• Title/Summary/Keyword: dye addition

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Studies on the Interaction of Edible Dyes with Protein (II). The effects of drug additions on protein binding of edible dyes

  • Kim, Bak-Kwang;Lah, Woon-Lyong;Jang, Seong-Ki;Lim, Bang-Ho;Jang, Jae-Yeon;Lee, Wang-Kyu
    • Archives of Pharmacal Research
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    • v.10 no.1
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    • pp.29-35
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    • 1987
  • The effect of drug addition on the bovine serum albumin (BSA)-edible dye complex was studied by spectrophotometric method. The edible dyes tested were amranth, erythrosine, tatrazine and sunset yellow. The moles of bound dye per protein mole and free energies for edible dyes bounded were determined at pH 7.4. The values of free energy change by the addition of drughs to BSA-edible dye were ranged fro -6, 260 to 08030 cal/mole. In the wide range of edible dye concentration (0.3-$7{\times}10^{-5}$$^{-5}$ M), acetylsalicylic acid (ASA) showed pattern of displacement different from that of dye. It was assumed that ASA has different binding mechanisms from edible dye.

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Dye Adsorption Ability of Chitin in Reactive Dyebath (반응염료염액에서의 키틴의 염료흡착성능)

  • 유혜자;김정희;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.2
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    • pp.349-354
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    • 2002
  • In order to decolorize the reactive dye wastewater, we investigated the dye-adsorption ability of chitin, which was natural polymer obtained from shrimp shell. Chitin particle(less than 250 ${\mu}{\textrm}{m}$n) was prepared from shrimp shells in the processes of decalcification in aqueous hydrochloric acid solution and deproteination in aqueous sodium hydroxide solution. The particle size of chitin was controlled to less than 250 ${\mu}{\textrm}{m}$. Three tripes of the reactive dyes-C.I. Reactive Red 120, C.I. Reactive red 241 and C.I. Reactive Black 5-were used. Dye adsorption ability of chitin was investigated by dipping the particle in the dyebaths of concentration of 0.0l%, 0.03% and 0.05% for various periods of time(1,3,5, 10,20,40,80,160minutes). The influence of addition of salt(Na$_2$SO$_4$) and alkali to the dyebaths on dye-absorption was also investigated. We obtained the following results fur the dye-absolution ability of chitin in the dyebaths of three types of reactive dyes. 1) The amount of dye uptake by chitin was increased by addition of salt to the dyebaths. 2) As the concentration of alkali became higher than 3g/I, the amount of dye uptake by chitin was increased. Chitin showed good dye-adsorption ability, when the alkali concentration was high. 3) Chitin showed equal dye uptake in the three types of dyebaths when the dye concentration was 0.0l%. Over 90% of dyestuffs was adsorbed from the dyebaths in ten minutes. When the dye concentration was higher, better adsorption ability was showed in a dye bath of Reactive black 5 than in the others. When the dye concentration was 0.03%, 90% of Reactive red 120 and Reactive red 241 was adsorbed in 40 minutes and the same of Reactive black 5 in 10 minutes. When the dye concentration was 0.05%, 9()% of Reactive red 120 was adsorbed in 80 minutes, and Reactive black 5 in to minutes.

Dyeability and Functionality of Chaenomelis Fructus Extract (모과 추출물의 염색성과 기능성)

  • Nam, Ki-Yeon;Lee, Jung-Soon
    • Fashion & Textile Research Journal
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    • v.14 no.3
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    • pp.478-485
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    • 2012
  • The dying properties of fabrics with Chaenomelis Fructus extract were studied through an investigation of the characteristic of Chaenomelis Fructus colorants, the effect of dyeing conditions (dye temperature, dyeing concentration, and times on dye uptakes), effect of mordant, effect of UV irradiation, and color change in addition, antimicrobial ability and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of maximum absorption of Chaenomelis Fructus extract was 280 nm and showed that tannin is the major pigment component. From the increase of absorbance by UV irradiation, it was assumed that catechol tannin color was developed through UV irradiation. An increased dyeing concentration resulted in a larger dye uptake. Dye uptake increased as the dyeing time and temperature increased. Chaenomelis Fructus extract showed relatively good affinity to silk than cotton. Mordant, Fe and Cu were effective to increase the dye uptake of cotton fabric in addition, the dye uptake of silk fabric mordanted with Fe and K improved. UV irradiation let the color of dyed fabrics develop regardless of the UV irradiation stage however, UV irradiation on the dyed fabric was more effective than on the extract for the color development. Dyed silk fabric showed very good antimicrobial abilities of 99.9% in addition, deodorant ability improved in the fabric dyed with Chaenomelis Fructus extract.

Blue Electroluminescent Properties of ZnS:Cu and Dependence of Dye Addition (ZnS:Cu의 청색 전계 발광 특성과 안료 혼합 의존성)

  • Lee, Jong-Chan;Park, Dae-Hui
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.1
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    • pp.1-4
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    • 2002
  • To obtain the blue emission of powder electroluminescent device, the emission properties of ZnS:Cu were estimated by the variation of applied frequency and the addition of dye to ZnS:Cu phosphor. The variation of applied frequency was from 400 to 4kHz and the addition ratio of dye was from 0 to 5 weight percent respectively. The increment of applied frequency made that emission peaks were shifted from 500.5nm and 460nm at 400Hz to 490nm and 450nm at 4kHz. CIE coordinate system was shifted from x=0.1647, y=0.3711 at 400Hz to x=0.1543, y=0.1856 at 4kHz. On the basis of applied voltage 100V, 400Hz, the increment of addition ratio of dye also made that emission peak was shifted from 505nm(0wt%) to 490nm(5wt%) and the CIE coordinate system was shifted from x=0.1647, y=0.3711(0wt%) to x=0.1334, y=0.2363 (5wt%). The brightness was increased from 60 cd/$m^2$(400Hz) to 174 cd/$m^2$(4kHz) with increment of frequency. When the addition ratio of dye was above 1wt%, the brightness was decreased below 42% of initial brightness and changed from 60 cd/$m^2$(0wt%) to 20.84 cd/$m^2$(5wt%).

Fluorescence Quenching Causes Systematic Dye Bias in Microarray Experiments Using Cyanine Dye

  • Jeon, Ho-Sang;Choi, Sang-Dun
    • Genomics & Informatics
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    • v.5 no.3
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    • pp.113-117
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    • 2007
  • The development of microarray technology has facilitated the understanding of gene expression profiles. Despite its convenience, the cause of dye-bias that confounds data interpretation in dual-color DNA microarray experiments is not well known. In order to economize time and money, it is necessary to identify the cause of dye bias, since designing dye-swaps to reduce the dye-specific bias tends to be very expensive. Hence, we sought to determine the reliable cause of systematic dye bias after treating murine macrophage RAW 264.7 cells with 2-keto-3-deoxyoctonate (KDO), interferon-beta $(IFN-{\beta})$, and 8-bromoadenosine (8-BR). To find the cause of systematic dye bias from the point of view of fluorescence quenching, we examined the correlation between systematic dye bias and the proportion of each nucleotide in mRNA and oligonucleotide probe sequence. Cy3-dye bias was highly correlated with the proportion of adenines. Our results support the fact that systematic dye bias is affected by fluorescence quenching of each feature. In addition, we also found that the strength of fluorescence quenching is based on not only dye-dye interactions but also dye-nucleotide interactions as well.

The Effects of Agents in Padding Liquor on the Resist-discharge Printing of Cotton Fabrics with Reactive/Reactive Dyes (반응염료/반응염료에 의한 면직물 방발염시 패딩액 조제의 영향)

  • 김형우;박건용;박병기;김진우
    • Textile Coloration and Finishing
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    • v.7 no.3
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    • pp.22-30
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    • 1995
  • The effects of agents in padding liquor on the fixation of vinylsulfonyl reactive dye of ground color and on the resist-dischargeability in resist-discharge printing of cotton fabrics with reactive/reactive dyes were investigated. Alkalis, such as sodium bicarbonate, sodium carbonate, sodium acetate and trichloro sodium acetate, were used to fix the dye for ground color on cotton fabrics. Sodium bicarbonate and sodium carbonate showed a good fixation of the dye for ground color, but they were ineffective to the white and the colored resistdsichargeabilities, which were caused by the fast fixation of the dye for ground color before its reaction with resist agent in printing paste. Therefore these are not suitable for the agent to fix the dyes for ground color because they deteriorate the resist-dischargeability. In case of sodium acetate, as the fixation yield of the dye for ground color was remarkably low. and the white resistdischargeability was not good, it had better not be used for the agent to fix the dye for ground color. However, the addition of sodium trichloroacetate to padding liquor gave a very good fixation yield of ground color, and showed an excellent resist-dischargeability. The effects of acetic acid in padding liquor on the fixation of the dye for ground color and on the resist-dischargeability were studied in case of immediate printing of resist-discharge pastes after padding and drying and in cases of printing after 1∼3 day-storage of padded goods. By the addition of 2% of 48% acetic acid aqueous solution to padding liquor, the white and the colored resist-dischargeabilities were improved and the fixation of the dye for ground color was good without any troubles. Especially, when the padded goods were stored for 2 or 3 days and printed with resist-discharge printing pastes, its addition was very effective on the resist-dischargeability.

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Studies of Low Temperature Dyeing on Silk Fiber II. Low Temperature Dyeing of Silk Fiber with the Complex Dye (견의 저온염색에 관한 연구 II. 산성 Metal Complex 염료에 있어서의 저온염색)

  • 배도규;배현석
    • Journal of Sericultural and Entomological Science
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    • v.35 no.1
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    • pp.48-51
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    • 1993
  • Using the new type auxiliary(K-1), dyeing experiment was done at the various dyeing conditions and the effects of auxiliary on the dyeing properties of metal complex dye for the silk fiber were dicussed. The exhaust rate was higher in the auxiliary 3% o.w.f. addition than sodium sulfate 50% o.w.f. The decreasing ratio of exhaust rate according to dye concentration increasing was lower at auxiliary addition than auxiliary non-addition. The exhaust rate according to increasing dyeing temperature was higher in the auxiliary addition than non-addition.

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The Effect of Acetophenone on the Dyeing of Silk (견섬유의 염색에 있어서 아세토페논의 영향)

  • 김태경;임용진;박태수
    • Textile Coloration and Finishing
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    • v.10 no.5
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    • pp.56-62
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    • 1998
  • In the prior study, the dyeing behaviors of Milling Cyanine 5R on silk fiber in aqueous dyeing liquor including small amount of organic compounds were investigated. The most effective compound was acetophenone which increased dye uptake as well as dyeing rate. In this study, the role of the acetophenone in dyeing of silk with Milling Cyanine 5R was studied. By addition of acetophenone into the dye solution, the molar absorptivity of Milling Cyanine 5R increased, and the wavelength of maximum absorption was shifted to longer wavelength, namely bathochromic shifted. This shows that the acetophenone prevents the dye to aggregate, and increases the number of monomeric dye molecule relative to the dye solution without acetophenone. This fact was also confirmed by the increase of the permeation rate of the dye through cellulose semipermeable membrane from the dye solution including the acetophenone. From these results, the acetophenone acts as a prohibitor of dye aggregation, increases the number of monomeric dye molecules even at relatively low temperature, and makes the dyes penetrate into the fiber easier.

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Coloration behaviors of phthalocyanine reactive dye on nylon substrates: experiments, empirical modeling and statistical analysis

  • Kim, Byung-Soon;Ravikumar, K.;Yoon, Seok-Han;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.14-23
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    • 2007
  • This research article explores the use of phthalocyanine reactive dye on nylon substrate. The effect of factors such as pH, temperature, liquor ratio and alkali addition on level of dye exhaustion, fixation and total fixation efficiency. Low pH, high temperature and low liquor ratio were found to be suitable conditions for maximum % exhaustion values. The effect of sulphatoethylsulphone(SES) and vinylsulphone(VS) form of the dyes on level of dye fixation was also discussed. The optimized exhaustion (%E), fixation(%F) and total fixation efficiency were determined. Modification of the dyeing process with alkali addition displayed that dye fixation(%) increased by alkali addition. Vinylsulphone(VS) moiety of the dye was found to be superior to. maximum fixation (%F). Appropriate predictable empirical models, relatively a new approach in dyeing processes, were developed incorporating interactions effects of temperature, pH and liquor ratio for predicting % exhaustion, fixation and total fixation efficiency. The significance of the mathematical model developed was ascertained using microsoft excel regression(solver) analysis module. High correlation coefficient was obtained (R2=0.9895 for % exhaustion, R2=0.9932 for fixation, R2=0.9965 for total fixation efficiency) for the model which shows prominent prediction capacity of the model for my conditions. The predictable polynomial equations developed from tile experimental results were thoroughly analyzed by ANOVA (Analysis of Variance) statistical concepts.

Modification of Tencel Fabric Treated with Chitosan( II ) - Change of Dyeing Properties - (키토산처리에 의한 텐셀 직물의 개질기능화(II) - 염색성의 변화 -)

  • 육은영;배현숙
    • Textile Coloration and Finishing
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    • v.14 no.3
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    • pp.1-10
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    • 2002
  • Tencel fabric cationized with chitosan can be effectively dyed with anionic dyes. To investigate the change of dyeing properties of cationized Tencel fabric, some experiments were performed under the several dyeing conditions with acid and reactive dyes. Whiteness index decreased with the increment of crosslinking agent concentration. The cationized Tencel fabric was dyed well by anionic dye such as acid dye, the dyeability of reactive dye was improved by addition of a little salt without alkali. The dye fixation on the cationized Tencel fabric was increased with chitosan concentration without electrolyte and alkali. The dyeability of Tencel treated with chitosan was better than controlled Tencel, especially under the acidic conditions. According to the number and the types of functional group of reactive dyes, dye affinity of the modified Tencel fabric varied and wash fastness of acid dye was better than reactive dye.