• 한국잠사곤충학회지
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• 제37권2호
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• pp.154-160
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• 1995

Silk/CDP 혼합사의 염색거동을 살펴보기 위하여 pH, 염색온도, 조제 등 염색조건을 변화시켜가면서 고찰한 결과 다음과 같은 결론을 얻었다. 1. 견섬유는 염욕의 pH가 증가함에 따라 일계 pH까지 염착량이 증가하는 경향을 나타냈으나 CDP 섬유는 pH에 따른 염착량의 변화가 거의 나타나지 않았다. 염색온도의 염착거동에 대한 영향은 염색온도가 증가하면 초기염착속도는 증가하는 반면 최종 염착량은 줄어드는 일반적인 경향을 나타내었다. 특히 CDP섬유의 경우 유리전이온도 이하에서도 염착속도가 상당히 느린 결과를 보였다. 2. Carrier를 사용하여 silk/CDP 혼합사를 염색하는 경우 염욕의 pH 및 염색온도에 따라 각 component에의 염료 흡착 및 탈착거동, 염착량 변화 등이 차이가 나는 것으로 나타났다. 또한 carrier가 없는 경우에는 CDP component에는 거의 염착이 이루어지지 않았다. 3. Silk/CDP 혼합사의 염색시에 나타나는 이염현상은 carrier의 존재하에서 CDP component의 구조 이완에 따라 염착능력이 증대되고 염욕의 평형이 깨어지면서 silk component의 탈착과 동시에 친화력이 큰 CDP component,쪽으로 염료이동이 일어나는 것으로 나타났다.

• 한국염색가공학회지
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• 제34권3호
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• pp.146-156
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• 2022

In this study, the dyeing properties of double knit fabric composed of PET/PTT bi-component fiber and quick dry fiber were examined with disperse dyes. In addition, the shrinkage characteristics were investigated during the dyeing process. The K/S values and shrinkage rate of PET/PTT bi-component fiber were higher than those of PET/co-PET bi-component fiber and quick dry fiber. In the dye bath, dye migration of exhausted on PET/PTT bi-component fiber to quick dry fiber was found at high dyeing temperature. It was not found that there was a significant difference in K/S value on dyeing temperature between 115℃ and 130℃. But the slight color difference of two sides of a double knit fabric was found.

• 한국염색가공학회지
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• 제11권2호
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• pp.46-54
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• 1999

The conventional dyeing of wool/cotton blends involves a two bath two step method, i.e., after dyeing of the wool component with acid dyes in an acidic dyebath at $100^\circ{C}$, the dyeing of the cotton component with reactive dyes in an alkaline dyebath is performed. In order to overcome the disadvantage of the conventional two bath two step dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in time, energy and water usage. To improve dyeing property of wool/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of wool/cationized cotton blends with acid dye/reactive dye by one bath two step method.

• 한국염색가공학회지
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• 제10권2호
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• pp.18-28
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• 1998

in order to overcome disadvantage of the conventional two bath dyeing method of polyester/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish sayings in time, energy and water usage. Also, when dyeing polyester/cotton blends by the one bath dyeing method, the high salt concentrations needed for the reactive dye can cause particles of disperse dye, used for the polyester component, to aggregate. A supplementary problem that can occasionally be happened is the change of hue that occurs on dyed polyester in an alkaline dyebath. To improve dyeing property of polyester/cotton blends, cotton component was pretreated with epichlolohydrine-trimethylamine hydrochloride in aqueous solution of sodium hydroxide to produce a cationized cotton that can be dyed under neutral conditions with reactive dye in a non-electrolytic or il little electrolytic dyebath. The one bath dyeing method of polyester/cationized cotton blends with disperse dye/reactive dye mixture resulted in a satisfactory dyeing property and color yield in comparison with ordinary two bath dyeing method.

• 한국의류산업학회지
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• 제11권4호
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• pp.672-677
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• 2009

To reduce the dependence of wool dyeing on the temperature several solvents with different properties and structures were added to the dye bath of C. I. Acid Yellow 42. Nearly the same total solubility parameters(${\delta}_t$) of solvents as those of wool fiber and hydrophobic part of the dyestuff were needed to increase disaggregation of dye molecules, loosening the wool fiber and wickabilty of dyeing solution; besides, the large surface tension(${\gamma}$) value of the solvents and the well balanced values of the three-component Hansen solubility parameters such as dispersion(${\delta}_d$), polar(${\delta}_p$), and hydrogen(${\delta}_h$) bonding parameters were required. Among the added solvents dimethyl phthalate(DMP) and acetophenone(AP) were satisfied with these conditions and worked the most successfully in the low temperature wool dyeing. Their effectiveness proven by the dyeing rate and the activation energy ($E_a$) of the dyeing was in the order of DMP > AP > DBE > CH > M >NONE. In conclusion the total solubility parameters(${\delta}_t$), the three-component Hansen parameters and the surface tension(${\gamma}$) of DMP and AP could be the guidelines to select suitable solvents for low temperature wool dyeing.

• 한국염색가공학회지
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• 제15권6호
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• pp.39-46
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• 2003

The experiments about dyeing concentration, temperature and time were done using yellow, red and purple loess as natural inorganic dyes in order to verify a degree of dyeing, characteristics of color and fastness. The results were as following; 1. As a result of analyzing components of loess, purple loess was much than other loess in quartz component and coarse particles contained. This affected to the degree of dyeing. 2. The stronger dyeing concentration was, the more the degree of dyeing was improved, and yellow loess containing fine particles was the best in the degree of dyeing. 3. When it was dyed with raising up to $100^\circ{C}$ for 10 minutes after stirring for 20 minutes at $60^\circ{C}$, was better than on starting at $40^\circ{C}$ or $80^\circ{C}$ in the degree of dyeing. Also yellow loess was the best in these experiments. 4. Washing fastness of loess was low such as other natural dyes, but dyeing wasn't transferred to other textiles. On the other hand, light fastness of it was very excellent and rubbing fastness was relatively good as 3~3.5.

• 한국의류산업학회지
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• 제3권2호
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• pp.168-173
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• 2001

In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

• 한국염색가공학회지
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• 제32권3호
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• pp.142-149
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• 2020

The purpose of this study was to investigate the dyeing properties of mugwort extract by nano-cellulose(n-cell). When dyeing cotton, rayon(artificial silk, called Ingyeon) and silk with mugwort extract, the difference with and without 2 wt% n-cell which it diluted to 0.6% treatment was compared. It was found that the addition of n-cell changed the values of L^∗, -a^∗(+red ~ -green), and b^∗(+yellow ~ -blue) of all scoured cotton, rayon and silk fabrics, compared to dyeing only mugwort extract. Furthermore, it was confirmed that the ΔE and the K/S value slightly increased in all of the dyed cotton, rayon, and silk fabrics treated with n-cell at the same time as dyeing compared to the untreated ones. Therefore, by treating the fabric with n-cell, a natural cellulose component, at the same time as dyeing, it is expected to maintain stable fastness, which is a disadvantage of dyeing using natural dyes, and contribute to the utilization and commercialization of other natural dyes.

• 한국염색가공학회지
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• 제19권1호
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• pp.1-11
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• 2007

Dyeing of polyester/cotton blends is usually carried out through the two-bath or one-bath two-step dyeing method using proper disperse dyes and reactive dyes for each fiber. However, the dyeing requires relatively long and complicated procedure as well as there are some problems such as lower dyeability. In the present study, new one-bath one-step dyeing process was investigated using disperse dyes having amino groups and hetero-bifunctional bridge compound(DBDCBS) including dichloro-s-triazinyl groups and ${\alpha},{\beta}$-dibromopropionylamido groups to improve the dyeability of cotton component in polyester/cotton blends. And the one-bath dyeing properties of polyester/cotton blends was evaluated by various dyeing conditions such as pH, temperature and dye concentration, The optimum dyeing condition was pH 4 and $110-120^{\circ}C$. Color fastness were relatively good because of the colvalent bond formation between DBDCBS-reacted cotton fiber and disperse dye.

• 한국산학기술학회논문지
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• 제19권4호
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• pp.525-531
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• 2018

본 연구는 우리나라 대표적인 전통 천연염색 기술인 풋감 염색의 단점인 뻣뻣한 촉감을 개선하고 천연자원을 효율적으로 활용하기 위하여 갈조류 감태와의 이성분 복합염료를 제조하여 염색성을 타진하고자 하였다. 풋감과 감태로 각 단일염료를 제조하고 단일염료 간의 혼합 비율을 달리한 동시 일욕염색을 실시한 결과, 전통 풋감 염색직물과의 색채의 차이가 허용 가능하고 염색 직물의 강연성이 가장 낮아져서 촉감의 개선이 기대되는 최적의 감태 혼합비율은 6%로 판단하였다. 이 혼합 비율로 풋감과 감태의 단일 염료를 혼합하여 열수추출과 필터링을 거쳐 동결건조시킨 이성분 복합염료를 제조하여, 염료의 입자 크기가 각 단일염료보다 미세하며, 풋감의 기능성 성분인 카테킨 함량이 유지됨을 확인하였다. 또한 이성분 복합염료로 염색한 면직물은 일욕염색 직물보다 전통 풋감 단일염색 직물과의 색차가 더 적어서 전통 풋감 염색과 시각적으로 차이가 없었으며, 강연성이 더 낮아져서 뻣뻣한 촉감이 완화되는 것으로 사료되었다. 따라서 풋감/감태의 이성분 복합염료는 풋감을 이용한 전통 천연염색 제품의 촉감을 개선할 뿐 아니라, 천연자원을 효율적으로 활용하는 데에 도움이 될 것으로 기대된다.