• Title/Summary/Keyword: electro-membrane process

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Ultra-Drawing of Gel Films of Ultra High Molecular Weight Polyethylene/Low Molecular Weight Polymer Blends Containing $BaTiO_3$ Nanoparticles

  • Park Ho-Sik;Lee Jong-Hoon;Seo Soo-Jung;Lee Young-Kwan;Oh Yong-Soo;Jung Hyun-Chul;Nam Jae-Do
    • Macromolecular Research
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    • v.14 no.4
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    • pp.430-437
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    • 2006
  • The ultra-drawing process of an ultra high molecular weight polyethylene (UHMWPE) gel film was examined by incorporating linear low-density polyethylene (LLDPE) and $BaTiO_3$ nanoparticles. The effects of LLDPE and the draw ratios on the morphological development and mechanical properties of the nanocomposite membrane systems were investigated. By incorporating $BaTiO_3$ nanoparticles in the UHMWPE/LLDPE blend systems, the ultra-drawing process provided a highly extended, fibril structure of UHMWPE chains to form highly porous, composite membranes with well-dispersed nanoparticles. The ultra-drawing process of UHMWPE/LLDPE dry-gel films desirably dispersed the highly loaded $BaTiO_3$ nanoparticles in the porous membrane, which could be used to form multi-layered structures for electronic applications in various embedded, printed circuit board (PCB) systems.

RECENT DEVELOPMENTS OF MEMBRANE TECHNOLOGY IN JAPAN

  • Kimura, Shoji
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.04a
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    • pp.10-12
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    • 1991
  • The first membrane technology applied in the Japanese industry was a. electro-dialysis(ED) process using ion-exchange meabranes. These membranes were first developed in early 50ties and the Japanese government decided to use this method for concentration of sea water to produce salt, which was then produced by solar evaporation. This development program started from 1960 by the Japan monopoly Coop. (at that time). To apply ED process for sea-water concentrat ion it was necessary to develop ion-exchange membranes having very low electric resistance to avoid energy loss due to Joule heat, and those having selectivity to permeate single valent ions only to avoid scale formation in the ED stacks. These Japanese companies, Asahi Glass, Asahi Chemical and Tokuyama Soda, have succeeded to develop such membranes, and until 1971 all of the seven salt manufacturing companies had adopted ED for production of food salt.

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A Study on the Pd-Ni Alloy Hydrogen Membrane Using the Sputter Deposition (스퍼터 증착 방식으로 제조된 Pd-Ni 합금 수소 분리막 연구)

  • Kim Dong-Won;Park Jeong-Won;Kim Sang-Ho;Park Jong-Su
    • Journal of the Korean institute of surface engineering
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    • v.37 no.5
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    • pp.243-248
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    • 2004
  • A palladium-nikel(Pd-Ni) alloy composite membrane has been fabricated on microporous nickel support formed with nickel powder. Plasma surface treatment process is introduced as pre-treatment process instead of HCI activation. Pd coating layer was prepared by dc magnetron sputtering deposition after $H_2$ plasma surface treatment. Palladium-nickel alloy composite layer had a fairly uniform and dense surface morphology. The membrane was characterized by permeation experiments with hydrogen and nitrogen gases at temperature of 773 K and pressure of 2.2psi. The hydrogen permeance was 6 ml/minㆍ$\textrm{cm}^2$ㆍatm and the selectivity was 120 for hydrogen/nitrogen($H_2$/$N_2$) mixing gases at 773 K.

Alkali Recovery by Electrodialysis Process: A Review (전기투석 공정에 의한 알칼리 회수: 총설)

  • Sarsenbek Assel;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.3
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    • pp.87-93
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    • 2023
  • Electrodialysis (ED) is essential in separating ions through an ion exchange membrane. The disposal of brine generated from seawater desalination is a primary environmental concern, and its recycling through membrane separation technology is highly efficient. Alkali is produced by several chemical industries such as leather, electroplating, dyeing, and smelting, etc. A high concentration of alkali in the waste needs treatment before releasing into the environment as it is highly corrosive and has a chemical oxygen demand (COD) value. The concentration of calcium and magnesium is almost double in brine and is the perfect candidate for carbon dioxide adsorption, a major environmental pollutant. Sodium hydroxide is essential for the metal carbonation process which, is easily produced by the bipolar membrane electrodialysis process. Various strategies are available for its recovery, like reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and ED. This review discusses the ED process by ion exchange membrane for alkali recovery are discussed.

Development Trend of Membrane Filter Using Ceramic Fibers (세라믹 섬유를 이용한 멤브레인 필터의 연구개발 동향)

  • Kim, Deuk Ju;Lee, Jeong Woo;Nam, Sang Yong
    • Membrane Journal
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    • v.26 no.2
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    • pp.87-96
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    • 2016
  • Ceramic materials have attracted increasing attention in the last 10 years because of their high thermal stability and high permeation property compared with polymeric nanofiber membranes. Recently, novel nanofiber ceramic membranes with high porosity and flux have been fabricated from metal oxide nanofibers. To improve the performance of ceramic membranes and reduce their costs, a new ceramic membrane with a selective separation layer made of nanofibers was fabricated by electrospinning process and modification process for filtration system. This review summarizes the research trends for the development of ceramic nanofiber membrane over the past few years.

Effect of Thermal Pressing Temperature on the Mechanical and Material Properties of Electro-spun Polyacrylonitrile Nano-fibrous Separator (열압착 온도가 전기방사 Polyacrylonitrile 분리막의 기계적 강도 및 물성치에 미치는 영향)

  • Kim, Minchoel;Ko, Tae Jo;Arifeen, Waqas Ul;Dong, Ting
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.4
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    • pp.109-116
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    • 2019
  • The mechanical deformation of a battery separator causes internal short-circuiting of the cathode - anode, which directly affects the explosion/ignition of batteries. To increase the mechanical properties of the separator fabricated by electro-spinning, use of a thermal pressing method is inevitable. Therefore, this research aims to maximize the mechanical strength of a porous separator by finding the proper thermal press temperatures given to Electro-spun Polyacrylonitrile (PAN) nanofibers. The different thermal press temperatures $25^{\circ}C$, $50^{\circ}C$, $75^{\circ}C$, and $100^{\circ}C$ were applied to the electro-spun fiber at 30 MPa pressure for one hour. The higher the temperature, the higher the resultant tensile strength; however, a higher temperature also lowered the strain and porosity. Thus, the membrane thermal pressed at $50^{\circ}C$ showed the best mechanical properties and the second highest porosity. Using the data, $50^{\circ}C$ was judged as the best thermal pressing temperature in terms of performance.

Application of electro-coagulation for the pretreatment of membrane separation of anaerobic digestion effluents (혐기성 소화액의 막분리를 위한 전기응집 전처리 연구)

  • Kim, Shin-Young;Chang, In-Soung;Kim, Jang-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4665-4674
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    • 2014
  • The aim of this study was to confirm the feasibility of the electro-coagulation process as a pre-treatment for the membrane separation of anaerobic digestion effluents to minimize membrane fouling. The reduction of membrane fouling was evaluated according to the number of electrodes (immersed surface area of electrodes), current density and contact time. In the case of the small surface area of electrodes, the increased electric field strength resulted in a soluble COD increase due to the destruction of the microbial flocs and/or cells, whereas large changes in the soluble COD were not observed in the case of the high surface area of electrodes. On the other hand, the T-P concentration decreased as a result of the precipitation of aluminum ions and phosphates. The membrane permeation flux increased and the fouling resistance (Rc+Rf) decreased with increasing electric current density. Although the particle size of the anaerobic digestion effluent increased slightly, it was not related directly to the reduced fouling phenomena. The main mechanism for the enhanced flux was attributed to the inorganic particulate produced during electrocoagulation, such as $AlPO_4$, which acted as a dynamic membrane deposited on the membrane surface.

HI concentration by EED for the HI decomposition in IS process (IS 프로세스의 HI 분해반응공정을 위한 전해 - 전기투석(EED) HI 농축)

  • Hong, Seong-Dae;Kim, Jeong-Geun;Lee, Sang-Ho;Choi, Sang-Il;Bae, Ki-Kwang;Hwang, Gab-Jin
    • Journal of Hydrogen and New Energy
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    • v.17 no.2
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    • pp.212-217
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    • 2006
  • An experimental study on Electro-electrodialysis (EED) for IS (Iodine-Sulfur) process which is well known as hydrogen production system was carried out for the HI concentration from HIx (HI: $H_2O$ : $I_2$ = 1 : 5 : 1) solution. The polymer electrolyte membrane and the activated carbon cloth were adopted as a cation exchange membrane and electrode, respectively. In order to evaluate the temperature effect about HI concentration in fixed molar ratio, three case of temperature were selected to $60^{\circ}C$, $90^{\circ}C$ and $120^{\circ}C$. The electro-osmosis coefficient and transport number of proton have been changed from 1.95 to 1.21 (mol/Faraday) and 0.91 to 0.76, respectively as temperature increase from $60^{\circ}C$ to $120^{\circ}C$. It can be realized that the HI mole fraction in final stage of EED experiments already over the quasi-azeotrope composition.

The Properties of Fine Drop Jetting Actuator at Various PZT Powder Composition (파우더 조성에 따른 PZT의 미세액적 토출 액츄에이터 특성)

  • Kim, Young-Jae;Yoo, Young-Seuck;Park, Sung-Jun;Kim, Soon-Young;Sim, Won-Chul;Hong, Sae-Won;Joung, Jae-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.340-341
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    • 2005
  • Three different composition 130um thickness PZT were fabricated by extrusion method and burned out at $550^{\circ}C$ and sintered at $1260^{\circ}C$/2.5hrs. Actuator was fabricated using glass and Si(100) wafer by MEMS process. From XRD data, in case of DECH, perovskite phase peak strength is higher than others. We were able to obtain the information of grain growth and porosity by SEM images. Also DECH PZT on glass membrane(100um thickness) have larger displacement than others.

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