• 한국건축시공학회지
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• 제18권5호
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• pp.413-418
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• 2018

이 기초 연구는 시멘트 페이스트의 초기강도 향상 및 열전도율 향상을 위한 흄드 실리카의 첨가에 대한 적용성 및 문제점을 평가하기 위한 것이다. 주요 변수인 흄드 실리카 는 시멘트 질량 대비 0%에서 1.6%까지 0.4% 간격으로 첨가하였다. 실험결과, 흄드 실리카의 첨가는 시멘트 페이스트의 초기강도 발현에 효율적이었는데, 재령 1일 압축강도는 28일 강도의 약 45%이었다. 이 높은 초기강도 발현율은 증기 양생 시멘트 콘크리트의 경우와 비슷한 수준이다. 하지만 흄드 실리카의 첨가가 시멘트 페이스트의 열전도 저항성 향상에 미치는 영향은 무의미 하였다.

• Composites Research
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• 제25권4호
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• pp.110-116
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• 2012

최근 대규모 토목구조물의 내구성 향상 및 수화열 저감 성능을 확보하기 위하여 1종 보통포틀랜드시멘트에 고로슬래그미 분말 및 플라이애시를 혼합 치환한 삼성분계 혼합시멘트(TBC)의 개발 및 현장적용이 증가하고 있다. 또한 최근 건설사를 중심으로 공사비용 절감 등을 이유로 공사기간 단축 노력이 계속되고 있다. 이를 위해 콘크리트의 조기강도 성능이 요구되어진다. 따라서 상대적으로 조기강도 발현이 느린 TBC의 성능 보완이 필요하다. 이 연구에서는 TBC 모르타르의 조기강도 발현 성능을 향상시키기 위한 노력으로, 고로슬래그미분말 및 무수석고의 분말도와 첨가율을 조절하여 모르타르의 압축강도, $SO_3$ 함량 및 SEM 분석을 실시하였다. 실험 결과, TBC 모르타르는 분말도 약 $4,200cm^2/g$의 고로슬래그미분말을 사용하고 분말도 약 $10,000cm^2/g$의 무수석고 3.5%를 첨가하고 $SO_3$함량을 3.72% 내외로 관리하는 것이 가장 우수한 조기강도 특성을 보이는 것으로 나타났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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• pp.214-215
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• 2018

This paper has been researched that the earlier compressive strength of the cement pastes containing nano-TiO₂ particle curing 1day, 3days and 7days. For the compressive strength measurements, all samples(dimensions 50×50×50mm) were prepared in accordance with ASTM C109. The compressive strength of the specimens with nano-TiO₂ at the early age(1day, 3days and 7days) stage was lower than that of the reference group. Therefore, nano-TiO₂ has little positive effect on the improvement of the compressive strength of cement pastes during early ages.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.609-612
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• 2008

마그네시아 인산염 시멘트를 사용한 보수용 모르타르의 접착강도 특성을 검토하기 위하여 모의 부재 시험체를 이용한 실험을 실시하였다. 접착강도 실험 결과 칩핑 처리를 한 시험체가 표면 처리를 한 시험체 보다 우수한 강도발현을 하였으며, 건식처리가 습식처리보다 우수한 강도발현을 하는 것으로 나타났다. 칩핑 건식 시험체의 경우 온도에 관계없이 재령 28일의 접착강도는 3.0MPa 이상의 높은 강도를 발현을 하는 것으로 나타나 일반 모르타르의 접착강도와 비교 시 매우 높은 접착성능으로써 우수한 접착성능이 요구되는 보수재료로서의 활용을 기대할 수 있을 것으로 판단된다.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2001년도 학술발표회 발표논문집
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• pp.193-197
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• 2001

The growth in concrete structures repair has prompted major efforts to develop high early strength concrete. The internal or external restraint of thermal shrinkage movements could thus generate tensile stresses in concrete structures if it is used rapid setting repair concrete. Restrained shrinkage and thermal stresses could produce microcracks in concrete which increase its permeability and accelerate its long-term deterioration under weathering and load effects. This study aims at evaluation and increase of the engineering properties of high early strength concrete using regulated set cement.

• 한국세라믹학회지
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• 제53권2호
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• pp.215-221
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• 2016

In this study, the utilization of the by-products of various industries was examined using raw materials of CSA high-functional cement such as coal bottom ash, red mud, phosphate gypsum, etc. Technology to improve energy efficiency and reduce $CO_2$ was developed as part of the manufacturing process; this technology included lower temperature sintering ($150{\sim}200^{\circ}C$) than is used in the OPC cement manufacturing process, replacement of CSA cement with the main raw material bauxite, and a determination of the optimum mix condition. In order to develop CSA cement, a manufacturing system was established in the Danyang plant of the HANIL Cement Co. Ltd., in Korea. About 4,200 tons of low purity expansion agent CSA cement (about 16%) and about 850 tons of the lime-based expansion agent dead burned lime (about 8%) were produced at a rate of 60 tons per hour at the HANIL Cement rotary kiln. To improve the OPC cement properties, samples of 10%, 13%, and 16% of CSA cement were mixed with the OPC cement and the compressive strength and length variation rate of the green cement were examined. When green cement was mixed with each ratio of CSA cement and OPC cement, the compressive strength was improved by about 30% and the expansibility of the green cement was also improved. When green cement was mixed with 16% of CSA cement, the compressive strength was excellent compared with that of OPC cement. Therefore, this study indicates the possibility of a practical use of low-cost CSA cement employing industrial wastes only.

• 산업기술연구
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• 제21권B호
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• pp.317-324
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• 2001

This study focused on the investigation of strength development and permeability of LMC(Latex Modified Concrete) and RSLMC(Rapid-Setting Cement Latex Modified Concrete) as the latex content, cement types and w/c ratio changed. The compressive strength of latex modified concrete decreased slightly and the flexural strength increased quitely at 15% of latex content. This may be due to the flexibility of latex filled in voids and interconnections of hydrated cement and aggregates by a film of latex particles, respectively. The permeability test results showed that the permeability of LMC was considerably lower than that of conventional concrete. Results of chloride permeability test, for RSLMC indicated very low at an early age caused by the early formation of needle-shape ettringites and latex film.

• 한국세라믹학회지
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• 제47권5호
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• pp.357-364
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• 2010

This study was performed to get basic information about properties of high blaine slag cement(HSC) to use shotcrete(or sprayed concrete and mortar). Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of HSC. Setting time of HSC was delayed slightly, but influence of accelerators was more bigger than ordinary portland cement(OPC). Compressive strength of HSC at 28 days was more higher than OPC regardless of using accelerators. Results of analysis showed early period hydration products of HSC is more small and located widely, because of the interface of between cement particle and water is increased as specific surface of cement increase. From the SEM observation and analysis of DSC and XRD results, aluminates accelerators bring on some hydration products like as calcium aluminium hydrates, alkali free accelerators increases ettringite and monosulfates. Aluminates accelerators has a advantage of setting time and early strength, alkali free accelerators increases strength after 7 days.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.583-586
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• 2005

Strength of concrete is very important factor in design and quality management and may represent overall quality of concrete. Such strength of concrete may differ depending on amount of cement mixed, water and fine aggregate ratio. Classic concrete products have been produced mainly with ordinary portland cement(hereinafter 'cement'), water and fine aggregate as shown above, but various additives and mixture materials have been used for concrete manufacturing, along with development of high functional concrete and diversification of structures. Various kinds of chemical mixtures agents and mixture materials have been used as it requires concretes with other features which cannot be solved with existing materials only, such as high strength, high flexibility and no-separation in the water. Such addition of various mixture agents may cause change in cement hydrate, affecting strength. Hydration of cement is the process of producing potassium hydroxide, C-S-H, C-A-H and Ettringite, while causing heat generation reaction after it is mixed with water, and generation amounts of such hydrates play lots of roles in condensation and hardening. This study aims to analyze its strength and features with hydrates by making specimen according to curing temperature, types of mixture agent, mixing ratio and ages and by analyzing such hydrates in order to analyze role of cement hydrate on early strength of concrete.

• 한국세라믹학회지
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• 제37권5호
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• pp.438-443
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• 2000

This dissertation is focused on the study over the improvement for the early strength of belite-rich cement(BRC). For this purpose, the initial hydration behaviors according to addition of different calcium sulfate types were evaluated. From the observations by XRD, DSC and SEM, the BRC II and III with the addition of natural anhydrate and flue gas desulphurization(FGD) gypsum, respectively, formed much ettringite after 7 days more than the BRC I with the addition of chemical gypsum. The compressive strength of the BRC II and III developed outstandingly due to the formation of calcium aluminate hydrate within pores of hardened BRC paste. Especially, in the case of BRC III adding FGD with low impurities, the early as well as long term compressive strengths were shown very high, compared with other specimens.