Dissolution rate of minerals may differ from climates configuration, but weathering rate of feldspars is generally proved to be relatively higher The result of geochemical reaction modeling indicates the acid water of pH 4.5 excluding any other variables, was 2.3 times higher than that in ordinary rain of pH 5.7. This result proved that pH is very important factor in preservation of granite cultural properties. To prevent the weathering of stone cultural properties, weathering characteristics of stones should be studied first and constitution of dry environments, using water repellent or oil coating, isolating water which cause chemical weathering reaction like hydration and oxidization should be considered. Considering the long-term reactions between granite and rain, selection of materials, which can bring neutralization and non-oxidization conditions, are very important in using cleaning agents and biological controls.
The objective of this study is to investigate the efficacy of leaf powder colorants as substitutes for traditional fresh juice extract dyeing. Three kinds of leaf powder colorants were prepared by freeze drying method with or without deep freezing as pre-treatment: one powder colorant from fresh leaf juice with deep freezing; two kinds of powder colorant from fresh leaves with and without deep freezing. Their dyeing properties and storage stabilities were studied and compared with the traditional fresh juice extract dyeing. The presence of indigo in the powder colorants was confirmed by UV/Visible absorption spectra. They showed absorption peak at 602nm which was same with indigo absorption peak. Dyeing was done at low temperature around 6$^{\circ}C$. All three powder colorants produced B colors on silk fabrics, showing similar color to the one dyed traditionally with fresh juice extract. The powder colorants from leaves gave higher color strength than the powder from leaf juice. The powder colorant prepared from leaves with deep freezing was the most stable for long term storage as its color and color strength were not changed after 360 days. So, this was used for further dyeing to study the effects of concentration and repeat dyeing on color strength and colorfastness. Fastnesses to dry cleaning and rubbing were fairly good above 4 rating. Further study is needed to improve light fastness. It was concluded that the leaf powder colorant with deep freezing could be used as a substitute for traditional juice extract dyeing at all seasons.
Journal of the Korean Society of Clothing and Textiles
/
v.35
no.2
/
pp.218-229
/
2011
Dyeing properties of cotton and ramie fabrics with pine needles colorants were studied by investigating the analysis of pine needles colorants, the effect of dyeing conditions (such as dye concentration, dyeing temperatures and times on dye uptakes), effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use; in addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of the maximum absorption for pine needles extract was 285nm, and pine needles colorants produced a yellow color. From FT-IR and GC-MS results, it was assumed that chromophoric substance from pine needles extracts were mixed with flavonol tannin and flavanol tannin. An increased dyeing concentration resulted in a larger dye uptake and a Freundlich absorption isotherm was obtained. A larger dye uptake occurred as the dyeing time and temperature increased. Post-mordanting was more effective than pre-mordanting and the dye uptake of fabrics improved by mordanting. The colorfastness of dyed fabrics showed a low rating; however, colorfastness to washing and dry cleaning of cotton fabrics mordanted with N.Cu, and friction fastness of ramie fabric mordanted with Cu improved. The dyed fabrics showed very good antimicrobial abilities of 99.9%. In addition, the ultraviolet-cut ability and deodorant ability improved in fabrics dyed with pine needles extracts.
The objective of this study is to investigate the efficacy of leaf powder colorants as substitutes for traditional indigo dyeing. Leaf powder colorants were prepared by hot air($50^{\circ}C$) and room temperanrre($25^{\circ}C$) drying methods from fresh leaves. The presence of indigo in the leaf powder colorants was confirmed by UV/Visible absorption spectra. All the powder colorants showed broad absorption at 602 nm as same as synthetic indigo. Dyeing was done by reduction method with sodium hydrosulfite and sodium hydroxide. Leaf powder colorants produced blue color on silk fabrics, showing similar color to the one dyed traditionally with fresh juice extract. The powder colorants prepared at room temperature drying were more stable for long term storage than that prepared by hot air drying. Thus, the powder colorants prepared by room temperature drying was reduced and dyed in one-step process without sodium hydroxide in the dyebath for further investigate dyeing properties. K/S value of the fabric dyed without sodium hydroxide was much higher than one dyed with sodium hydroxide. Regardless of the addition of sodium hydroxide, rubbing fastness was fairly good showing above 4 rating. Fastness to dry cleaning and light of the fabrics dyed without sodium hydroxide were mote higher than that dyed in alkaline condition.
Proceedings of the Safety Management and Science Conference
/
2013.04a
/
pp.19-29
/
2013
Slips and falls are associated with many occupational injuries in Korea. It is also estimated that slipping are major contributors to slip, trip and fall injury burden. So "LOCAL RULE ON OCCUPATIONAL SAFETY AND HEALTH STANDAR D" must be improved, especially article 3(prevention of slip, trip and fall). The primary purpose of the present study is to determine if, and to what extent, the standard could be improved in present environment. In order to fulfill our objective, the another regulation in Korea and foreign countries were investigated and reviewed. Many kind of standard, mandatory documents and guideline were also reviewed. And then, regulations, standard, guideline etc. reviewed were compared with each others. The article 3 was revised as below. 1. The floors of the traffic route in workplace shall have no hole or slope, or be uneven or slippery so as, in each case, to expose employees to slip, trip and fall risk, except if adequate measures have been taken to prevent a employees falling. 2. The employer shall design, install and fix the drain for effective drainage if fluid contaminants were frequently occurred. So far as is reasonably practicable, An employer shall keep the workplace clean, sanitary, and dry so that employees won't have any risk to tripping or slipping at the workplace. 3. To facilitate cleaning, every floor, workplace, and passageway shall be, so far as is reasonably practicable, kept free from protruding objects, splinters, holes, etc. Also, some criteria was developed in this study. Standard and criteria developed in this study will help to prevent slip, trip, and fall injuries.
The purpose of this research is to revive the colors of combination dyeing and mixed dyeing with natural dyestuffs. The fabrics used were cotton and rayon. The natural dyestuffs used in this research were indigo, Phellodendron amurense, and Caesalpinia sappan. The effects of combination dyeing were as follows. First, all samples showed deeper colors. Second, according to the results of the surface K/S measurement, while the surface K/S of cotton was over 15, that of rayon was over 17. Third, the results of the light fastness measurement showed the superiority (by over grade 4) of all the samples, except in the case of rayon fiber sample no. 6 (which had been pre-dyed with indigo five times before being dyed with P. amurense once and then being dyed with C. sappan once). In the color fastness to washing measurement, all fibers showed superiority (by over grade 3~4). In addition, the color fastness to dry cleaning of all fibers was satisfactory or excellent (by over grade 3). Fourth, according to the results of the tensile strength measurement, it tended to decrease in the case of cotton and increase in the case of rayon. Fifth, the results of the density measurement showed that the density of cotton decreased by about 15~20% in the case of warp and 10% in the case of weft for all samples. The density of rayon decreased 20% in the case of warp for all samples and increased 30% in the case of weft for all samples.
The pine needles has been used as medicines and it is using as dyeing as well as food. It is distributed through 50% in Korean forest. The pine needles is related to antimicrobial activity, however, dyeing properties of the extract components and effects of them are not well known yet. To examine dyeing properties of the pine needles extract, various fabrics(nylon, silk, wool, and soybean) were dyed under different dyeing conditions, and mordanted with one of five mordants(Al, Sn, Fe, Cr, and Cu). Dye uptake, Colors and Colorfastness of the dyed fabrics were measured. By the K/S values, dye uptake of all the dyed fabrics enhanced as increasing dyeing temperature and dyeing time. The highest K/S values were obtained from the protein fiber(wool and silk) fabrics dyed with water extract at $100^{\circ}C$, and with ethanol extract at $90^{\circ}C$ for 80 minutes. Colors of the dyed fabrics showed variety of yellow, brown and green colors. Colors changed by using Cu, Fe and Cr mordants: Cr-mordanted fabrics into light green, Fe-mordanted fabrics into reddish brown, and Cu-mordanted fabrics into deep green in ethanol extraction. Dry-cleaning fastness of the dyed fabrics presented good to excellent except wool fabrics dyed with ethanol extract. Washing fastness of the dyed nylon and soybean fabrics were good to excellent but wool and silk fabrics showed average grades. Most dyed fabrics were poor to light fastness.
This study was accomplished to examine the dyeing property and functionality of both cotton and silk fabrics dyed with clove extract. The purpose of this study was to investigate the effects of dyeing property, antibiosis, and sun protection effectiveness for a clove. The study method used in this study was the experimental research to extract dyestuffs from a clove, to treat dyestuffs with a mordant, and then to measure dyeing colorfastness, antibiosis, and sun protection for dyed fabrics. As a result of the test for dyeing colorfastness, in the case of colorfastness to laundry, the degree of discoloration showed grade $1\sim4$ and the degree of pollution showed grade $4\sim5$. Colorfastness to perspiration for both cotton and silk fabrics dyed showed grade $1\sim2$ to $4\sim5$. Colorfastness to sunlight showed grade 2 to $4\sim5$. Colorfastness to rubbing showed grade $3\sim4$ to $4\sim5$. In the colorfastness to dry cleaning, the degree of discoloration showed grade $3\sim4$ and the degree of pollution showed grade $4\sim5$. As a result of the antibiosis test, for the Staphylococcus aureus, both cotton and silk showed the bacteria reduction rate of 99.9% even after five times laundry, and for the Escherichia coli, cotton fabrics showed the bacteria reduction rate of 99.9% only after one time laundry, but silk fabrics showed the bacteria reduction rate of 99.9% even after five times laundry. As a result of the test for sun protection effectiveness, dyed silk fabrics showed the result more excellent than dyed cotton fabrics.
The coffee has been used as drink in the world and it has been using not only food but also dyeing. It can be used for four seasons in our normal living and it can be taken friendly everywhere. The coffee consists of about 8${\sim}$10% phenol(chlorogenic acid) that related to antioxidant and antimicrobial activity. However, its exact components and the dyeing property effects has not been well known yet. Therefore, the purpose of this study was to investigate the dyeing property and ultraviolet-cut ability of silk and nylon fabrics that was dyed variously with coffee extracts. Coffee extracts were done by boiling coffee with distilled water at $100^{\circ}C$ for 2 hours. As mordanting agent, we used $AlK(SO_4)_2$$12H_2O$, $CuSO_4$$5H_2O$, $FeCl_2$$4H_2O$. As the result of the dyeing properties and ultraviolet-cut ability of fabrics dyed with coffee bean extracts, we can find that the optimum dyeing temperature and dyeing time of the silk and nylon fabrics dyed with coffee bean extracts was $90^{\circ}C$, 60 min. and the colorfastness of washing and dry-cleaning was improved by using mordanting agent(4${\sim}$5 grade). Ultraviolet-cut ability was showed more 90% in dyed nylon fabrics.
The purpose of this research was to revive the bathochromic effects of wool fabrics by using natural dyestuffs with minimum heavy metallic mordants. The natural dyestuffs used in this research were the indigo plant, Phellodendron amurense, and Caesalpinia sappan. Sample no. 1 was pre-dyed five times with indigo. Sample no. 2 was pre-dyed five times with indigo and then once dyed with Phellodendron amurense. Following the same method as sample no. 2 with an additional Phellodendron, Sample no. 3 consisted of a pre-dye five times with indigo and twice with Phellodendron amurense. Sample no. 4 was pre-dyed six times with indigo and then once dyed with Caesalpinia sappan. Sample no. 5 followed the same method as no. 4 with an additional dye of Caesalpinia sappan. Sample no. 6 was pre-dyed five times with indigo and then once dyed with Phellodendron amurense and once dyed with Caesalpinia sappan. The results were as follows: first, all samples showed deeper colors. Second, according to the results of the surface K/S measurement, the surface K/S of wool fabrics was >20. Third, the results of lightfastness measurement showed superiority over grade 4 in samples no. 1, 2, 3, 5, and 6. However, sample no. 4 was grade 3. In the colorfastness to washing measurement, sample no. 2 showed greater superiority than grade 3-4, while samples no. 1 and 3 were grade 3. In addition, the colorfastness to dry cleaning for all samples was satisfactory or excellent by more than grade 3.
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