• Title/Summary/Keyword: effective diffusion coefficients

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Estimation of Effective Dose to Residents Due to Hypothetical Accidents During Dismantling of Steam Generator

  • Kyeong-Ju Lee;Chang-Lak Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.2
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    • pp.183-191
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    • 2023
  • The potential impact of hypothetical accidents that occur during the immediate and deferred dismantling of the Kori Unit 1 steam generator has been comprehensively evaluated. The evaluation includes determining the inventory of radionuclides in the Steam Generator based on surface contamination measurements, assuming a rate of release for each accident scenario, and applying external and internal exposure dose coefficients to assess the effects of radionuclides on human health. The evaluation also includes calculating the atmospheric dispersion factor using the PAVAN code and analyzing three years of meteorological data from Kori NPP to determine the degree of diffusion of radionuclides in the atmosphere. Overall, the effective dose for residents living in the Exclusion Area Boundary (EAB) of Kori NPP is predicted, an it is found that the maximum level of the dose is 0.034% compared to the annual dose limit of 1 mSv for the general public. This implies that the potential impact of hypothetical accidents on human health discussed above is within acceptable limits.

A Study on Evaluation of Adsorption Performance of Humic Acid on Granular Activated Carbon (Humic acid 제거를 위한 국산 입상활성탄의 흡착성능 평가에 관한 연구)

  • Shin, Sung-Gyo;Kim, Jong-Gu;Park, Cheong-Gil
    • Journal of Environmental Science International
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    • v.2 no.1
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    • pp.73-81
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    • 1993
  • Adsorption process using granular activated carbon(GAC) has been considered as one of the most effective water treatment technologies to remove humic acid which is recon- niEed as trihalomethane(THM) precursor in chlorination. To design the most effective GAC process, it is necessary to conduct the test of adsor- ption performance by means of isothem, batch rate and column studies and to select the most effective activated carbon according to raw materials of GAC - lignite and coconut shell. The objective of this study is to investigate the adsorption performance of humid acid on two activated carbons - lignite activated carbon(LAC) and coconut shell activated car- bon(CAC) made in Korea. It is available to represent UV-abs and trihalomethane formation potential(THMFP) as concentration of humic acid due to good relationship. The adsorption capacity of humid acid is not concerned with surface area of activated carbon but with pore size related to about $100{\AA}$, and then LAC forming at the extent of mesopore is found to be eight times more effective in adsorption capacity than CAC forming at micropore. The adsorption capacity of LAC and CAC is better at pH 5.5 than at pH 7. Pore and surface diffusion coefficients calculated from the diffusion model are $7.61\times10^{-13}m^2/sec$, $3.52\times10^{-15}m^2/sec$ for CAC, and $3.38\times10^{-12}m^2$/sec and $Ds=1.48{\times}10^{-15}m^2/sec$ for GAC respectively. From the results of column test it shows that the performance of LAC is also better than CAC and the optimal EBCT(Empty Bed Contact Time) is 4.52min. and activated carbon removes selectively the components of humic acid to be easily formed to THM.

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Analysis of Exposure Doses and Determination of Atmospheric Diffusion Coefficients (피폭선량 해석과 대기확산계수 결정)

  • Kim, Byung-Woo;Han, Moon-Hwee;Lee, Young-Bok;Lee, Jeong-Ho
    • Journal of Radiation Protection and Research
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    • v.9 no.1
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    • pp.26-32
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    • 1984
  • The exposure doses by the radioactive gaseous effluents from nuclear power plants are investigated in the two cases of normal operation and hypothetical accident. Gaussian equation is adapted in the normal operation as the diffusion model of effluents for long period, which uses annual average meteorological data. But the real time models have been used in the case of accidents which analyze the changes of wind direction and speed. In this study the annual exposure doses by the normal operation of Kori unit 1 during $1977{\sim}1982$ were calculated on the basis of the atmospheric diffusion factor by the Gaussian straight line model. And the image processing technique was suggested as the effective method through the wind tunnel experiments to get the characteristic value of atmospheric diffusion coefficient required especially in the accidents of nuclear power plants.

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Numerical Analysis of Meso-Scale Circulation with Inclusion of a Layer of Vegetation over Ulsan Area (식생의 영향을 고려한 울산지역의 중규모 지역기상장에 관한 연구)

  • Lee, Seong-Dae
    • Journal of Korea Water Resources Association
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    • v.30 no.2
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    • pp.119-129
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    • 1997
  • A three-dimensional numerical model for the simulation of meso-scale local circulation is developed and it is applied to the land and sea breezes which take place around Ulsan. The surface temperature and moisture on the land are determined by means of the surface heat budget with a layer of vegetation considered. The vertical diffusion coefficients of momentum, heat and specific humidity at the surface layer are obtained by the lever-2 model of the turbulence closure proposed by Yamada (1982). This model proved to be effective in simulating the structure of the land and sea breezes around Ulsan.

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Adsorption of Lead Ion by Zeolites Synthesized from Jeju Scoria (제주 스코리아로부터 합성된 제올라이트에 의한 납이온 흡착)

  • Kam, Sang-Kyu;Hyun, Sung-Su;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.20 no.11
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    • pp.1437-1445
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    • 2011
  • The adsorption performance of lead ion was studied using five zeolites (Na-P1, sodalite (SOD), analcime (ANA), nepheline hydrate (JBW), cancrinite (CAN)) synthesized from Jeju scoria. The adsorption performances of lead ion decreased in the order of Na-P1 > SOD > ANA > JBW > CAN. These results showed that the synthetic zeolite with a higher cationic exchange capacity showed a higher adsorption performance. The uptake of lead ion by synthetic zeolites were described by Freundlich model better than Langmuir model. The adsorption kinetics of lead ion by synthetic zeolites fitted the pseudo 2nd order kinetics better than pseudo 1st order kinetics. The effective diffusion coefficients of lead ion by synthetic zeolites were ten times higher than the zeolite A synthesized from coal fly ash.

Removal of Copper ton by Na-P1 Synthesized from Jeju scoria (제주 스코리아로부터 합성된 Na-P1 제올라이트에 의한 Cu 이온 제거)

  • 감상규;홍정연;현성수;안병준;이민규
    • Journal of Environmental Science International
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    • v.11 no.1
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    • pp.75-83
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    • 2002
  • The removal performance of copper ion was studied using Na-P1 zeolites synthesized from Jeju scoria. The scoria which is found in large amounts in Jeju Island, was sampled at four regions, Jeju-shi Bonggae-dong(A). Pukcheju-gun Hanlim-eup Sangmyong-ri Mangoreum(B), Pukcheju-gun Hanlim-eup Keumag-ri(C) and Namcheju-gun Andeok-myun Dongkwang-ri(D). Synthetic Na-P1 zeolites used in this study were more effective than natural zeolite and scoria for the removal of copper ion. The removal performances of copper ion decreased in the order of Na-P1(D) > Na-P1(C) > Na-P1(B) > Na-P1(A) among Na-P1 synthesized from the scoria according to region. These results showed the same trend with cation exchange capacity(CEC) for each synthetic zeolite, i.e., the synthetic Na-P1 zeolite with a higher CEC showed a higher removal performance. The effective diffusion coefficients of copper ion by synthetic Na-P1 zeolites were one hundred and ten times higher than those by a pure zeolite 4A and the zeolite A synthesized from coal fly ash, respectively.

Drying Kinetics of Onion Slices in a Hot-air Dryer

  • Lee, Jun-Ho;Kim, Hui-Jeong
    • Preventive Nutrition and Food Science
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    • v.13 no.3
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    • pp.225-230
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    • 2008
  • Onion slices were dehydrated in a single layer at drying air temperatures ranging from $50{\sim}70^{\circ}C$ in a laboratory scale convective hot-air dryer at an air velocity of 0.66 m/s. The effect of drying air temperature on the drying kinetic characteristics were determined. It was found that onion slices would dry within $210{\sim}460\;min$ under these drying conditions. Moisture transfer during dehydration was described by applying the Fick's diffusion model and the effective diffusivity changed between $1.345{\times}10^{-8}$ and $2.658{\times}10^{-8}\;m^2/s$. A non-linear regression procedure was used to fit 9 thin layer drying models available in the literature to the experimental drying curves. The Logarithmic model provided a better fit to the experimental drying data as compared to other models. Temperature dependency of the effective diffusivity during the hot-air drying process obeyed the Arrhenius relationship with estimated activation energy being 31.36 kJ/mol. The effect of the drying air temperature on the drying model constants and coefficients were also determined.

Quantitative Label-free Terahertz Sensing of Transdermal Nicotine Delivered to Human Skin

  • Lee, Gyuseok;Namkung, Ho;Do, Youngwoong;Lee, Soonsung;Kang, Hyeona;Kim, Jin-Woo;Han, Haewook
    • Current Optics and Photonics
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    • v.4 no.4
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    • pp.368-372
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    • 2020
  • We report the terahertz time-domain spectroscopy (THz-TDS) of transdermal drug delivery in human skin. The time evolution of transdermal nicotine delivery in nicotine patches was assessed by detecting the transmission coefficient of sub-picosecond THz pulses and using a semi-analytic model based on the single-layer effective medium approximation. Using commercial nicotine patches (Nicoderm CQ®, 7 mg/24 h), THz transmission coefficients were measured to quantitatively analyze the cumulative amounts of nicotine released from the patches in the absence of their detailed specifications, including multilayer structures and optical properties at THz frequencies. The results agreed well with measurements by conventional in vitro and in vivo methods, using a diffusion cell with high-performance liquid chromatography and blood sampling respectively. Our study revealed the ability of the THz-TDS method to be an effective alternative to existing methods for noninvasive and label-free assessments of transdermal drug delivery, showing its high promise for biomedical, pharmaceutical, and cosmetic applications.

A Study on the Ventilation Effects of the Shaft Development at a Local Limestone Mine (국내 석회석 광산 수갱 굴착에 의한 통기효과 분석 연구)

  • Lee, Changwoo;Nguyen, Van Duc;Kubuya, Kiro Rocky;Kim, Chang O
    • Tunnel and Underground Space
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    • v.28 no.6
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    • pp.609-619
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    • 2018
  • This study was carried out at a local limestone mine to analyze the ventilation efficiency of the shaft equipped with a main fan. The results show that its ventilation efficiency is clearly verified for the natural as well as the mechanical ventilation. The airflow rate of $11.7m^3/s$ was induced by the natural ventilation force and the maximum quantity is almost same as the airflow rate estimated by monitoring the average temperatures in the upcast and downcast air columns. Meanwhile, the airflow rate exhausted by the main fan through the shaft was $20.3{\sim}24.8m^3/s$; variation of the quantity was caused by the upward shift of the mine ventilation characteristic curve due to the frequent movement of the equipment. This indicates efforts are required to reduce the ventilation resistance and raise the quantity supplied by the main fan. The turbulent diffusion coefficients along the 1912 m long airway from the portal to the shaft bottom was estimated to be $15m^2/s$ and $18m^2/s$. Since these higher coefficients imply that contaminants will be dispersed at a faster velocity than the airflow, prompt exhaust method should be planned for the effective air quality control. The ventilation shaft and main fan are definitely what local limestone mines inevitably need for better working environment and sustainable development.

Studies on the Micelle Formation of Nonionic Surfactant(1) -1NMR Self-Diffusion and Proton Relaxation of Polyoxyethylene Alkyl Ether- (계면활성제 수용액의 미셀형성(제1보) - Polyoxyethylene Alkyl Ether의 자기확산과 프로톤 이완 -)

  • Choi, Seung-Ok;Jeong, Hwan-Kyeong;Lee, Jin-Hee;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.822-828
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    • 1998
  • Binary system of water and polyoxyethylene dodecyl ether, $C_{12}H_{25}(OCH_2CH_2)nOH$, have been studied by $^1H$ NMR techniques. For n=5($C_{12}EO_5$) and n=8($C_{12}EO_8$), the self-diffusion coefficients of nonionic surfactants in the isotropic phase($L_1$) have been measured by using pulsed field gradient technique for a range of temperature and concentrations. In addition the line widths of the different proton signals have been monitored, and samples of some liquid crystalline characteristic were also studied. Dramatic Broadening of the methylene signals of the alkyl($C_{12}H_{25}$) chain is observed as the hexagonal liquid crystalline phase is approached in the $C_{12}EO_5-$water system, while only small broadening is observed in the $C_{12}EO_8-$water system. It was shown that there was a growth of $C_{12}EO_5$ micelles to rods with increasing concentrations, while the $C_{12}EO_8-$ micelles at low temperature remain small in the concentration range. The self-diffusion coefficients of the surfactants decrease rapidly with increasing concentration until a minimum is reached after which there is slow increase. The location of the minimum point occurs at lower concentrations the temperature is close to the cloud point, where the system separate into two isotropic phase. In the line width studies, broadening is found at a certain temperature interval when the concentration is increased in the $C_{12}EO_5$ system. The results indicate that the surfactant aggregates grow in size at the cloud point is approached. The aggregates seem to be flexible and probably not to be of a definite shape close to the cloud point. In the $C_{12}EO_8$ system, the micelles are much less affected by an increase in temperature and micellar growth can't be unambiguously established. The methylene signals of the ethylene oxide moieties consistantly show narrower $^1H$ signals, showing that in the aggregates they are less ordered than the chain methylenes. The various changes in aggregate size and shape are correlated with the stability ranges of the isotropic and liquid crystalline phases according to phase diagrams from the literature. Both aggregate size and phase structure are in qualitative agreement with concentration based on the effective shape of the molecules at different temperature and concentration.

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