• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.291-293
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• 2012

Recently, environmental pollution and global warming and greenhouse gases are increasing, because Efforts to improve are continued throughout the world. As part of the resource recycling industry has become an important research area. In the field of waterproofing industry, focus on the resource recycling is growing, due to serious resource depletion and sharp price. Therefore, in this research on the resource recycling such as reclaimed rubber and rubber waste is enable and these eco-friendly materials are applied high adhesive flexible non-exposed type self adhesion compound waterproofing material was measured eco-friendly performance and field application was evaluated.

• Journal of the Korean Chemical Society
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• v.64 no.3
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• pp.153-158
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• 2020

With the recent popularity of mobile devices, the demand for lithium-ion batteries is increasing. In this study, the surface treatment process for the development of the Al (aluminum) lead tab for positive electrode, a key component of the pouch-type lithium-ion battery, was investigated. Anodizing and sealing processes were tested as surface treatment techniques. It was found that only a sealing process is needed to obtain sufficient adhesive strength. In the present study, an adhesive strength of 17 N/12 mm was achieved by degreasing and etching pretreatment, followed by a sealing process of 10 min duration. This adhesive strength was greater than that achievable using Cr (chromium) surface treatment. Using various surface analysis techniques, the shape and composition of the surface before and after being subjected to the surface treatment were compared and analyzed. The results of this study are expected to contribute to the development of an eco-friendly lead tab.

• Journal of Adhesion and Interface
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• v.21 no.4
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• pp.135-142
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• 2020

Recently, people's interest in eco-friendly plastics derived from nature to replace petroleum-based plastics is increasing due to environmental problems such as microplastics. In line with this trend, eco-friendly adhesives using natural materials and processes are also being developed in the adhesive field. Among them, maltose is a natural substance derived from starch and is the main component of starch syrup used as a food additive. Due to its lower molecular weight than starch, it is easily soluble in water, and above all, there is a possibility that it can be copolymerized with other monomers through solution polymerization. However, researches related to the application of maltose to adhesives are very rare. In this study, after modifying maltose using acrylic anhydride, the product was analyzed through FT-IR and H-NMR. And the modified maltose was copolymerized with two kinds of acrylic monomers. The synthesized adhesive was applied on the wood and the adhesive performance were investigated.

• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.33-38
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• 2022

In this study, we report on the synthesis and properties of eco-friendly waterborne polyurethane (WPU) according to bio-polyol contents. It was successfully synthesized by the different polyester polyol (DT-1040) and castor oil based polyol (COP) ratios. The glass transition temperature (Tg) of the synthesized bio polyol based waterborne polyurethane was around -70 ℃ and -30 ℃, and it was confirmed that the Tg range was widened as the COP content increased. In addition, as the COP content increased, the tensile strength decreased, and optimum adhesive strength showed when DT-1040:COP ratio was 7:3.

• Journal of Environmental Science International
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• v.23 no.11
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• pp.1909-1918
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• 2014

In this experiment no solvent based polyurethane(PU) adhesives were prepared with the polyol, isocyanate, dioctyl phthalate(DOP), 2-hydroxyethylacrylate(2-HEA) and other acrylate monomers. The softenening point of the PU adhesives measured by Ring & Ball method were examined in the present study. And adhesion strength and mechanical properties such as tensile strength and 100% modulus of the PU adhesives were evaluated by Universal Test Machine. The experimental results showed that increase of both DPE-41, benzoylperoxide(BPO) and toluene diisocyanate(TDI) increased softenening point, adhesion strength, tensile strength and 100% modulus. However as DOP content increased sofenening point, adhesion strength decreased and tensile strength, 100% modulus also decreased.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.11a
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• pp.62-63
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• 2019

Currently, polymer-based tile cement (Thin-bed method) and epoxy adhesive (Thick-bed method) are mainly used as tile adhesive for polishing and porcelain. In the case of epoxy adhesive, there is a low economic efficiency, there is a problem that the work efficiency is reduced by mixing the resin and the hardener. In particular, the epoxy contains a bisphenol A and amine component, there is a risk of workable disease when a worker is exposed to odor and harmful gases generated in the epoxy adhesive for a long time. Against this background, it is necessary to analyze the hazards of using epoxy adhesives indoors, and develop cementitious high performance tile adhesive products with significantly lower hazards than epoxy adhesives.

• Journal of Adhesion and Interface
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• v.17 no.2
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• pp.49-55
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• 2016

In this study, we designed an environment friendly, water-based adhesive using the acrylic emulsion method as a replacement for solvent-based adhesives, which are most commonly used in layered laminates for flexible food packaging. We designed adhesives with different combinations of anionic, non-ionic, and phosphoric ester surfactants, and with different concentrations of chain transfer agent (CTA). We also examined the effect of the degree of cross-linking by synthesizing and comparing 8 test group adhesives with different types of functional monomers. Additionally, we synthesized 2 other test group pressure-sensitive adhesives (PSA) using styrene/alpha-methyl styrene/acrylic acid (SAA) semipolymer dispersing agents (with molecular weights of 13,000 g/mol and 8,600 g/mol, respectively) to replace the conventional surfactants. We evaluated whether the 10 test group pressure-sensitive adhesives met the basic physical property criteria required for flexible food packaging by carrying out a physical analysis of their glass transition temperature (Tg), particle size, adhesion, and molecular weight. In our test, 2 test group adhesives manufactured with the combination of anionic and non-ionic surfactants, CTA concentration of 0.2%, and functional monomers of hydroxyethyl acrylate (HEA) and glycidyl methacrylate (GMA) demonstrated molecular weight and flexibility suitable for flexible packaging, with low adhesiveness and small particle size.

• Journal of the Korean institute of surface engineering
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• v.47 no.3
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• pp.128-136
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• 2014

In the present study, we successfully developed an eco-friendly chemical etching solution and proper condition for plating on ABS material. The mechanism of forming Ni plating layer on ABS substrate is known as following. In general, the etching solution used for the etching process is a solution of chromic acid and sulfuric acid. The etching solution is given to the surface resulting in elution of butadiene group, so-called anchor effect. Such a rough surface can easily adsorb catalyst resulting in the increase of adhesion between ABS substrate and Ni plating layer. However a use of chromic acid is harmful to environment. It is, therefore, essential to develop a new alternative solution. In the present study, we proposed an eco-friendly etching solution composed of potassium permanganate, sulfuric acid and phosphoric acid. This solution was testified to observe the surface microstructure and the pore size of electrical Ni plating layer, and the adhesive correlation between deposited layers fabricated by electro Ni plating was confirmed. The result of the present study, the newly developed, eco-friendly etching solution, which is a mixture of potassium permanganate 25 g/L, sulfuric acid 650ml/L and phosphoric acid 250ml/L, has a similar etching effect and adhesion property, compared with the commercially used chromium acid solution in the condition at $70^{\circ}C$ for 5 min.

• Journal of the Korea Furniture Society
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• v.25 no.3
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• pp.233-237
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• 2014

The eco-friendly preservatives such as ACQ or CUAZ have been used in landscape architectural facilities these days. In this study, the decay efficacies of ACQ treatments were evaluated according to domestic veneer species, concentration of ACQ, weathering test, adhesive type, and fungus type. In case of veneer species, hinoki cypress and yellow poplar showed the highest and lowest decay resistance, respectively. And the decay resistance appeared to be greater in plywoods bonded by resorcinol resin-bonded plywood and non-weathering treated plywood than polyurethane resin-bonded plywood and weathering treated plywood.

• Textile Coloration and Finishing
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• v.26 no.1
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• pp.32-38
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• 2014

There has been increasing demand to the eco-friendly materials such as phytoncide which is extracted to plants in the textile industry, recently. It is interesting that alginic acid sodium salt(Alg-Na) is used to eco-friendly binder for the functional capsule finishing. In this study, we made PEO/Alg-Na blend solutions of various ratio and observed the changing binding property of the blend solutions according to PEO contents through FT-IR, DSC, contact angle, peel strength, etc. The viscosity of Alg-Na/PEO blend solutions increased with increase of contents and the viscosity quickly increased with increase of PEO content in Alg-Na 5% content, specially. It is shown that the hydrogen bond peak by blend of Alg-Na and PEO found through FT-IR analysis but the peak decreased in PEO above 60% content. And the peel strength was predominant in PEO 50% ratio.