• 제목/요약/키워드: effective diffusion coefficient

검색결과 138건 처리시간 0.025초

이온교환 평판도파로의 실효굴절율 측정 및 해석 (Analysis and Measurement of Effective Refractive Indices with Ion-exchanged Slab Waveguide)

  • 천석표;박정일;박태성;정홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.73-76
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    • 1995
  • In this study, the slab waveguide was fabricated using potassium-nitride(KNO$_3$) or silver-nitride (AgNO$_3$) molten sources by ion-exchange process. The effective refractive indices of waveguide were measured by Prism-Coupling method. and The characteristics of waveguide(mode dispersion, effective diffusion depth. surface refractive index, diffusion coefficient, and refractive index profile etc,) were investigated by WKB method, In the case of potassium ion-exchange, the computer calculation showed that the refractive index profile of waveguide followed Gaussian function, the surface refractive index increased with ion-exchange time and the effective diffusion depth increased a little as ion-exchange time increased, while the surface refractive index of silver ion-exchanged waveguide decreased with ion-exchange time because of the ion depletion on the surface of waveguide, and the effective diffusion depth seriously with ion-exchange tim. Double ion-exchanged waveguide was fabricated by performing silver ion-exchange after potassium ion-exchange. Double ion-exchanged waveguide had a tight mode binding force since the surface refractive index was larger than single step ion-exchanged waveguide.

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Migration of calcium hydroxide compounds in construction waste soil

  • Shin, Eunchul;Kang, Jeongku
    • Advances in environmental research
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    • 제4권3호
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    • pp.183-196
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    • 2015
  • Migration of leachate generated through embankment of construction waste soil (CWS) in low-lying areas was studied through physical and chemical analysis. A leachate solution containing soluble cations from CWS was found to have a pH above 9.0. To determine the distribution coefficients in the alkali solution, column and migration tests were conducted in the laboratory. The physical and chemical properties of CWS satisfied environmental soil criteria; however, the pH was high. The effective diffusion coefficients for CWS ions fell within the range of $0.725-3.3{\times}10^{-6}cm^2/s$. Properties of pore water and the amount of undissolved gas in pore water influenced advection-diffusion behavior. Contaminants migrating from CWS exhibited time-dependent concentration profiles and an advective component of transport. Thus, the transport equations for CWS contaminant concentrations satisfied the differential equations in accordance with Fick's 2nd law. Therefore, the migration of the contaminant plume when the landfilling CWS reaches water table can be predicted based on pH using the effective diffusion coefficient determined in a laboratory test.

마감공사후 경과시간에 따른 복합마감재의 VOCs/VVOCs 방출량과 실내농도에 관한 연구 (Emission rates of VOCs/VVOCs from multi-layers and their impacts on indoor air quality of Apartments)

  • 윤창현;권경우;박준석
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.295-300
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    • 2006
  • The purpose of this study is to evaluate the impacts of finishing materials' VVOCs and VOCs emission rates on indoor air quality of Apartment. VOCs emission rate of multi-layer finishing is predicted using the effective diffusion coefficient of each materials, and then the prediction is compared with Mock-up test and sample apartment house. From the results, the prediction of multi-layer finishing using the effective diffusion coefficient show good relation with the measured values.

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이온교환법에 의한 탈질소 공정개발의 기초연구(III) - 회분식 반응기에서의 반응속도론- (Basic Study for Development of Denitrogenation Process by Ion Exchange(III) - A kinetic study in the batch reactor -)

  • 채용곤;이동환;김승일;윤태경;홍성수;이민규
    • 한국환경과학회지
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    • 제9권2호
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    • pp.165-171
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    • 2000
  • A kinetic study for anion exchange was performed for commercially available Cl- type anion exchange resin in use to remove nitrate in water. The obtained results from the batch reactor were applied to the Langmuir and Freundlich models. The constants for Lagmuir model were qmax =29.82 and b=0.202, and for Freundlich model were K=5.509 and n=1.772. Langmuir model showed betterfit than Frendlich model for the experimental results. Ion exchange reaction rate was also calculated and the the approximate first-order reaction, rate constant k1 was 0.16 L/mg.hr. Effective diffusion coefficient was obtained in the range from $9.67$\times$10^{-8} cm^2/sec$ for initial concentration change, and from $6.09$\times$10^{-7} to 3.98$\times$10^{-6} cm^2/sec$ for reaction temperature change. Activation energy during the diffusion was calculated as 26 kcal/mol.

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$CF_4$ 기체의 MCS-BEq 알고리즘에 의한 전자에너지 분포함수 (Electron Energy Distribution Function in $CF_4$ Gas used by MCS-BE Algorithm)

  • 박재세;김상남;김일남
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
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    • pp.102-105
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    • 2002
  • In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1${\sim}$300 [Td] by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

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시뮬레이션에 의한 $CF_4$ 기체의 전자수송특성 (A Study of the Insulation Characteristic in $CF_4$ Gas)

  • 김상남;황청호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.468-469
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    • 2007
  • In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1~300[Td] by a two-tenn approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

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14K 화이트-레드골드의 확산접합 공정에 따른 접합 물성 연구 (Bonding Properties of 14K White-Red Gold Alloy by Diffusion Bonding Process)

  • 송정호;송오성
    • 한국재료학회지
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    • 제27권7호
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    • pp.386-391
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    • 2017
  • Using a customized diffusion bonder, we executed diffusion bonding for ring shaped white gold and red gold samples (inner, outer diameter, and thickness were 15.7, 18.7, and 3.0 mm, respectively) at a temperature of $780^{\circ}C$ and applied pressure of 2300 N in a vacuum of $5{\times}10^{-2}$ torr for 180 seconds. Optical microscopy, field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDS) were used to investigate the microstructure and compositional changes. The mechanical properties were confirmed by Vickers hardness and shear strength tests. Optical microscopy and FE-SEM confirmed the uniform bonding interface, which was without defects such as micro pores. EDS mapping analysis confirmed that each gold alloy was 14K with the intended composition; Ni and Cu was included as coloring metals in the white and red gold alloys, respectively. The effective diffusion coefficient was estimated based on EDS line scanning. Individual values of Ni and Cu were $5.0{\times}10^{-8}cm^2/s$ and $8.9{\times}10^{-8}cm^2/s$, respectively. These values were as large as those of the melting points due to the accelerated diffusion in this customized diffusion bonder. Vickers hardness results showed that the hardness values of white gold and red gold were 127.83 and 103.04, respectively, due to solid solution strengthening. In addition, the value at the interface indicated no formation of intermetallic compound around the bonding interface. From the shear strength test, the sample was found not to be destroyed at up to 100,000 gf due to the high bonding strength. Therefore, these results confirm the successful diffusion bonding of 14K white-red golds with a diffusion bonder at a low temperature of $780^{\circ}C$ and a short processing time of 180 seconds.

단열재의 무게변화와 열전도도와의 상관관계에 관한 실험적 연구 (Experimental Study of the Relationship between Weight Variation and Thermal Conductivity in Polyurethane Foam)

  • 이효진
    • 설비공학논문집
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    • 제27권5호
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    • pp.241-246
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    • 2015
  • Cellular foamed insulation such as polyurethane foam ages and degrades the thermal conductivity. Aging of foam is a result from the diffusion of gases, initially consisting of $CO_2$ but eventually replaced by air from the environment. The variation of the cell gas content with time is primarily influenced by the increase of thermal conductivity of the cellular foam. The weight of foam also changes as the gas diffuses and exchanges. In this study, a weight measurement method has been proposed to evaluate the effective diffusion coefficients of $CO_2$ and Air, $D_{CO2}=7.08504E-11$ and $D_{air}=4.86086E-12$, respectively and are compared with the gas analysis method.

복합자재에서의 VOCs 방출량 예측에 관한 연구 (Prediction of VOCs Emissions from Multi-layers Materials)

  • 윤창현;권경우;박준석
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2005년도 동계학술발표대회 논문집
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    • pp.9-14
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    • 2005
  • The purpose of this study is to predict VOCs emission rates from multi-layers materials, which are composed of single-layer materials having various VOCs emission rates, by using effective diffusion coefficients of the single-layer materials. The study was consisted of two parts; the one is the prediction of VOCs emission rates from multi-layer materials through numerical methods. The other is the measurement of VOCs emissions rates of wall composite and floor composite in Mock-up rooms for comparing the prediction and the experiments' values. The results of the study show that the short-term VOCs emission rates of multi-layers materials can be predicted from the effective diffusion coefficients of single materials in odor accuracy.

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Study on Sol-Gel Prepared Phosphosilicate Glass-Ceramic For Low Temperature Phosphorus Diffusion into Silicon

  • Kim, Young-Sig
    • Transactions on Electrical and Electronic Materials
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    • 제2권2호
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    • pp.32-36
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    • 2001
  • A new solid source for low temperature diffusion into silicon was developed. The source wafer consists of an “active” compound, which is sol-gel prepared phosphosilicate glass-ceramics containing 56% P$_2$O$\sub$5/, embedded in a skeletal foam-like, inert substrate. Phosphorus diffusion from the new solid sources at low temperatures (800-875$^{\circ}C$) produced reprodecible sheet resistances and shallow junctions. From a series of one hour doping runs, the life time of the phosphosilicate source was determined to be over 40 hours. The effective diffusion coefficient of phosphorus into silicon and the corresponding activation energy at 850$^{\circ}C$ were determined to be 7.5${\times}$10$\^$-15/ $\textrm{cm}^2$/sec and ∼3.9 eV, respectively.

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