• Journal of the Korean institute of surface engineering
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• v.29 no.6
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• pp.735-738
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• 1996

Amorphous nickelphthalocyanine(NiPc) thin films were prepared by vacuum evaporation and their electrochromic behavior and voltammograms were examined in the five kinds of aqueous electrolytes. Amorphous NiPc films were prepared on indium-tin-oxide(ITO) glass substrates cooled to-$120^{\circ}C$ by using liquid nitrogen under a vacuum of $2.4 \times 10^{-4}$. The voltammetric and electrochromic measurements were made using a potential galvanostat. In order to confirm the color change, optical vis-transmission spectra of the NiPc films were measured by a spectrophotometer with various electrode potential applied. The NiPc amorphous thin films exhibited most clearly electrochromism in $KNO_3$ aqueous electrolyte. The specimen films underwent 3 color transitions (from blue to yellow-green, then to red violet, then to dark blue), corresponding to the three peaks on the voltammograms in $KNO_3$ aqueous electrolyte. Blue is color of the as-prepared film. When the potential was swept, charge compensation was attained upon oxidation by injection of anions from the electrolyte and upon reduction by expulsion of anions.

• Korean Journal of Materials Research
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• v.28 no.7
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• pp.411-416
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• 2018

Tungsten oxide($WO_3$) films with uniform surface morphology are fabricated using a spin-coating method for applications of electrochromic(EC) devices. To improve the EC performances of the $WO_3$ films, we control the heating rate of the annealing process to 10, 5, and $1^{\circ}C/min$. Compared to the other samples, the $WO_3$ films fabricated at a heating rate of $5^{\circ}C/min$ shows superior EC performances for transmittance modulation(49.5 %), response speeds(8.3 s in a colored state and 11.2 s in a bleached state), and coloration efficiency($37.3cm^2/C$). This performance improvement is mainly related to formation of a uniform surface morphology with increased particle size without any cracks by an optimized annealing heating rate, which improves the electrical conductivity and electrochemical activity of the $WO_3$ films. Thus, the $WO_3$ films with a uniform surface morphology prepared by the optimized annealing heating rate can be used as a potential candidate for performance improvement of the EC devices.

• Polymer(Korea)
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• v.30 no.5
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• pp.367-372
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• 2006

Electrochromic materials based on conducting polymers with pendant chromophores as well as their electrochromic properties are described. The conducting polymers described aye polypyrrole, polythiophene, poly(3,4-ethylenedioxythiophene), poly (cyclopentadithiophene), and poly (1,4-bis [2- (3,4-ethylenedioxy) thienyl] benzene). The chromophores described are viologen and perylenetetra-carboxylic diimide. When the wavelength ranges of absorption of the conducting polymer and the chromophore aye not overlapping, multiple electrochromism was achieved. When the wavelength ranges are largely overlapping, higher contrast was achieved. An easy method for prediction of the film thickness for maximum contrast of a given electrochromic material is also described.

• Journal of the Korean Solar Energy Society
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• v.38 no.5
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• pp.75-84
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• 2018

The most crucial point of reducing building energy is application of high performance envelope. The amount of heat exchange through window is highest in comparison of other envelopes so that heat exchange through window influence directly with building energy consumption. The window energy performance can be define with thermal, leakage and optical performance. In previous study we can confirmed that not only thermal performance but also optical performance are considered, 11% to 15% of building energy consumption can be reduced. Smart window system has potential of energy saving so that many industry field use smart window system including architectural area and these aspect causes smart window market continuous growth year by year. In this study, building energy consumption has been analyzed which consist of smart window that dynamically control optical states. The consideration of standard commercial building model for research, the reference medium size commercial building model of DOE (Department Of Energy, USA) has been used. The building energy simulation result of 4 axis in 8 regions in Korea shows 8% to 22% reduction of building energy consumption by application of smart window system.

• Proceedings of the Materials Research Society of Korea Conference
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• 1994.11a
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• pp.75-75
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• 1994

• Proceedings of the Materials Research Society of Korea Conference
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• 1994.11a
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• pp.25-26
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• 1994

• 한국전기화학회:학술대회논문집
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• 1998.10a
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• pp.14-14
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• 1998

• 한국전기화학회:학술대회논문집
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• 2002.04a
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• pp.33-33
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• 2002

• Proceedings of the Korean Vacuum Society Conference
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• 1994.06a
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• pp.48-49
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• 1994

• Proceedings of the Korean Vacuum Society Conference
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• 1996.02a
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• pp.128-129
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• 1996