• Title/Summary/Keyword: dye uptake

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Natural Dyeing using the Colorants extracted from American Fleabane (Part II) - Dyeing properties on cotton - (개망초 추출물을 이용한 천연염색 (제2보) -면섬유에 대한 염색성-)

  • Shin Younsook;Cho Arang
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.12 s.138
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    • pp.1625-1631
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    • 2004
  • The purpose of this study was to investigate dyeing properties of cotton fabrics by American fleabane extract. Effect of dyeing condition on dye uptake and effect of mordanting on dye uptake, color change and colorfastness were explored. Its affinity to cotton fiber was considerably lower than wool, and its hydrogen bonding was involved in the absorption of American fleabane colorants to cotton fiber. K/S value of pre­mordanting was higher than sim-mordanting or post-mordanting. Except that Sn mordanted showed high K/S value, it did not significantly increase. American fleabane produced mainly yellowish color on mordants and mordanting method. Cotton fabrics showed generally high colorfastness except colorfastness to washing.

Study on the Dyeing Behavior of Palmatine, a Major Coloring Compound of Phellodendron Bark, on Cotton Fabric (황백 색소 팔마틴의 면직물에 대한 염색성 연구)

  • Li, Longchun;Narantuya, Lkhagva;Ahn, Cheunsoon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.39 no.4
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    • pp.601-612
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    • 2015
  • This research investigated the dyeing behavior of palmatine (a major coloring compound of Phellodendron bark in addition to berberine) using mercerization (M), tannic acid (T), mercerization-tannic acid (MT), and tannic acid -mercerization (TM) pretreatments. Mercerization was conducted using $20^{\circ}C$ of 20% NaOH for 5 minutes. Tannic acid treatment was conducted using 15% o.w.f. solution of tannic acid at $60^{\circ}C$ for 30 minutes and fixed with potassium antimonyl tartrate trihydrate. Dyeing was conducted using 1% o.w.f. palmatine chloride hydrate with 1:100 liquor ratio at $10-95^{\circ}C$ for 10-60 minutes in a dyebath of pH 3-9. MT method resulted in the highest dye uptake and was two times higher than the average dye uptake of T method. MT method provided the best result when the dyeing temperature was $80^{\circ}C$ or $95^{\circ}C$ and the dyeing time was 60 minutes. The pH of the dyebath had less effect on the dye uptake but a pH higher than 5 provided better results. The study confirmed that palmatine is a major coloring compound of Phellodendron bark and that the MT method can be used as a successful cotton dyeing method.

The Effects of the Pre-treatments with Proteins on Dyeing of Silk Fabric with Caesalpinia sappan (견직물의 소목염색에서 단백질 전처리 효과)

  • Hwang, So Hee;Jang, Jeong Dae
    • Textile Coloration and Finishing
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    • v.28 no.3
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    • pp.208-218
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    • 2016
  • This study investigated the effects of the working mechanisms of proteins, mordants, and dyes, as well as the mordanting order, on dye uptake by silk fabric pre-treated with proteins and dyed with freeze-dried sappan wood water extract. Soybean protein and sodium caseinate were used as the proteins. 1. When Al mordants were not used, the dyeability of the fabrics increased upon protein pre-treatment as compared to the case without treatment. 2. Dyeing with protein pre-treatment, followed by mordanting, led to the highest dye uptake, and the optimal protein concentration was 5%. 3. The K/S values slightly decreased with an increase in the dyeing temperature, and the fabric turned dark red in color when dyeing was carried out at increasing temperature. Fabrics showed the highest dye uptake at $40^{\circ}C$. 4. Regarding the effect of time, the K/S values of the fabrics with and without protein treatment showed almost no increase after the initial dyeing time of 10min; further, there was hardly any difference in the cases with and without protein pre-treatment. 5. In case of protein pre-treatment fabrics, the washing fastness was level 2. The dry cleaning fastness showed very excellent result with level 4-5. The rubbing fastness was better in dry rubbing than in wet rubbing of the fabrics. For the light fastness, all dyed fabrics showed low fastness.

Dyeing Properties of the Fabrics Dyed with Pine Needles Extract (솔잎 추출물의 염색성 및 염색 견뢰도)

  • Joen, Mi-Sun;Park, Myung-Ja
    • The Research Journal of the Costume Culture
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    • v.17 no.6
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    • pp.1129-1140
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    • 2009
  • The pine needles has been used as medicines and it is using as dyeing as well as food. It is distributed through 50% in Korean forest. The pine needles is related to antimicrobial activity, however, dyeing properties of the extract components and effects of them are not well known yet. To examine dyeing properties of the pine needles extract, various fabrics(nylon, silk, wool, and soybean) were dyed under different dyeing conditions, and mordanted with one of five mordants(Al, Sn, Fe, Cr, and Cu). Dye uptake, Colors and Colorfastness of the dyed fabrics were measured. By the K/S values, dye uptake of all the dyed fabrics enhanced as increasing dyeing temperature and dyeing time. The highest K/S values were obtained from the protein fiber(wool and silk) fabrics dyed with water extract at $100^{\circ}C$, and with ethanol extract at $90^{\circ}C$ for 80 minutes. Colors of the dyed fabrics showed variety of yellow, brown and green colors. Colors changed by using Cu, Fe and Cr mordants: Cr-mordanted fabrics into light green, Fe-mordanted fabrics into reddish brown, and Cu-mordanted fabrics into deep green in ethanol extraction. Dry-cleaning fastness of the dyed fabrics presented good to excellent except wool fabrics dyed with ethanol extract. Washing fastness of the dyed nylon and soybean fabrics were good to excellent but wool and silk fabrics showed average grades. Most dyed fabrics were poor to light fastness.

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Natural Indigo Dyeing of Hanji Fabric using Baker's Yeast: Effect of Yeast Concentration and Repeat Dyeing (효모를 사용한 한지직물의 천연인디고 염색 : 효모농도와 반복염색 효과)

  • Son, Kyunghee;Shin, Younsook;Yoo, Dong Il
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.191-201
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    • 2021
  • In this study, an eco-friendly indigo reduction system(scale up reduction, use of buffer solution, and pH control) using baker's yeast(Saccharomyces cerevisiae) was applied for natural indigo(Polygonum tinctorium) dyeing of Hanji fabric and Hanji-mixture fabric(Hanji/Cotton, Hanji/Silk). The effect of concentration of baker's yeast, repeat dyeing, and bath reuse was investigated in terms of dye uptake indicating reduction power. And the oxidation-reduction potential(ORP) was monitored. We also evaluated color properties and colorfastness according to the color strength. The yeast concentration did not significantly affect the maximum reduction power. However, the highest yeast concentration was effective in improving the initial dye uptake, and its the reduction retention power was the most excellent. Even on the last reduction day, the effect of increasing the dye uptake by repeat dyeing was observed. And it was confirmed that the reduction bath could be reused for up to 30 days by supplementing yeast at the end of reduction. For all the fabrics used, deeper and darker PB color were obtained by repeat dyeing. As dyeing was repeated, purplish tint got stronger on the Hanji/Silk fabric compared to other fabrics. Regardless of the composition of Hanji fabrics and color strength, washing and dry cleaning fastness were relatively good with above rating 4-5, and fastness to rubbing and light were acceptable with a rating 3-4 ~ 4-5. The eco-friendly natural indigo dyeing process using niram and baker's yeast would offer global marketability and diversity of Hanji product as a sustainable high value-added material.

Relation between Chemical Structure of Yellow Disperse Dyes and Their Lightfastness

  • Kim, Sung-Dong;Park, Eun-Jin
    • Fibers and Polymers
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    • v.2 no.3
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    • pp.159-163
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    • 2001
  • Five yellow disperse dyes were synthesized and their dyeing, fastness and photodegradation behaviors were investigated. It was found that dyes derived from phenylindole and N-alkylaminobenzene showed dye uptake directly proportional to the dye concentration, but the build-up of dyes derived from carbazole and pyridone were not good. The wavelength at maximum absorption. molar extinction coefficient. and the tendency to the photodegradation were strongly dependent on the electron donating ability of the coupling component. The dye, whose coupling component was phenylindole, possessed the excellent dyeing properties and the high degree of lightfastness. UVA had an effect on the inhibition of the photodegradation especially for the easily photodegradabte dyes.

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The Preparation and Dyeing Properties of Modified Polypropylene (개질 PP섬유의 제조 및 염색성)

  • 손태원;김삼수;이남순
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.405-412
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    • 2001
  • In order to impart dyeability on to Polypropylene fiber, PP/EVA blend in the form of fibers and film were preparared using melt blending process. Ethylene vinylacetate containing 28wt% of vinylacetate(EVA(28)) was used as a copolymer. In the study of mechanical properties, tenacity and initial modulus decreased with Increasing EVA concentrations, whilst extension at break increased with increasing EVA contents. Their results in the dyeing behavior show that dye adsorption increased with increased EVA contents iota both blend fibers and films. The extent of dye uptake of red dye to modified polypropylene fibers was greater than that of Blue and Yellow counterparts due to the difference behavior of dye particles in dyeing bath.

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The Preparation and Dyeing Properties of Modified Polypropylene (개질 PP섬유의 제조 및 염색성)

  • Son, Tae Won;Kim, Sam Su;Lee, Nam Sun
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.47-47
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    • 2001
  • In order to impart dyeablility on to Polypropylene fiber, PP/EVA blend in the form of fibers and film were preparared using melt blending process. Ethylene vinylacetate containing 28wt% of vinylacetate(EVA(28)) was used as a copolymer. In the study of mechanical properties, tenacity and initial modulus decreased with increasing EVA concentrations, whilst extension at break increased with increasing EVA contents. Their results in the dyeing behavior show that dye adsorption increased with increased EVA contents for both blend fibers and films. The extent of dye uptake of red dye to modified polypropylene fibers was greater than that of Blue and Yellow counterparts due to the difference behavior of dye particles in dyeing bath.

Adsorption Kinetic Study of Ruthenium Complex Dyes onto TiO2 Anodes for Dye-sensitized Solar Cells (DSSCs) (염료감응 태양전지용 루테늄 금속착체 염료의 이산화티타늄 전극에 대한 동적 흡착 연구)

  • An, Byeong-Kwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.11
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    • pp.929-934
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    • 2011
  • The adsorption kinetic study of ruthenium complex, N3, onto nanoporous titanium dioxide ($TiO_2$) photoanodes has been carried out by measuring dye uptake in-situ. Three simplified kinetic models including a pseudo first-order equation, pseudo second-order equation and intraparticle diffusion equation were chosen to follow the adsorption process. Kinetic parameters, rate constant, equilibrium adsorption capacities and related coefficient coefficients for each kinetic model were calculated and discussed. It was shown that the adsorption kinetics of N3 dye molecules onto porous $TiO_2$ obeys pseudo second-order kinetics with chemisorption being the rate determining step. Additionally the heterogeneous surface and the pore size distribution of porous $TiO_2$ adsorbents were also discussed.

A study on the mordanting and dyeing properties of Rhusjara ica Dye (오배자의 염색성에 관한 연구)

  • 주영주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.8
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    • pp.971-977
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    • 1998
  • For the purpose of standardization and practicability of nautral dyeing, the mordanting and dyeing properties of Rhusjara ica was studied. Appropriate extraction, dyeing and mordanting condition of Rhusjara ica were determined, and the effect of mordanting method on dye uptake and color fastness of dyed fabric was investigated. The most absorbance of Rhusjara ica solution was 299 nm. The color of Rhusjara ica solution was affected by pH 8~9. The optimum temperature to extract Rhusjara ica was 6$0^{\circ}C$ and dyeing solution for 1 hour. Effective dyeing time to silk was 60min. Effective mordanting temperature was 80~10$0^{\circ}C$, and its time was 30 min. K/S value of dyeing fabrics was recoginazed by mordanting treatment, specially Fe, Al, Cu. K/S value of pre-mordanting was higher than post-mordanting. In the case of Rhusjara ica fastness was increased by mordanting treatment.

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