• Title/Summary/Keyword: elecrodeposition

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PHOTOELECTRODEPOSITION OF COPPER ON BORON-DOPED DIAMOND FILMS: ITS APPLICATION TO CONDUCTIVE PATTERN FORMING ON DIAMOND AND DIAMOND PHOTOGRAPHIC PHENOMENON

  • Yoshihara, S.;Shinozaki, K.;Shirakashi, T.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.244-248
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    • 1999
  • Photoelectrodeposition of copper on semiconductive B-doped diamond films was investigated. There are cleasr morphology differences between photodeposited copper and electrodeposited copper. Photoelecrodeposition proceeded as uniform 2-dimensional growth. On the other hand electrodeposition proceeded as scarce random deposition. By applying this effect we have succeeded in forming a conductive pattern on semiconductive B-doped diamond with the aid of a photo-mask. And it was suggested that the surface reforming caused by photoelectrochemical process could be easily detected by the following metal (copper) deosition method, which is demonstrated as 'Diamond photographic phenomenon'.

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Electrochemical Analysis of the Electrodeposition of Platinum Nanoparticles (백금 나노입자 전착의 전기화학적 분석)

  • Lee, Hae-Min;Cho, Sung-Woon;Kim, Jun-Hyun;Kim, Chang-Koo
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.540-544
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    • 2015
  • A bath for electrodeposition of platinum nanoparitcles on low-cost graphite substrates was developed to attach nanoparticles directly onto a substrate, and electrochemical characteristics of the electrodeposition of platinum nanoparticles were investigated. The reaction mechanism was examined by the analysis of polarization behavior. Cyclic voltammetry measurements revealed that the elecrodeposition of platinum nanoparticles was limited by mass transfer. The chronoamperometric study showed an instantaneous nucleation mechanism during the electrodeposition of platinum nanoparticles on graphite. Because graphite is much cheaper than other carbon-based substrates, the electrodeposition of platinum nanoparticles on the graphite is expected to have useful applications.