• Journal of the Korean Home Economics Association
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• v.39 no.4
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• pp.49-59
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• 2001

Natural red and yellow dyestuff was extracted from safflower (Carthamus tinctorius Linnaeus) by a new process of cellulase extraction compared with the conventional hot water extraction. Dyestuffs were extracted from safflower easily and repeatedly by means of cellulose as safflower cell wall destroyer. It means that new dyestuff extraction by cellulase improves not only yields of dyestuff from safflower successfully but also the rate of repetition of extraction. From the above experiments, the conclusions of this study were summarized as follows. 1. The optimum conditions of dyestuff extraction from safflower by general extraction method were that the solvent was the water of pH 6.0 on yellow dyestuff and 3% $K_2CO_3$ solution on red dyestuff, extraction temperature was $55^{\circ}C$, and extraction time was 30 min. 2. Among various cellulase, the NOVO cellulase was the best cell wall destroyer of safflower and finally produced the largest amount of dyestuff from safflower by cellulase extraction method. 3. The optimum conditions of dyestuff extraction by cellulase extraction method were conducted on 10 unit of cellulase per gram of safflower at $100m{\ell}$ water of pH 5.0 at $50^{\circ}C$ for 30 min.

• Journal of Fashion Business
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• v.13 no.2
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• pp.145-153
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• 2009

By introducing chitosan treatment prior to dyeing, examination was given to the effect of chitosan coated on the surface of fabrics on the color change of dyed fabric based on th e change of ${\Delta}E$, a*, and b* values. At the same time, the dyeing mechanism of Caesalpinia sappan dyestuff was predicted by the investigation of the change of air-permeability ac cording to the chitosan treatment. The change of elution was investigated by the examination of the elution of metallic ions employed as mordants after soaking dyed fabrics in the solution of alkaline perspiration ba sed upon the fact that chitosan carries excellent absorption ability toward metallic ions.

• Journal of Fashion Business
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• v.13 no.2
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• pp.136-144
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• 2009

The purpose of this study is to investigate various phenomena quantitatively occurring during the course of changing dyeing conditions of cotton and silk fibers in natural dyeing using Caesalpinia sappan. Paying attention to the fact that the color may be varied according to the extraction conditions of dyestuffs in Caesalpinia sappan dyeing, the color changes were investigated after dyeing using dyestuffs extracted at elevated temperature and dyestuffs extracted at room temperature. According to the extraction methods, the degree of color development for the category of red color and the category of yellow color has changed.

• Fashion & Textile Research Journal
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• v.8 no.4
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• pp.465-470
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• 2006

Walnut hull is a by-product from the Walnut tree, used as natural dyestuff from ancient times. This study was done to examine the effects of extractive conditions on the properties of walnut hull extracts for making efficient use of the walnut hull as a natural colorant. Aqueous extracts of walnut hull were prepared at various extractive concentration, temperature and time. Then they were characterized using UV-Vis. Spectrophotometer, FT-IR Spectrometer, Prep Liquid Chromatography, and Energy dispersive X-ray spectrometer. The aqueous extracts have two absorbency peaks of UV-Vis. Spectrum, shoulder type peak in the range of 270-280 nm and broad type band around 420 nm. Intensity of absorbency is increased with increase of extraction concentration and time. However, Boiling temperature extraction method showed the most efficiency of all. Intensity of absorbency is also affected by extraction pH. The Prep LC examined two kinds of isolated colorant with different molecular weight. FT-IR spectra of hull extracts showed an absorption band around $3400cm^{-1}$, the peaks at $1700-1600cm^{-1}$, which are characteristic of aromatic compounds with unsaturated ketone and benzene ring. It showed that the extraction contained some mineral ions, such as K, Ca, Si, Mg.

• The Research Journal of the Costume Culture
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• v.12 no.4
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• pp.579-590
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• 2004

This research was aimed to investigate and compare the effectiveness of TLC and GC-MS methods in the analysis of chromophoric substances extracted from madder plant. Alizarin and purpurin 0.3% solution were used as comparative standards; madder extraction was prepared by heating the solution of powdered madder at 80℃, pH 1.5, for 90 min. Best elution solvent for TLC in silica gel plate was toluene:ethyl acetate=9:1, which resulted in red and yellow spots from madder extraction each of which showed R/sub f/ values 0.32-0.43 and 0.07-0.11. Although the red spot in particular exhibited similar characteristics as standard purpurin in color, shape, and R/sub f/ values, the result was inconsistent throughout different TLC trials. GC-MS analysis showed only small amount of alizarin and no purpurin in the madder extraction. Other chromophoric substance such as 2-furancarboxaldehyde, 5-(hydroxymethyl)-, anthralin, and danthron were also detected in small amounts. The result indicated that TLC was less sensitive to detecting and identifying the natural dyestuff which is generally constituted with a number of similar but chemically different chromophoric substances.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.41 no.2
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• pp.40-46
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• 2009

The purpose of this study was to estimate natural dyeing properties of Korean traditional paper (Hanji). We dyed the Korean traditional paper with dyestuff which extracted from wood meal of Cotinus coggygria Scop (smoke tree) using hot-water, ethanol and $K_{2}CO_{3}$ solution. As mordants, 0.5% of $AlK(SO_4)_2$, $FeCl_2$, and $CuCH_3(COO)_2$ solution were used respectively. The color of dyed Hanji mainly depended on not the methods of extraction but the kinds of mordant. The dyed Hanji mordant with $AlK(SO_4)_2$ colored vivid yellow, $FeCl_2$ colored dark olive, and $CuCH_3(COO)_2$ colored brown and/or orange. The dyed Hanji with hot-water extractive had the highest K/S value and ethanol and $K_{2}CO_{3}$ solution extractives were followed. The K/S value of dyed Hanji mordant with $AlK(SO_4)_2$ was higher than that of $FeCl_2$ and $CuCH_3(COO)_2$. The dyeing effectiveness of after-mordanting method was superior to the others but sim-mordanting method was the worst.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.3
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• pp.57-65
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• 2016

Indigo (Polygonum tinctorium L.) is a typical blue dye which had been used from ancient times. This study was going to shade the complicated traditional methods extracting indigo dye by the fermentation and producing as adsorbate on calcium hydroxide, which says so called as the 'Indigo lime'. Accordingly we were going to make indigo through the hydrolysis of the hot water extractives of indigo leaves simply. During hot-water extraction, ${\beta}$-glucosidase which required hydrolysis of the linkage between indigo and glucose was not activated. To achieve this goal, indican was acid-hydrolyzed to glucose and indigo. The acetic acid, citric acid, hydrochloric acid, and sulfuric acid were used for the hydrolysis of hot water extractives. The hydrolysis conditions of extractives performed in water bath at $80^{\circ}C$ for 120 minutes and in an autoclave for 120 minutes. In the acid hydrolysis of extracted indican by hot water, the indican yields of acetic acid and hydrochloric acid hydrolysis were higher than sulfuric acid in water bath. Also, the indican yield of hydrochloric acid hydrolysis was better than sulfuric acid in autoclave. The hot water extracted indican was confirmed by HPLC analysis and its structure was confirmed by UV-Vis and FT-IR spectroscopy, compared with isolated indigo and commercial synthesized indigo. This improved extraction and hydrolysis methods can be replace the traditional indigo making method.