• Title/Summary/Keyword: electro-osmotic

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Lifetime Prolongation of Poly (dimethylsiloxane) Surface Modification via 2-Hydroxyethyl Methacrylate Grafting for Electroosmotic Flow

  • Park, Eun-Soo;Yang, Sang-Sik
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.4
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    • pp.142-144
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    • 2004
  • To use Poly-dimethylsiloxane (PDMS) for the electrokinetic flow channel, the PDMS surface must be modified to be hydrophilic. With $O_2$ plasma treatment, it is difficult to maintain hydrophilicity for more than one day. In this paper, we present the chemical modification of the PDMS surface using 2-Hydroxyethyl methacrylate (HEMA) to prolong hydrophilicity lifetime. The oxide radicals generated temporarily on the PDMS surface by $O_2$ plasma are grafted with HEMA. Once the PDMS samples have been grafted, they demonstrate improved hydrophilicity retainment and electroosmotic flow characteristics compared to the untreated PDMS and the oxidized PDMS following the $O_2$ plasma process. This phenomenon was verified by the contact angles, Fourier transform infrared (FTIR) spectra and electro osmotic flow rates observed for more than 300 hours.

Simulation and Validation of Methanol Crossover in DMFCs (직접메탄올 연료전지의 메탄올 크로스오버에 대한 시뮬레이션 및 검증)

  • Ko, Johan;Ju, Hyunchul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.126.1-126.1
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    • 2010
  • In direct methanol fuel cells(DMFCs), it is well known that methanol crossover severely reduces the cell performance and the cell efficiency. There are a number of design and operating parameters that influence the methanol crossover. This indicates that a DMFC demands a high degree of optimization. For the successful design and operation of a DMFC system, a better understanding of methanol crossover phenomena is essential. The main objective of this study is to examine methanol-crossover phenomena in DMFCs. In this study, 1D DMFC model previously developed by Ko et al. is used. The simulation results were compared with methanol-crossover data that were measured by Eccarius et al. The numerical predictions agree well with the methanol crossover data and the model successfully captures key experimental trends.

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Development of A New Device for Controlling Infinitesimal Flows inside a Lab-On-A-Chip and Its Practical Application (랩온어칩 내부 미세유동 제어를 위한 새로운 장치의 개발 및 적용)

  • Kim, Bo-Ram;Kim, Guk-Bae;Lee, Sang-Joon
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.305-308
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    • 2006
  • For controlling micro-flows inside a LOC (lab-on-a-chip) a syringe pump or an electronic device for EOF(electro-osmotic flow) have been used in general. However, these devices are so large and heavy that they are burdensome in the development of a portable micro-TAS (total analysis system). In this study, a new flow control system employing pressure chambers, digital switches and speed controllers was developed. This system could effectively control the micro-scale flows inside a LOC without any mechanical actuators or electronic devices We also checked the feasibility of this new control system by applying it to a LOC of micro-mixer type. Performance tests show that the developed control system has very good performance. Because the flow rate in LOC is controlled easily by throttling the speed controller, the flows in complicate microchannels network can be also controlled precisely.

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Method of Material-Stretching Mapping for Quantification of Mixing Effect in Microchannels (마이크로 채널 내의 혼합효과 정량화를 위한 물질신장 사상법)

  • Suh Y. K.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.04a
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    • pp.1-13
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    • 2005
  • Fluid flows within microchannels are characterized by low Reynolds numbers. Therefore the effect of mixing is a crucial factor in design of the channels. Since the action of the electro-osmotic or magnetic forces used in the mixing enhancement is usually periodic in the three-dimensional channel configuration, use of the various concepts of chaotic advection is reasonable in the quantification of the stirring effect. In this paper, the details of the method of material-stretching mapping is explained. The actual application of the method to the screw extruder is also presented.

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CHAOTIC MIXING IN SQUARE CAVITY FLOW (정사각형 캐비티 유동의 혼돈적 혼합 특성)

  • Le, T.H.V;Kang, S.;Suh, Y.K.
    • 한국전산유체공학회:학술대회논문집
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    • 2007.04a
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    • pp.53-57
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    • 2007
  • The quality of chaotic mixing in square cavity flow was studied numerically by CFD simulation and particle tracking technique. The chaotic mixing was generated by using time-periodic electro-osmotic flow. Finite Volume Method (FVM) was employed to get the stretching and folding field in cavity domain. With adjusting the initial condition of concentration distribution, the best values of modulation period and Peclet number which gave us good mixing performance was determined precisely. From $Poicar{\acute{e}}section$and Lyapunov exponents for characteristic trajectories we find that mixing performance also depends on modulation period. The higher value of modulation period, the better mixing performance wag achieved in this case. Furthermore, the results for tracking particle trajectories were also compared between using of Bilinear Interpolation and Higher-order scheme. The values of modulation period for obtaining best mixing effect were matched between using FVM and particle tracking techniques.

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Numerical Study for the Effect of Inlet Humidity Condition at PEMFC Channel (전산해석을 통한 고분자 전해질 연료전지 내 입구 가습조건의 영향에 관한 연구)

  • Lee Dong-Ryul;Ahmed Dewan Hasan;Bae Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.12 s.255
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    • pp.1228-1235
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    • 2006
  • PEMFC(Proton Exchange Membrane Fuel Cell) is a low temperature fuel cell and has many probabilities of commercial use. However, water management is one of the serious technical problems for commercialization. It is necessary to understand the relationship between operation conditions and water behavior in PEMFC channel because it affects fuel cell performance. In this paper, the distribution of current density according to inlet humidity condition is mainly observed and discussed. If the anode inlet is well humidified, electro-osmotic drag is very active. For this reason, current density is very high at inlet side and the distribution is non-uniform.

Series Stacking Techniques of Electrochemical Hydrogen Compressors (전기화학식 수소 압축기 직렬 스택 기술)

  • SANG HOON CHO;CHANG JONG KIM;MIN SOO KIM;DONG KYU KIM
    • Journal of Hydrogen and New Energy
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    • v.35 no.2
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    • pp.168-174
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    • 2024
  • The electrochemical hydrogen compressor was run under diverse operating conditions in order to probe its capabilities and limitations. It was found that, unlike single-cell operations, the electrochemical hydrogen compressor stack performance improved with a rise in temperature. This improvement in performance was attributed to the gradual weakening of the electro-osmotic drag over time, impacting membrane resistance. As a result of these experiments, compression levels, up to an impressive 120 bar, using the electrochemical hydrogen serial stack were achieved.

Evaluation of Electrolyte and Electrode Spacing for Application of Electrokinetic Remediation (전기동력학적 정화기술 적용을 위한 최적의 전해질 선택 및 전극간의 거리 평가)

  • Park, Geun-Yong;Kim, Woo-Seung;Kim, Do-Hyung;Yang, Jung-Seok;Baek, Kitae
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.6-15
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    • 2013
  • The influence of processing fluids and electrode spacing on the electrokinetic process was evaluated to remediate As-, Cu-, Pb-contaminated soil. Single and mixture of sodium citrate, EDTA and NaOH was used to investigate the metal extraction. EDTA for washing reagent showed the highest removal efficiency. Based on the extraction result, the electrode spacing (20, 40, 60 cm) on the electrokinetic process was investigated to remove the multi-metals from soil. The highest removal was observed at the experiment with 60 cm of electrode spacing, however, the correlation between electrode spacing and removal of metals was not clear. The electrode spacing influenced the amount of accumulated electro-osmotic flow. BCR sequential extraction showed that electrokinetic process removed the fractionation of metals bound to Fe-Mn oxyhydroxide.

Prediction of Fuel Cell Performance and Water Content in the Membrane of a Proton Exchange Membrane Fuel Cell (고분자 전해질 연료전지의 전해질 막내의 함수율과 성능 예측)

  • Yang, Jang-Sik;Choi, Gyung-Min;Kim, Duck-Jool
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.151-159
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    • 2006
  • A one-dimensional numerical analysis is carried out to investigate the effects of inlet gas humidities, inlet gas pressures, and thicknesses of membrane on the performance of a proton exchange membrane fuel cell. It is found that the relative humidity of inlet gases at anode and cathode sides has a significant effect on the fuel cell performance. Especially, the desirable fuel cell performance occurs at low relative humidity of the cathode side and at high humidity of the anode side. In addition, an increase in the pressure ranging from 1 atm to 4 atm at the cathode side results in a significant improvement in the fuel cell performance due to the convection effect by a pressure gradient toward the anode side, and with decreasing the thickness of membrane, the fuel cell performance is enhanced reasonably.

Performance Characteristics of a Polymer Electrolyte Fuel Cell with the Anodic Supply Mode (고분자 전해질 연료전지의 수소극 공급모드에 따른 성능특성)

  • Lee, Yong-Taek;Park, Cha-Sik;Heo, Jae-Hyeok;Kim, Yong-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.7 s.262
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    • pp.588-595
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    • 2007
  • The water transport inside a polymer electrolyte fuel cell (PEFC) varied according to the anodic supply mode. The performance characteristics of a PEFC which can be affected by the water transport were observed with the anodic supply mode. In the flow-through and recirculation mode the performance showed no reduction with time because the flow in the anode was not stagnated. In the dead-end mode, without any discharged gas, the water remains inside of the anode, which caused the reduction of the performance with the lapse of time. However, even in the dead-end mode, little reduction of the performance with time was shown when only the anode was humidified externally. It means that the back-diffusion was the major factor to the accumulation of water in the anode rather than external humidification.