($Z_{FB}$ ; feedback impedance, $Z_e$; electrode impedance). There is trade-off between a non-differential amplifier's CMRR and its differential input impedance. And a non-differential amplifier system has some advantages for a bio-potential measurement with two electrodes because a designer can control the impedance between the body and system's common.

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Effective Body Signal Measurement with the Bioelectric Impedance Analysis (효율적인 생체 임피던스 신호 측정에 관한 연구)

  • Oh, Se-Yong;Lee, Young-Woo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • v.9 no.2
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    • pp.689-692
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    • 2005
  • Bioelectrical Impedance Analysis(BIA) can measure body water amount and then body fat mass. Locate 4 electrode in palm to measure efficiently and flow current(50kHz, 800uA) in body for measuring voltage and capacitance. And proposed method to measure body fat with hight, weight, age and distinction of sex.

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Fuel Cell Performance by the Impedance Method (임피던스법을 적용한 연료전지 성능규명)

  • 김귀열;서장수;박용필;이준응
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.157-159
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    • 2001
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO$_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(47vo1%) was bettor excellent than the others.

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Effects of Length of Down Conductor on Transient Ground Impedance (인하도선 길이에 따른 과도접지임피던스 특성)

  • Lee, B.H.;Jeong, D.C.;Lee, S.B.;Lee, T.H.;Jung, H.U.;Lee, K.S.;Lee, S.C.
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2235-2237
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    • 2005
  • This paper presents the transient impedance behaviors of grounding systems to lightning impulse current. The potential rise and effective impulse ground impedance of the test grounding electrodes were measured as a function of the rise time of impulse currents and lengths of down conductor. The transient ground impedances strongly depend on the configuration and size of grounding electrodes, the impulse current shapes and lengths of down conductor, and the inductance of reduce of grounding electrode inductance is an important factor to improve the transient ground impedance.

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A Study on the Grounding Impedance Effects and Its Characteristics (접지 임피던스의 영향분석에 관한 연구)

  • Chang, Myong-Soo;Park, Keon-Woo;Kim, Chul-Hwan
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1948-1949
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    • 2007
  • This paper presents the characteristics and effects of grounding resistor and impedance. In grounding system, Grounding resistor is governed neutral currents and voltage. It seems that, grounding resistor has 0 value, then circuit has no faults. While if grounding resistor has large value, then neutral current has large value of fault current and it is made a damage to the utility. In order to analyze the grounding impedance characteristic, EMTP simulation has been used. The grounding impedance characteristic has been analyzed and tested for various grounding arrangements and electrode circuit shapes.

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