• 제목/요약/키워드: effect of pore structure

검색결과 343건 처리시간 0.027초

시멘트 재료의 수밀성에 대한 스테아르산의 영향 (Effects of Stearic Acid on the Watertightness Properties of the Cementitious Materials)

  • 라승현;강현주;송명신
    • 한국세라믹학회지
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    • 제46권4호
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    • pp.365-371
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    • 2009
  • It is well known that the properties of concrete such as the compressive strength, water permeability, water tightness and durability are affected by micro-structure in hardened cement paste. Especially, for durability of concrete, watertightness of cementitious materials is the most critical property among various properties. Recently, many types of materials as organic and/or inorganic materials are used for watertightness of concrete. In this study, The effect of Stearic Acid at $0.5\;wt%{\sim}3.0\;wt%$ adding ratios on the hydration and watertightness property of cement were investigated. And we also discussed the changing of microstructure in hardened cement paste by addition of Stearic Acid. Cement paste with Stearic Acid showed improvement of watertightness by reducing of cement total pore volume and decomposition of Stearic Acid.

An Overview of the Activated Carbon Fibers for Electrochemical Applications

  • Lee Gyoung-Ja;Pyun Su-Il
    • 전기화학회지
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    • 제9권1호
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    • pp.10-18
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    • 2006
  • This article is concerned with the overview of the activated carbon fibers. Firstly, this review provides a comprehensive survey of the overall processes for the synthesis of the activated carbon fibers from the carbonaceous materials. Subsequently, the physicochemical properties such as pore structures and surface oxygen functional groups of the activated carbon fibers were discussed in detail. Finally, as electrochemical applications of the activated carbon fibers to electrode materials for electric double-layer capacitor (EDLC), the electrochemical characteristics of the activated carbon fiber electrodes and the various methods to improve the capacitance and rate capability were introduced. In particular, the effect of pore length distribution (PLD) on kinetics of double-layer charging/discharging was discussed based upon the experimental and theoretical results in our work. And then we discussed in detail the applications of the activated carbon fibers to adsorbent materials for purification of liquid and gas.

실내 진동대 실험을 통한 하구둑 구조물의 내진 안정성에 관한 연구 (A Study on Stability of Earthquake in Estuary Barrage through Shaking Table Test)

  • 신은철;강현회;류병현
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 추계 학술발표회 2차
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    • pp.38-44
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    • 2010
  • Shaking table tests were performed to reproduce the dynamic behavior of estuary barrage and its subbase soil which can be potentially damaged during earthquake loading. For understanding the vibration effect to the ground during earthquake, the model was formulated with 1/300 scale of prototype estuary barrage and subbase soil. Scott and Iai(1989) proposed the law of the similarity for similar experimental conditions. The laboratory model shaking table test was conducted under the vibration condition of simulated earthquake of 0.154g. The horizontal displacement on the structure was measured during the shaking table test. The pore water pressure was also monitored for the underground layers of soil. The field horizontal displacement and the pore water pressure can be predicted by using the results of the laboratory shaking table test.

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Electrochemical Properties of EDLC Electrodes Prepared by Acid and Heat Treatment of Commercial Activated Carbons

  • Wu, Jin-Gyu;Hong, Ik-Pyo;Park, Sei-Min;Lee, Seong-Young;Kim, Myung-Soo
    • Carbon letters
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    • 제9권2호
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    • pp.137-144
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    • 2008
  • The commercial activated carbons are typically prepared by activation from coconut shell char or coal char containing lots of inorganic impurities. They also have pore structure and pore size distribution depending on nanostructure of precursor materials. In this study, two types of commercial activated carbons were applied for EDLC electrode by removing impurities with acid treatments, and controlling pore size distribution and contents of functional group with heat treatment. The effect of the surface functional groups on electrochemical performance of the activated carbon electrodes was investigated. The initial gravimetric and volumetric capacitance of coconut based activated carbon electrode which was acid treated by $HNO_3$ and then heat treated at $800^{\circ}C$ were 90 F/g and 42 F/cc respectively showing 94% of charge-discharge efficiency. Such a good electrochemical performance can be possibly applied to the medium capacitance of EDLC.

콘크리트 종류별 겉보기 염소이온 확산특성 평가 (Evaluation of Apparent Chloride Diffusivity of Types of Concretes)

  • 문한영;김홍삼;최두선;이승훈;손유신
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.74-77
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    • 2003
  • This paper investigated the apparent chloride diffusivity of various concretes. Ten mixtures of concrete were initially prepared and tested to estimate diffusion property. The penetration depth and concentration of chloride ion were examined at the same water-binder ration. The binders were composed of normal portland cement, fly ash, ground granulated blast-furnace slag, and silica fume. From the results, it was concluded that using the mineral admixtures had a filling effect on the pore structure of cements matrix due to those pozzoanic reaction with the hydrates of cement, which increases the tortuosity of pore and makes large pore finer. And diffusivity of chloride is following: NPC100 > F10N90 > F30N70 > F20N80 > F20S05 > G30N70 > F10S05 > G30S05 > G30F15 > G50N50.

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쾌속조형시스템을 이용한 생체 조직 재생용 지지체 제작과 특성분석 (Bio-degradable 3D-scaffold fabrication using rapid-prototyping system)

  • 김지웅;박고은;이준희;박수아;김완두
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1697-1699
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    • 2008
  • The purpose of tissue engineering is to repair or replace damaged tissues or organs by a combination of cells, scaffold, suitable biochemical and physio-chemical factors. Among the three components, the biodegradable scaffold plays an important role in cell attachment and migration. In this study, we designed 3D porous scaffold by Rapid Prototyping (RP) system and fabricated layer-by-layer 3D structure using Polycarprolactone (PCL) - one of the most flexible biodegradable polymer. Furthermore, the physical and mechanical properties of the scaffolds were evaluated by changing the pore size and the strand diameter of the scaffold. We changed nozzle diameter (strand diameter) and strand to strand distance (pore size) to find the effect on the mechanical property of the scaffold. And the surface morphology, inner structure and storage modulus of PCL scaffold were analyzed with SEM, Micro-CT and DMA.

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도핑된 알루미나 여과막의 미세구조 변화 (Microstructural Change of Doped-Alumina Membrane)

  • 이진하;최성철;한경섭
    • 한국세라믹학회지
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    • 제36권10호
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    • pp.1040-1047
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    • 1999
  • After alumina sol was prepared by Yoldas process supported membranes were fabricated by adding ce and Re solution and SiO2 sol into alumina sol. The particle size of alumina sol was 11 nm and it was monodispersed transparent and stable for long time. The pore size of un-doped membrane started to increase to about 7,5nm at 1000$^{\circ}C$ and it was grown to twice (about 15nm) at 1100$^{\circ}C$ However the pore size of doped alumina was uniform to 1100$^{\circ}C$. The effect of retardation of grain growth was superior in SiO2 addition to that of Ce and Ru Because SiO2 doped samples transformed to needed-like phase and densified at 1200$^{\circ}C$ their application in membranes was limited. Ce and Ru doped sample showed vermicular structure identical to the un-doped ones at 1200$^{\circ}C$ But the particle size was smaller than that of un-doped ones.

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수분의 함수율에 따른 공극구조의 변화와 리튬실리케이트의 침투성 (Study on Performance of Lithium-Silicate Permeation and Changing Prosity Structure according to Water Content)

  • 김광기;문형재;김정진;박순전;이주호;정상진
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.769-772
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    • 2008
  • 공극은 열화인자의 이동경로가 되어 콘크리트의 성능을 저하시키는 요인으로 작용할 수 있으며 수분은 콘크리트 내부의 공극을 충전시킬 수 있기에 수분에 의한 투기성이 시멘트경화체의 공극구조에 미치는 영향을 평가하는 것은 중요하다. 이에, 본 연구에서는 공극구조와 투기성에 대하여 0%, 40%, 60%, 80%, 90%의 습도를 유지시킨 시험체와 화학조성물인 리튬실리케이트를 도포시켰을 경우의 공극구조 변화를 평가하였다. 그 결과, 함수율이 증가할수록 투기성은 저하되고 공극구조의 밀실성이 향상되어 수분에 의한 응축현상을 확인할 수 있었다. 그리고 수용액 상태의 리튬실리케이트는 수분을 함유하고 있는 상태에서 1$\mu$m 전, 후의 공극을 충전시켜 밀실성을 향상시키나함수조건에 따라 침투성에 의한 성능향상 범위가 제한적일 것으로 판단된다.

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불포화토의 전단 및 함수특성곡선 (The shear strength and soil water characteristic curve for Unsaturated Soils)

  • 임성윤;송창섭;류태진
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2005년도 학술발표논문집
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    • pp.361-366
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    • 2005
  • Since most soils exist above the ground water table, negative pore pressure exist in unsaturated soils. Negative pore water pressure in unsaturated soil affects the soil structure and degree of saturation and it is important for accurate evaluation of unsaturate flow and behavior. This negative pore pressure is called a matric suction which causes an increased shear strength. Therefore, it is required that the effect of increase in the shear strength should be included in a geotechnical analysis. From the test result, the influence of net confining pressure and matric suction on the shear strength was analyzed and strength parameter was increased with matric suction increase and a unliner relationship was found to relate matric suction and shear strength.

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유기실리카와 나노기공형성 수지의 상용성 변화에 의한 나노기공의 구조 변화

  • 차국헌;최연승;김상율;진문영
    • 한국결정학회:학술대회논문집
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    • 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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    • pp.52-52
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    • 2002
  • Recently, nanoporous low-k materials using porogen (pore generating material) template method have gained much attraction due to the feasible advantage of dielectric constant decrease with the increase of porogen content, which is burning out and making air void by thermal curing. In nanoporous thin films, further, control of pore size and its distribution is very important to retain suitable thermal, mechanical and electrical properties. In this study, nanoporous low-k films were prepared with MTMS-BTMSE copolymer and porogen. The effect of interaction of copolymer matrix and porogen on pore size and distribution was comparatively to investigate with molecular structure and end functional group. The characterization of nanoporous thin film prepared was also performed using various techniques including NMR, GPC, Ellipsometer, FE-SEM, TGA, and FT-IR.

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