• Title/Summary/Keyword: e-SQ

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Syntheses and Absorption Spectra of Polymethine Cyanine Dyes Such as Squarylium and Croconium Dyes (Squarylium, Croconium계 기능성 색소의 합성과 흡수 스펙트라)

  • 김성훈;한선경;임용진
    • Textile Coloration and Finishing
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    • v.6 no.1
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    • pp.28-32
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    • 1994
  • The synthesis and absorption spectra of squarvlium(SQ) dyes and croconium(CR) dyes were .studied. Absorption spectra of SQ dye in various solvents exhibited a negative solvatochrornism. Thus, it was suggested that the structure of SQ dye may be a highly polar structure. The λ$_{max}$ of CR dyes undergoes a bathochromic shift of about 100nm compared with the corresponding SQ dyes. This shift can be calculated by the Pariser-Parr-Pople molecular orbital method. From the PPP MO calculation results, we found that SQ dye and CR dye have a almost same Highest Occupied Molecular Orbital(HOMO) level(SQ : -8.0eV, CR : -8.09eV). On the other hand, energy levels of Lowest Unoccupied Molecular Orbital(LUMO) of SQ and CR dyes are -4.09eV and -4.13eV respectively. Thus, replacement of five membered ring by four membered ring in SQ dye causes a large bathochromic shift.t.

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Alleviative Effects of Jujube Water Extract on the Inflammation and Barrier Damage in Hairless Mice Skin (Hairless 마우스에서 대추 열수추출물의 피부내 염증 및 장벽 손상 완화 효과)

  • Choi, So-Young;Kim, Young-Chul
    • Environmental Analysis Health and Toxicology
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    • v.24 no.4
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    • pp.351-357
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    • 2009
  • To investigate the alleviative effects of jujube water extract (JWE) on the inflammation and skin barrier damage, both the irradiation of UVB and the application of squalene monohydroperoxide (Sq-OOH) were applied to the back skin of experimental animals for 4 weeks. And at the same time experimental materials were applied topically. Six weeks female SKH-1 hairless mice were divided into five groups (five animals for each group) including normal (N; saline), control (C; UVB+Sq-OOH+saline), vehicle control (VC; UVB+Sq-OOH+vehicle), positive control (PC; UVB+Sq-OOH+0.01% retinoic acid) and experimental (E; UVB+Sq-OOH+JWE) groups. The skin erythema index in the E group was significantly low compared to the C group (p<0.05). Lipid (p<0.05) and water (p<0.01) capacities in the E group were significantly high compared to the C group. In comparison with the C group, E group showed a relatively well preserved lipid lamellae in the epidermis and a relatively much less infiltration of mast cells in the dermis or hypodermis. As for the both absolute and relative weights of the spleen, PC group were significantly higher than the other groups. These results suggest that JWE have a considerably inhibitory effect on the inflammation and the skin barrier damage induced by UVB irradiation and Sq-OOH application.

Emulsion using Biosurfactant as Emulsifier (Biosurfactant를 이용한 유화)

  • 홍세흠;한창규;조춘구
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.1
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    • pp.137-155
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    • 1999
  • The o/w emulsions were prepared by lysolecithin as a biosurfactantsto to emulsify oils with squalane(SQ), liquid paraffin(LP), octylpalmitate(OP), octylstearate(OS), alkyl benzoate(AB), isostearyl benzoate(ISB). The droplets size and shape of o/w emulsions were investigated by laser light scattering, With dynamic light scattering hydrodynamic radius(Rh) of emulsion droplets was varied from 150m to 250m and critical concentration of oil In which the hydrodynamic radius(Rh) of emulsion droplets decreased and increased was found in the point of 0.5wt% oil concentration, and it was found increasing the polarity of oil deccreased the droplets, the droplets size of SQ(polar oil) were lower than SQ(nonpolar oil) With static light scattering radius of gyration(R$_{g}$) of emulusion droplets was to be calculated. From measurements of the ratio of R$_{g}$R$_{h}$ it was found that the shape of droplet of ISB, AB(polar oils) were sphere, for OP, OS(apolar oil) were oblate, for LP, SQ(nonpolar oil) were rod. The viscosity of emulsion in the form of rod was higher than that of emulsion in the form of sphere.e.e.

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Inhibition Effects of Frankincense Oil on Skin Aging (II): Focussed on Histological Observation (프랑킨센스 오일의 피부노화 억제 효과 (II) - 조직학적 관찰을 중심으로 -)

  • Choi, Oi-Sook;Kwon, Mi-Hwa;Kong, Min-Kyu;Lee, Soon-Hee;Gang, Sung-Rye;Kim, Pil-Sun;Kim, Young-Chul
    • Environmental Analysis Health and Toxicology
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    • v.23 no.2
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    • pp.129-138
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    • 2008
  • The purpose of this study was to investigate the effects of frankincense oil in skin aging animal model. Skin aging was induced by both the irradiation of UVB and the application of squalene monohydroperoxide (Sq-OOH) to the back of experimental animals for 4 weeks. And at the same time experimental materials were applied topically. Six to seven weeks female SHR-1 hairless mice were divided into five groups including normal (N: saline), control (C: UVB+Sq-OOH+saline), vehicle control (VC: UVB+Sq-OOH+jojoba oil), positive control (PC: UVB+Sq-OOH+0.01% retinoic acid) and experimental (E: UVB+Sq-OOH+3% Frankincense oil) groups, five animals each group. Lipid lamella and lipid content in stratum corneum of the E group were almost intact with a regular arrangement which were similar to the N group. Collagen fibers in dermis of the E group were almost intact with a regular arrangement which were similar to the N group. Relatively much less number of mast cells and inflammatory cells were found in the E group compared to the C group. The activities of XO, SOD and CAT were no significant difference between the E and N groups. In conclusion, the application of frankincense oil to the skin aging animal model reduced both the generation of free radicals and the damage of skin tissues. Therefore, frankincense oil can be used practically for the prevention or improvement of skin aging in terms of health promotion and beauty for the people.

Inhibition Effects of Frankincense Oil on Skin Aging (I) : Focussed on Gross Examination (프랑킨센스 오일의 피부노화 억제 효과 (I) - 육안적 관찰을 중심으로 -)

  • Choi, Woi-Sook;Kwon, Mi-Hwa;Kim, Young-Chul
    • Environmental Analysis Health and Toxicology
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    • v.23 no.2
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    • pp.119-127
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    • 2008
  • The purpose of this study was to investigate the effects of frankincense oil in a skin aging animal model. Skin aging was induced by both the irradiation of UVB and the application of squalene monohydroperoxide (Sq-OOH) to the back of experimental animals for 4 weeks. And at the same time experimental materials were applied topically. Six to seven weeks female SHR-1 hairless mice were divided into five groups including normal (N: saline), control (C: UVB+Sq-OOH+saline), vehicle control (VC: UVB+Sq-OOH+jojoba oil), positive control (PC: UVB+Sq-OOH+0.01% retinoic acid) and experimental (E: UVB+Sq-OOH+3% Frankincense oil) groups, five animals each group. The skin erythema index for the PC and E groups were lower than that of the C group. Whereas, both the lipid and water capacities for the PC and E groups were higher than those of the C group. Wrinkles for the C group were formed as a pattern of deep furrows and thick crests. Whereas, wrinkles for the PC and E groups were formed as a pattern of shallow furrows and thin crests which were similar to that of the N group. As for the both absolute and relative weight of the spleen, the PC group were significantly higher than the other groups. In conclusion, frankincense oil can be used practically for the prevention or improvement of skin aging in terms of health promotion and beauty for the people.

Evaluating feed value of native Jeju bamboo (Sasa quelpaertensis Nakai) for beef cattle

  • Seul, Lee;Youl Chang, Baek;Mingyung, Lee;Seoyoung, Jeon;Han Tae, Bang;Seongwon, Seo
    • Animal Bioscience
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    • v.36 no.2
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    • pp.238-247
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    • 2023
  • Objective: Recently, indigenous Korean grass Sasa quelpaertensis Nakai (SQ) has garnered much interest as a roughage source for livestock to mitigate its adverse effects on habitat diversity. Thus, the objective of the present study was to evaluate the ruminal fermentation, palatability, and nutrient digestibility of SQ for Korean native beef cattle (Hanwoo) using in vitro rumen fermentation, in situ rumen degradability, and in vivo feeding trials. Methods: Using in vitro tests with rumen fluid as the inoculum for 48 h, ruminal fermentation of SQ was evaluated and compared with that of other roughage sources commonly used in Korea (i.e., rice straw, Timothy hay, and Italian ryegrass [IRG]). Additionally, an in situ trial 96 h was performed using three cannulated Hanwoo steers. Further, an in vivo trial was performed using eight Hanwoo steers to compare the palatability of SQ with rice straw in total mixed ration (TMR) and forage-concentrate separate feeding conditions. Finally, an in vivo digestibility trial of SQ fed as TMR of two particle sizes was performed with four Hanwoo steers. Results: In vitro and in situ trials revealed that SQ was comparable or superior to rice straw in terms of the ruminal fermentation characteristics of pH, gas production, total volatile fatty acid content, and effective ruminal dry matter digestibility (DMD), although its fermentability was lower than that of Timothy hay and IRG. In the palatability test, steers showed a greater preference for SQ when given as TMR. The total tract DMD of SQ fed as TMR was 75.9%±1.37%, and it did not differ by particle size. Conclusion: The feed value of SQ as a roughage source for Hanwoo steers is comparable or superior to that of rice straw, particularly when provided as TMR.

BLOCK LOSS DISTRIBUTION IN AN M/M/1 QUEUE WITH A CELL DISCARDING SCHEME

  • Lee, Gye-Min;Kwag, Min-Kon;Jeon, Jong-Woo;Kim, Chong-Kwon
    • Communications of the Korean Mathematical Society
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    • v.13 no.3
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    • pp.635-642
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    • 1998
  • When an integrated communication system is congested, we may reserve some spaces for non-realtime traffic by discarding a part of realtime traffic. That is sensible because realtime traffic is insensitive to a few losses. Several discarding schemes have been developed including Separate Queue (SQ). Under such schemes, the block loss distribution, i.e., the distribution of the number of losses within a given block which consists of successive data of a type, is important. We derive the block loss distribution of the SQ scheme and modifies the SQ scheme with a threshold.

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UV 처리에 의해 표면 산화 처리한 Silver Oxide 박막의 결정 변화에 따른 Nano Mechanics 특성 연구

  • Lee, Gyu-Yeong;Kim, Seong-Jun;Song, Ji-Eun;Kim, Su-In;Lee, Chang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.506-506
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    • 2013
  • Ag (Silver) 박막은 낮은 전기 저항과 높은 가시광대의 반사율을 가져 T-OLED (Top Emission-Organic Light Emitting Diode)의 Anode로 각광 받고 있지만, 일반적인 Ag 박막의 일함수는 4.3 eV 이하로 T-OLED의 Anode로 사용하기에는 낮은 단점이 있다. 따라서 이를 극복하기 위한 방법으로 Ag 박막 표면을 산화시켜 일함수를 증가시키기 위한 연구가 진행중에 있다. 하지만 연구는 단순히 일함수를 증가시키는 것에 한정되어 있을 뿐 UV 처리된 박막의 nano-mechanics 특성에 대한 연구는 현재 전무하다. 따라서 본 연구에서는 순도 99.9%의 Ag 타겟을 이용하여 rf magnetron sputter 장비를 통해 Ag 박막을 증착 하였고, 이후 UV (Ultra-Violet) 램프를 통해 시료 표면을 산화시켰다. 특히, 이 논문의 주요 관심사인 박막의 nano mechanics 특성 분석을 위하여 nano indenter와 SPM (Scanning Probe microscope) 장치를 활용 하였다. 실험 결과 후처리 시간이 3분 이하인 경우 박막이 비결정질의 silver oxide로 성장하는 것을 확인하였으며, 이때 박막의 면저항은 $0.16{\Omega}$/sq.에서 $0.55{\Omega}$/sq.로 증가하는 것을 관찰할 수 있었고, 3분 이후, 비결정질의 silver oxide가 conducting 특성을 갖는 silver oxide 결정을 이루면서 면저항이 $0.55{\Omega}$/sq.에서 $0.21{\Omega}$/sq.로 감소하는 것을 보았다. 또한 결정질의 박막이 자라는 3분이상의 박막에서 surface hardness는 급격하게 증가($3.57{\rightarrow}9.47$ GPa)했으며, 6분 이후에는 감소하는($9.47{\rightarrow}3.46$ GPa) 경향을 보였다. 이러한 경향은 silver oxide의 결정 크기가 Ag 결정 보다 크므로 상대적인 압축응력을 받아 표면 경도가 증가됐다. 처리시간 6분 이후, 경도 감소는 박막의 표면 물성이 불안정해졌기 때문이다.

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UV 처리에 의한 T-OLED용 산화전극에 적합한 Ag 박막 연구: Nano-Mechanical 특성 분석을 중심으로

  • Lee, Gyu-Yeong;Kim, Su-In;Kim, Ju-Yeong;Gwon, Gu-Eun;Gang, Yong-Uk;Son, Ji-Won;Jeon, Jin-Ung;Kim, Min-Cheol;Lee, Chang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.238-238
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    • 2012
  • Ag (silver)의 일함수는 T-OLED (Top Emission Organic Light Emitting Diode)의 전극소자로 사용하기에는 다소 낮다는 단점이 있다(~4.3 eV). 이러한 단점을 해결하기 위한 대안으로 Ag 박막의 표면을 플라즈마 처리, UV 처리 및 열처리를 통하여 일함수를 높이는 연구가 진행 되어왔다(>5.0 eV). 하지만 현재의 대부분 연구는 후 처리된 박막의 일함수에 초점을 맞춰 연구가 진행 되어 박막의 nano-mechanical property에 대한 연구는 매우 부족하다. 따라서 본 논문에서는 AgOx 박막의 nano-mechanical property에 초점을 맞춰 분석을 실시하였다. 연구에 사용된 샘플은 Ag 박막을 유리기판 위에 rf-magnetron sputter 장치를 이용하여 100 W의 power로 150 nm 두께로 증착하였다. 증착된 Ag 박막은 $O_3$ 발생 UV 램프를 이용하여, 다양한 시간동안 UV 처리하였다(0~9분). 증착된 샘플은 Four-point probe, nanoindenter 장비를 이용하여 nano-mechanical property를 분석하였다. 실험 결과 UV 처리 시간이 0, 1분에서 면저항이 0.16, 0.50 ${\Omega}$/sq로 급격한 변화가 나타났으나, 반면 3분 이후 9분의 샘플의 경우, 0.55 ${\Omega}$/sq에서 0.24, 0.20, 0.15 ${\Omega}$/sq로 감소하여 전기적 특성변화를 볼 수 있었다. 또한 nanoindenting 결과 UV 처리한 박막의 극 표면 경도 값의 변화는 0~5분 처리한 샘플의 경우, 물리적인 경도가 증가하는 형태를 보이며 UV 처리를 5분간 했을때 7.89 GPa로 최고의 경도를 가진다. 그 이후부터는 6.97, 3.46 GPa의 결과로 박막의 경도가 감소되는 결과를 얻었다. 이러한 결과로부터 Ag 박막의 후처리에 따른 Ag 물질의 산화 및 결정상태에 따라 박막 내에 존재하는 residual stress를 분석할 수 있다.

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The Study of Service Quality Model in O2O(Online-to-Offline) Context (O2O(Online-to-Offline) 환경에서의 서비스 품질요인 탐색에 관한 연구)

  • Moon, Yun-Ji
    • Management & Information Systems Review
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    • v.35 no.3
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    • pp.213-230
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    • 2016
  • In O2O environment(Online-to-Offline), providers attract new customers via web sites and lead them to pay online, then induce them again to offline when receiving products. Thus, online and offline channel is integrated and create synergy for marketing in O2O context. As online and offline channel coexist in O2O, consumers' perceptions for products and services that providers offer cannot help being different compared to an independent channel (i.e., either online or offline). Therefore, this research aims to develop the O2O service quality model(O2O-SQ model). Especially, O2O is the unique environment where offline, online, and mobile commerce are integrated so that the current paper suggests the $1^{st}$ O2O-SQ model by integrating the common factors of offline, online, and mobile service quality model through the previous literature review. Hence, this study conducts FGI(Focus Group Interview) for customers who have experienced in purchasing products in O2O commerce. Among integrated common service quality factors of $1^{st}$ O2O-SQ model, the current paper identifies the specific service quality factors that customers perceive significantly through FGI analysis. Moreover, after extracting the unique O2O-SQ factors with this qualitative analysis and integrating with the $1^{st}$ O2O-SQ model, the paper develops the final O2O-SQ model.

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