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The State and Sources of Contamination with Heavy Metals and Anion in Stream Within Chonju City (전주시 하천의 중금속과 음이온에 대한 수질현황 및 오염원)

  • 오창환;이지선;김강주;정성석;황갑수;이영엽
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.89-104
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    • 2001
  • The Chonju and Samchun streams are passing though Chonju city and several contamination sources are located along these streams. The Samchun stream joins the Chonju stream in the Gosapyeong waste disposal site and the Chonju stream finally joins to the Mankyeong River. The objectives of this study are to determine the state and sources of contamination for heavy metals and anions in the Chonju and Samchun streams and to evaluate the effect of these streams on the contamination of the Mankyeong River. In order to select sampling locations, a stratified random sampling method was used. These streams was divided into several parts according to the expected contamination state, and samples were selected randomly from these parts. Generally, the water qualities of these streams were generally below the Drinking Water Level at the time of sampling in various heavy metals and anions. However, the levels of AI, Fe, $NH_{3}-N,Cl^{-}$, Cl- in these streams could be higher during dry season due to continuous inputs from various contamination sources. This study identified several contamination sources for these streams; two waste disposal sites along these streams for Fe, Mn, AI, Zn and $Cl^{-}$, the Chonju Waste Water Treatment Plant for Zn, Mn, $Cl^{-}$, $SO_{4}S$, $NO_{2}N$, and $NH_{3}-N$ and the untreated sewages for AI, Zn, Mn, $Cl^{-}$, $SO_{4}S$, $NH_{3}-N$ and $PO_{4}^{2-}$. This study also revealed that the Chonju stream itself is an important contamination source for Fe, Mn, $Cl^{-}$ and $SO_{4}S$ in the Mankyung River.

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Sulfate Reduction and Origin of Organic Matter in the Ulleung Basin, East Sea (동해 울릉분지에서의 황산염 환원작용과 유기물의 기원)

  • Park Myong-Ho;Kim Ji-Hoon;Ryu Byong-Jae;Kim Il-Soo;Lee Youngju;Chang Ho-Wan
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.335-346
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    • 2005
  • In this study, core sediments and pore water were analysed to identify the origin of organic matter and Bas in late Quaternary sediments from the northwestern Ulleung Basin of the East Sea. C/N and C/S ratios in the sediments show that the organic matter in the study area originated predominantly from marine algae. However, the results of Rock-Eval pyrolysis indicate that the organic matter has an origin of the land-plant (Type III), locating in the immature stage. These different results might be due to the heavy oxidizing of the organic matter during sinking down to the seafloor or after deposition in the sediments. Concentration of sulfate in the pore water decreases gradually with core depth, while concentration of $CH_4$ increases gradually with core depth. This indicates that sulfate reduction and methanogenesis occurred actively in the sediments. Also, it is likely that the compositions of $CH_4$ are characterized as a more biogenic origin, mostly caused by microbial activity, rather than a thermogenic one.

Application of In-Situ Mixing Hydration Accelerator on Polymer Modified Concrete for Bonded Concrete Overlay (접착식 콘크리트 덧씌우기를 위한 초속경화 첨가재 현장 혼합 폴리머 개질 콘크리트의 적용성 연구)

  • Kim, Young Kyu;Hong, Seong Jae;Lee, Seung Woo
    • International Journal of Highway Engineering
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    • v.17 no.3
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    • pp.85-95
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    • 2015
  • PURPOSES : Recently, bonded concrete overlay has been used as an alternative solution in concrete pavement rehabilitation since its material properties are similar to those of the existing concrete pavements. Deteriorated concrete pavements need rapid rehabilitation in order to prevent traffic jams on Korean expressways. Moreover, speedy and effective repair methods are required. Therefore, the use of bonded concrete overlay with ultra-rapid hardening cement has increased in an effort to reopen promptly the expressways in Korea. However, mobile mixer is required for ultra-rapid hardening cement concrete mixing in the construction site. The use of mobile mixer causes various disadvantages aforementioned such as limitation of the construction supply, open-air storage of mixing materials, increase in construction cost, and etc. In this study, therefore, hydration accelerator in-situ mixing on polymer modified concrete produced in concrete plant is attempted in order to avoid the disadvantages of existing bonded concrete overlay method using ultra-rapid hardening cement. METHODS : Bonded concrete overlay materials using ultra-rapid hardening cement should be meet all the requirements including structural characteristics, compatibility, durability for field application. Therefore, This study aimed to evaluate the application of hydration accelerator in-situ mixing on polymer modified concrete by evaluating structural characteristics, compatibility, durability and economic efficiency for bonded concrete overlay. RESULTS : Test results of structural characteristics showed that the compressive, flexural strength and bond strength were exceed 21MPa, 3.15MPa and 1.4MPa, respectively, which are the target strengths of four hours age for the purpose of prompt traffic reopening. In addition, tests of compatibility, such as drying shrinkage, coefficient of thermal expansion and modulus of elasticity, and durability (chloride ions penetration resistance, freezing-thawing resistance, scaling resistance, abrasion resistance and crack resistance), showed that the hydration accelerator in-situ mixing on polymer modified concrete were satisfied the required criteria. CONCLUSIONS : It was known that the hydration accelerator in-situ mixing on polymer modified concrete overlay method was applicable for bonded concrete overlay and was a good alternative method to substitute the existing bonded concrete overlay method since structural characteristics, compatibility, durability were satisfied the criteria and its economic efficiency was excellent compare to the existing bonded concrete overlay methods.

An Assessment of Groundwater Pollution Potential of a Proposed Petrochemical Plant Site in Ulsan, South Korea Hydrogeologic and site characterization and groundwater pollution potential by utilizing several empirical assessment methodologies (지하수 오염 가능성 평가 -수리지질 및 부지특성 조사와 경험적 평가 방법을 이용한 지하수 요염 가능성-)

  • Han, Jeong Sang;Han, Kyu Sang;Lee, Yong Dong;Yoo, Dae Ho
    • Economic and Environmental Geology
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    • v.23 no.4
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    • pp.425-452
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    • 1990
  • A tentative hydrogeologic and hydrodispersive study was carried out to evaluate the groundwater pollution potential at a selected site by utilizing empirical assessment methodologies in an advanced stage of quantitative computer aided assessment. The upper most aquifer is defind as saturated overburden and weathered zone including the upper part of highly fractured rock. Representative hydraulic conductivity and storativity of the uppermost aquifer are estimated at 2.88 E-6 m/s and 0.09, respectively. Also calculated Darcian and average linear velocity of groundwater along the major pathway are 0.011 m/d and 0.12 m/d with average hydraulic gradient of 4.6% in the site. The results of empirical assessment methodologies indicate that 1) DRASTIC depicts that the site is situated on non-sensitive and non-vulnerable area. 2) Legrand numerical rating system shows that the probability of contamination and degree of acceptability are classed to "Maybe-Improbable, and Probable Acceptable and Marginally Unacceptable" with situation grade of "B". 3)Waste soil-site interaction matrix assessment categorizes that the study site is located on "Class-8 Site".

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An Analysis of the Locational Motives for the Korean Auto Industry′s Investment in the U.S. - Case Study of Hyundai Motor Manufacturing Alabama - (우리나라 자동차산업의 미국투자 입지동기 분석 - 현대자동차 미 앨라배마 투자 사례를 중심으로 -)

  • 서정욱
    • Journal of the Economic Geographical Society of Korea
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    • v.7 no.1
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    • pp.65-81
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    • 2004
  • Foreign direct investment (FDI) by firms has various motives in terms of the strategy for firms' long-term growth. This research uses the case study of Hyundai Motor Manufacturing Alabama to analyze the motives of the Korean auto industry's FDI in the U.S. and the locational factors that determined the selection of the site. This paper starts from the question of why Hyundai made the decision to invest in the U.S., which is not favorable in terms of production cost, especially considering that its exports to the U.S. have been on the increase. The results indicate that the strongest motive for the decision to invest in the U.S. was to ameliorate the trade friction between Korea and the U.S. Given that Hyundai depends on the U.S. market to a large extent for its exports, the foremost motive was to use local production in order to reduce the serious trade imbalance in the automobile sector between Korea and the U.S. in order that trade friction with the U.S. may be avoided and causes for trade disputes may be reduced. Other motives such as improving the access to local consumers were of secondary importance. After the selection of the country in which to invest, however, various factors were considered in the decision regarding the location of the plant, and incentives by local governments ultimately played a key role in this decision. The results imply that the Korean manufacturing industry's investment in the U.S. cannot be explained by traditional FDI theories and instead was greatly driven by a strategic defensive motive. In addition, the results confirm that the design of an appropriate incentive structure by host governments is important for attracting FDI.

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Properties of the Variation of Fe and Mn in the Vicinity of Soil Affected by Forest Fire for the Development of Technics that Reduces Forest Fire-induced 2nd Damage from Gangwon Provinces, Korea (2차산불피해저감기술개발을 위한 강원도 산불지토양 중 Fe-Mn원소의 분포특성)

  • 오근창;양동윤;김주영;남욱현;윤정한
    • Economic and Environmental Geology
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    • v.35 no.3
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    • pp.285-297
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    • 2002
  • This study was carried out to prove the factor properties of the soil affected by a forest fire through the physical and chemical analysis and the data from the conclusion of those analysis are applied to the development of technics that reduces a forest fire-induced 2nd damage. The forest fire was in December 2000 at Gangreung city and Donghae city, Gangwon provinces, Korea. Soil samples were collected at upper layers (0-5 cm) and bottom layers (5-40 cm) in November 2001 from the burned and control sites. Values of pH in burned soils of the upper layers affected by forest fire are higher than those in control soils. Both the fragments of fire-burned plant and differences of geological properties are resulted in a class of soil. Contents of organic matters in burned soils are higher than those in control soils, exceptionally the contents of organic matters in burned soils that contain coaly shale are lower than those in control soils. Weathering indices in burned soils are higher than those in control soils and it concerned with loss of soil. Iron ions Fe(Fe$^{2+}$ or Fe$^{3+}$) are easily extracted from the burned soils by rainfall, but Mn ions are straightly exist in the burned soils by physiochemical adsorption of colloid. Through the sequential extraction in the burned soils and control soils, we are certificate the extraction of Fe ions and the disturbance of Mn ions from the burned soils. As a consequence of factor analysis in burned soil and control soil, we are certificate that the influence of forest fire results in a disturbance of positive correlation factors.

Aquifer Characterization Using Seismic Data on the Aquistore CCS Project, Canada (캐나다 아퀴스토어 탄성파자료를 통한 이산화탄소 지중저장 연구지역 대수층 특성화)

  • Cheong, Snons;Kim, Byoung-Yeop;Shinn, Young Jae;Lee, Ho-Yong;Park, Myung-Ho
    • Economic and Environmental Geology
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    • v.47 no.6
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    • pp.625-633
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    • 2014
  • The Aquistore project is the world's first commercial capture, transportation, utilization and storage project of post-combustion $CO_2$ from a coal-fired thermo electric power plant, and the proposed storage is a saline aquifer at a depth of about 3,500 m. Deep saline aquifer, compared to hydrocarbon reservoir, provides the great volumetric potential for storage of $CO_2$ anywhere in the world, therefore the research results from the project may be exported globally to other sites. Geological $CO_2$ storage characterization for saline aquifer instead of hydrocarbon reservoir needs to estimate the geophysical properties of subsurface geology. This study calculated the geophysical property of water-saturated formation by applying amplitude variation analysis developed from oil and gas exploration. We correlated horizon tops at the well logs to seismic traveltime of 1,815 and 1,857 ms as Winnipeg and Deadwood formations. Gradient analysis from seismic traces showed correlation coefficient of 45 - 81 % on amplitude variation with respect to incident angle. Crossplot of intercept and gradient shows the inverse proportional trend which represents typical water saturated sediments. Product attribute of intercept and gradient described the base of wet sediment. Poisson's ratio change attribute increased at the top of target area satisfying with wet sediment and decreased at the top of basement in a dry rock bed.

The Study of KOGAS DME Process in Small and Medium Sized Gas Field Containing $CO_2$ ($CO_2$가 함유된 중소규모 가스전을 위한 KOGAS DME Process 연구)

  • Mo, Yong-Gi;Cho, Won-Jun;Song, Taek-Yong;Baek, Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.51-55
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    • 2010
  • The global activities to reduce the $CO_2$ emission as a greenhouse gas have been various efforts. Under this circumstance, small and medium sized gas field containing $CO_2$ to develop as LNG is not economic feasibility. Particularly, for the separation of $CO_2$ in gas field, separation facilities should be installed to add. This is and increase in plant construction cost and separated $CO_2$ emission into the atmosphere is not the result of greenhouse gas reduction. When the uneconomic gas field apply the KOGAS DME process, the gas field containing $CO_2$ can be increase economic feasibility because of natural gas and $CO_2$ can be use to resource gas. The Tri-reformer produced syngas as H2 and CO in KOGAS DME process and the resource gases are natural gas, steam, oxygen and $CO_2$. The $CO_2$ is used as raw material gases from recover $CO_2$ in DME process. In this study, we investigated range of application of $CO_2$ in gas field.

Mineralogical Changes of Oyster Shells by Calcination: A Comparative Study with Limestone (소성에 따른 굴패각의 광물학적 특성변화: 석회석과의 비교 연구)

  • Lee, Jin Won;Choi, Seung-Hyun;Kim, Seok-Hwi;Cha, Wang Seog;Kim, Kangjoo;Moon, Bo-Kyung
    • Economic and Environmental Geology
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    • v.51 no.6
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    • pp.485-492
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    • 2018
  • About 300 thousand tones of oyster shells are produced annually and, thus, their massive recycling methods are required. Recently, a method, utilizing them as wet desulfurization materials after removal of organic matters and changing $CaCO_3$ phase into CaO through calcination, is under consideration. This study investigates the mineralogical changes (specific surface area, phase changes, surface state, etc.) of oyster shells by calcination and their characteristics were compared with those of limestone. Uncalcined oyster shells showed the higher specific surface area than limestone because the former are composed of platy and columnar structures. In contrast, investigated limestone showed a dense structure. The phase change of oyster shells occurred at lower temperature than that of limestone. The specific surface area of oyster shell decreased significantly after calcination while limestone depicted a drastic increase. Small amount of Na contained in oyster shell was suggested as the cause of this phenomenon; in that, it acted as a flux causing melting and sintering of oyster materials at lower temperature. Because of this, an additional phenomenon was observed that a part of shell materials remained untransformed even at higher calcination temperature and after longer treatment period due to the sintered surface, which covers the rest parts. Further studies investigating the effect of this phenomena from the perspective of desulfurization is required.

Transfer of Arsenic from Paddy Soils to Rice Plant under Different Cover Soil Thickness in Soil Amendments in Abandoned Coal Mine (폐탄광지역 비소오염 농경지(논) 개량 시 복토두께에 따른 비소의 벼 전이 및 토양용액 특성)

  • Koh, Il-Ha;Kwon, Yo Seb;Jeong, Mun-Ho;Ko, Ju In;Bak, Gwan-In;Ji, Won Hyun
    • Economic and Environmental Geology
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    • v.54 no.4
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    • pp.483-494
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    • 2021
  • This study was carried out to investigate the feasibility of reducing clean cover soil using a flooded column test in arsenic-contaminated farmland reclamation of abandoned coal mine area that shows generally low or about worrisome level (25 mg/kg) of Korea soil environment conservation act unlike abandoned metal mine. During the monitoring period of soil solution for 4 months, chemical properties (pH, EC, ORP, Fe, Mn, Ca, and As) in each layer (clean soil cover and contaminated/stabilized soil) showed different variation. This result revealed that soil solution in stabilized or contaminated soil rarely affected that in cover soil. Whether stabilized or not, arsenic concentrations in the rice roots grown in the soil covers with the thickness of 40 cm decreased by 98% in compared with the that grown in the control soil. In case of the soil covers with 20 cm thickness on stabilized soil, it decreased by 80% and this was 22 percentage point higher than when the soil of lower layer was not stabilized. Thus, reducing clean cover soil could be possible in contaminated farmland soil reclamation if appropriate stabilization of contaminated soil is carried.