• 제목/요약/키워드: dye-sensitized

검색결과 652건 처리시간 0.037초

에너지 전환 소자용 $TiO_{2}/CNT$ 하이브리드 나노 섬유 전극 (Ti02/CNT Hybrid Nanofiber Electrode for Energy Conversion Devices)

  • 서재섭;김주용;진형준;강민성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.323-325
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    • 2007
  • $TiO_{2}$ electrode electrospun directly onto the substrate was developed for energy conversion device. To enhance energy conversion efficiency of dye-sensitized solar cell, electrodes should have higher surface area to absorb more dyes and higher conductivity to reduce recombination of generated electrons. $TiO_{2}$ nanofibers with higher surface areas were fabricated by annealing electrospun $TiO_{2}/PVP$ nanofibers at $500^{\circ}C$ for 3 hrs in air. it was revealed that $TiO_{2}$ nanofiber electrodes is hybrid with MWNT showed higher conductivity than $TiO_{2}$ semiconductor electrode possibly due to band gap change.

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A study on the development of DC-DC converter for low-power DSC

  • Park, Sung-Joon;Kim, Whi-Young
    • Journal of information and communication convergence engineering
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    • 제7권1호
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    • pp.52-56
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    • 2009
  • In this research, we have studied the development of dc-dc converter suitable for the driving of mobile instruments by using a dye-sensitized solar cell(DSC). We also have designed a interlocking circuit. The circuit makes power generation be saved in one battery and concurrently be discharged in the other battery. As this application, mobile devices such as MP3, cellular phone are operated by using power generator from DSC during the daytime and they can be operated by using the saving energy of the daytime during the night. Consequently, it has a simple and robust circuit configuration. Besides, we designed dc-dc converter circuit to drive low power instruments by using NMOS switch and PMOS rectifier. Operational modes are analysed, and then validity of the proposed interface circuit is verified through DCS.

Dye Sensitized Solar Cell using Polymer Electrolytes based on Poly(ethylene oxide) with an Ionic Liquid

  • Singh Pramod K.;Kim, Ki-Il;Rhee Hee-Woo
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.273-273
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    • 2006
  • The encapsulation of volatile organic electrolytes is a major challenge in practical applications of the DSSC. Ionic liquid (IL) within polymer electrolytes is an attractive candidate for replacement. Here we used a low viscosity ionic liquid 1-ethyl 3-methylimidazolium thiocyanate in order to modify ionic conductivity (${\sigma}$) of polymer electrolyte ($PEO:Kl/l_{2}$) and hence DSSC efficiency. The doping of IL enhanced ${\sigma}$ and attained maximum (${\sigma}=7.62{\times}10^{-4}S/cm$) at 80 wt% of IL concentration. Beyond this it was harder to get stable films. XRD confirmed that the intensity of the sharp PEO crystalline peaks decreased when IL was added. The DSC studies confirmed the reduction in crystallinity by adding ionic liquid.The efficiency of solar cell using aforesaid material was 0.6 % at 1 sun irradiation.

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Solar-hydrogen Production by a Monolithic Photovoltaic-electrolytic Cell

  • Jeon, Hyo Sang;Min, Byoung Koun
    • Journal of Electrochemical Science and Technology
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    • 제3권4호
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    • pp.149-153
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    • 2012
  • Among the various solar-hydrogen production techniques a combination of a photovoltaic (PV) and an electrolytic cell into one single system, a monolithic PV-electrolytic cell, has been suggested as a promising one in terms of efficiency and stability. In this mini-review, we describe our recent efforts on the fabrication of the monolithic PV-electrolytic cell. Particularly, we focus on the electrocatalysts for water oxidation and its fabrication method suitable for a monolithic PV-electrolytic cell. We also introduce proto-type devices with a dye-sensitized solar cell module and an InGaP/GaAs photoelectrodes.

염료감응형 태양전지용 상대전극 Pt의 AFM을 이용한 표면 연구 (AFM study of Pt as the Counter electrode for Dye-sensitized solar cell)

  • 김현주;이동윤;구보근;이원재;송재성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.695-698
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    • 2004
  • 최근 고유가 시대를 맞으면서 대체 에너지로서 무한자원인 태양빛을 이용하는 염료감응형 태양전지에 대한 관심이 급증하고 있으며, 이미 오래전부터 이에 대한 연구는 이루어져왔다. 한편, 염료감응형 태양전지를 구성하는 여러 분야 중 산화물 전극이나 전해질 또는 염료에 대한 연구는 많은 관심속에 진행되어오고 있는데 반해 상대전극에 대한 연구는 미비한 실정이다. 이에 본 연구에서는, 일반적으로 태양전지의 상대전극으로 사용되어오고 있는 Pt를 스퍼터링법 및 전기도금법을 이용하여 증착한 후 AFM을 통한 표면 형상 및 전기화학적 특성을 바탕으로 비교하여 태양전지의 상대전극으로서 적합한 제조 조건을 결정하였다.

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나노 클러스터 증착법을 이용한 ITO-CNT 복합체의 염료감응형 태양전지의 이용 (Indium tin oxide - Carbon nanotubes nano composite electrodes using by nano cluster deposition for dye sensitized solar cell applications)

  • 박종현;스리벤카타;정현준;윤순길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.69-69
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    • 2010
  • Carbon nano tubes (CNTs) have been attractive candidates for fundamental research studies due to their outstanding physical and chemical properties. High thermal and chemical stability and large surface area make CNTs an ideal platform for many nano materials systems. Several applications such as Several applications were proposed for CNTs many of which are concerned with conductive or high strength composites make them excellent candidates for a variety of energy conversion and storage technologies.

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산소와 UV 조사된 $TiO_2$ 광전극의 표면형상과 전기화학적 특성 (The morphology and Phtoelectrochemical properties of $TiO_2$ electrode with UV Treatment and Oxygen Injection)

  • ;;;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.240-240
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    • 2010
  • In this paper, in these case of photoelectrode using UV treatment after oxygen solar conversion efficiency is increased. According to oxygen injection UV treatment will removal residual organics and increase the TiO2 surface area but also UV treatment can affect the same chemical action of ozone treatment. More porous networks and larger porosities were obtained in the TiO2 films prepared UV treatment after oxygen injection.

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차단층에 따른 염료감응형 태양전지의 특성 (Characteristics of dye-sensitized solar cell by blocking layers)

  • 송양기;황문식;공대영;마재평
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2008년도 하계종합학술대회
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    • pp.381-382
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    • 2008
  • We investigated the properties of DSSC by $TiO_2$-blocking layer formed at several annealing temperatures. At $300^{\circ}C$ and $600^{\circ}C$ anatase and rutile phase of $TiO_2$ were formed, respectively. The characteristics of DSSC was improved by blocking layer annealed at $600^{\circ}C$.

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Highly Laminated Electrospun ZnO Nanofibrous Film on the Transparent Conducting Oxide for Photovoltaic Device

  • Kim, Jinsoo;Yoon, Sanghoon;Yoo, Jung-Keun;Kim, Jongsoon;Kim, Haegyeom;Kang, Kisuk
    • Journal of Electrochemical Science and Technology
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    • 제3권2호
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    • pp.68-71
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    • 2012
  • The electrospinning technique is a revolutionary template-catalyst-free method that can generate 1D nanostructure with the tunability and the potential for the mass production. This approach received a great deal of attention due to its ability to give direct pathways for electrical current and has been utilized in various electronic applications. However, the delamination of inorganic electrospun film has prevented the intense utilization due to the thermal expansion/contraction during the calcination. In this study, we propose an electrical grounding method for transparent conducting oxide and electrospun nanowires to enhance the adhesion after the calcination. Then, we examined the potential of the technique on ZnO based dye-sensitized solar cells.

N,N,N-Tris-[4-(Naphthalen-1-yl-phenylamino)Phenyl]-N,N,N-Triphenylbenzene-1,3,5-Triamine을 이용한 Hole Transporting 재료의 합성 (Synthesis and Characterisation of Hole Transporting Materials Based on N,N,N-Tris-[4-(Naphthalen-1-yl-phenylamino)Phenyl]-N,N,N-Triphenylbenzene-1,3,5-Triamine)

  • Mathew, Siji;Haridas, Karickal R.
    • 대한화학회지
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    • 제54권6호
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    • pp.717-722
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    • 2010
  • Two derivatives of star shaped compounds based on naphthylamine benzene고리에 methoxy기와 ethoxy기가 치환기로 연결되어있는 naphthylamine 관련 화합물을 합성하였다. 합성한 화합물의 전자 및 열적특성을 cyclic voltametry (CV) 및 differential scanning calorimetry (DSC)를 이용하여 조사하였다.