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Characterization of Stretchable Polypyrrole Films Prepared by Chemical and Electrochemical Method (화학적 및 전기화학적 방법으로 합성한 연신성 폴리피롤 필름의 특성)

  • 장관식;문봉진;오응주;홍장후
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.323-329
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    • 2003
  • Stretchable Polypyrrole films using functionalized doping agent, di(2-ethylhexyl) sulfosuccinate sodium salt (NaDEHS), were synthesized by chemical and electrochemical method. Chemically and electrochemically Prepared Polypyrrole films were stretch-oriented (L/L$\_$0/= 1.0 ∼ 2.5) by zone drawing method and the electrical conductivities were measured. As the draw ratio was increased, the electrical conductivities were increased. This result was confirmed by the increase in crystallinity through the increase in draw ratio. The temperature dependence of electrical conductivity showed that 3D-variable range hopping model (L/L$\_$0/ = 1.0∼2.0) and ID-VRH model (L/L$\_$0/ = 2.5) gave the best fit to the data for stretched Ppy-DEHS films.

Multivariate pHd analysis (다변량 pHd 분석)

  • 이용구
    • The Korean Journal of Applied Statistics
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    • v.8 no.1
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    • pp.61-74
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    • 1995
  • These days, many kinds of graphical methods have been developed, and it is possible to get information directly from data. Especially, R-code (Cook and Weisberg, 1994) make it possible to draw various kinds of two and three dimensional plots, and to rotate the axis of the plots. But the maximum dimensional of the plot is three, so we can not draw plot of one response variable with more than three explanatory variables. Li(1991, 1992) has developed a method to reduce the dimension of the explanatory variables, so it is possible to draw lower dimensional plots to get information of the full explanatory variables. One of the dimension reduction method developed by Li is pHd. In this paper, we have tried to apply the pHd method for the model with multivariate response.

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Development of Finite Element Program for Analyzing Springback Phenomena of Non-isothermal Forming Processes for Aluminum Alloy Sheets(Part 1 : Experiment) (알루미늄 합금박판 비등온 성형공정 스프링백 해석용 유한요소 프로그램 개발 ( 1부 : 실험 ))

  • 금영탁;유동열;한병엽
    • Transactions of Materials Processing
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    • v.12 no.3
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    • pp.202-207
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    • 2003
  • In order to examine the springback amount and material properties of aluminum alloy sheets (AL1050 and AL5052) in the warm forming which forms the sheet above the room temperature, the stretch bending and draw bending tests and tensile test in various high temperatures are carried out. The warm forming temperature 15$0^{\circ}C$ is a transition in terms of the material properties: over the forming temperature 15$0^{\circ}C$, them $\sigma$$_{YS}$ , $\sigma$$_{TS}$ , E, K, n, etc. are bigger but $\varepsilon$ and plastic strain ratio are smaller. Below the forming temperature 15$0^{\circ}C$, there are no big differences in material properties as the forming temperature changes. AL5052 sheet has more springback effect than AL1050 sheet. While the springbacks of AL5052 and AL1050 sheets show a big reduction over the warm forming temperature 15$0^{\circ}C$ in the stretch bending test, the springback rapidly reduces in the warm forming temperature 15$0^{\circ}C$-20$0^{\circ}C$ for AL5052 sheet and 20$0^{\circ}C$-25$0^{\circ}C$ for AL1050 sheet in the draw bending test.

Stress-Based Springback Reduction of an AHSS Front Side Member (고강도강 프런트 사이드멤버의 응력분포 최적화를 통한 스프링백 저감)

  • Song J.H.;Kim S.H.;Park S.H.;Huh H.
    • Transactions of Materials Processing
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    • v.15 no.4 s.85
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    • pp.295-303
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    • 2006
  • Optimization is carried out to determine process parameters which reduce the amount of springback and improve shape accuracy of a deep drawn product in sheet metal forming process. The study uses the amount of stress deviation along the thickness direction in the deep drawn product as an indicator of springback instead of springback simulation. The scheme incorporates with an explicit elasto-plastic finite element method for calculation of the final shape and the stress deviation The optimization method adopts the response surface method in order to seek for the optimum condition of process parameters such as the blank holding force and the draw-bead force. The present scheme is applied to design of the variable blank holding force in an U-draw bending process and the application is further extend ε d to the design of draw-bead force in a front side member formed with advanced high strength steel (AHSS) sheets of DP60. Results show that design of process parameter is well performed to decrease the stress deviation through the thickness and to reduce the amount of springback. The present analysis provides a guideline in a design stage for controlling the springback based on the finite element simulation of the complicated parts.

Intrinsic Flux Inequality in Forward Osmosis (FO) and Pressure-Retarded Osmosis (PRO) Processes (수학적 귀납법을 이용한 정삼투 및 압력지연삼투 공정의 투과율 불균형 해석)

  • Kim, Albert S.;Lee, Seung-won
    • Membrane Journal
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    • v.25 no.4
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    • pp.367-372
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    • 2015
  • In pressure-retarded osmosis (PRO) and forward osmosis (FO) processes, solvent (permeate) flux depends on which surface the draw solution faces. There are two operation modes. PRO mode indicates that the active layer faces the draw solution, and FO mode means that the porous substrate fronts the draw stream. It is often observed that the PRO mode produces higher flux than that of FO under the same operating conditions. The current work uses the method of proof by contradiction, and mathematically proves the intrinsic flux inequality between the two modes.

Enhancement of the Ionic Conductivity and Mechanical Strength of Micro-porous Separator by Uni-axial Drawing

  • Lee Je-An;Seol Wan-Ho;Lee Yong-Min;Park Jung-Ki
    • Journal of the Korean Electrochemical Society
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    • v.9 no.1
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    • pp.29-33
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    • 2006
  • A new porous separator based on poly(vinyl chloride) (PVC)/poly(vinylidene fluoride-co-hexafluoro-propylene) (P(VdF-co-HFP)/poly(methyl methacrylate) (PMMA) was prepared by a phase inversion method. To enhance mechanical property, the membrane was stretched uniaxially at high temperature. Tensile strength and ionic conductivity were measured for various draw ratios. The tensile strength and ionic conductivity were increased with increasing draw ratio. The tensile strength of the separator reached 52MPa after stretching to draw ratio of 5, and the ionic conductivity of the separator was increased from $1.9Xs10^{-4}S/cm\;to\;4.6X10^{-4}S/cm\;at\;25^{\circ}C$. The stretched separator immersed in liquid electrolyte was electrochemically stable up to 4.7 V. The cell based on the stretched separator was maintained at about 99% of the initial discharge capacity after 10th cycle operation at 0.2C rate.

The Effects of Drawing Conditions on Physical Properties of the Drawn Worsted Yarns (I) (연신공정 조건이 소모연신사의 물성에 미치는 영향 (I))

  • Han, Won-Hee;Kim, Seung-Jin;Kim, Sang-Ryong
    • Textile Coloration and Finishing
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    • v.22 no.1
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    • pp.51-60
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    • 2010
  • This research works on the effects of drawing conditions on the physical properties of the drawn worsted yarns. The drawn worsted yarns were made by the yarn drawing system under various drawing conditions such as concentration of reducing agent, draw ratio, setting time of drawn yarn, and concentration of oxidizing agent. The drawn worsted yarns from 2/80Nm to 2/90Nm were obtained from 2/60Nm worsted yarns, the surface and cross-sectional shapes and tensile properties of these various specimens were measured and discussed with the various drawing conditions. The drawing of worsted yarn made constituent wool fiber scratched and made it changing to polygonal cross-sectional shape. The tenacity and modulus were increased with draw ratio and concentration of reducing agent. And tensile strain was increased with draw ratio, which decreased with concentration of reducing agent.

Analysis-based Die Face Design for the Improvement of Surface Quality for a Heat Protect Panel of an Automobile (차량용 열차단판의 면품질 개선을 위한 성형해석 기반 금형면 설계)

  • Kim, K.P.;Kim, S.H.;Lee, D.G.;Jang, K.C.
    • Transactions of Materials Processing
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    • v.17 no.4
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    • pp.278-283
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    • 2008
  • This paper concerns the die face design for a heat protect panel aided by the finite element forming analysis in order to eliminate the surface defect and to improve the surface quality. The CAE procedure of the stamping process is introduced in order to reveal the reason of surface inferiorities and to improve surface quality. Complicated shape of the product induces the surface inferiorities such as wrinkling due to the insufficient restraining force of the forming blank and the non-uniform contact of the blank with the tools. This paper proposes a new guideline for the die design which includes the modification of tool shapes and addition of the draw-beads on the tool surface for ensuring the increased the restraining force with the uniform contact condition. The effectiveness of the proposed design is verified by the forming analysis and is confirmed by the tryout operation in the press shop. The analysis and test results show that the modified process parameters such as tool shapes and draw-beads can reduce the tendency of wrinkling and improve surface quality.

Prediction of Air Pocket Pressure in Draw Die during Stamping Process (드로우 금형의 에어포켓 수축에 따르는 내부공기 압력예측에 대한 연구)

  • Koo, Tae-Kyong;Hwang, Se-Joon;Park, Warn-Gyu;Oh, Se-Wook
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.6
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    • pp.10-18
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    • 2008
  • Metal stamping is widely used in the mass-production process of the automobile industry. During the stamping process, air may be trapped between the draw die and the panel. The high pressure of trapped air induces imperfections on the panel surface and creates a situation where an extremely high tonnage of punch is required. To prevent these problems, many air ventilation holes are drilled through the draw die and the punch. The present work has developed a simplified mathematical formulation for computing the pressure of the air pocket based on the ideal gas law and isentropic relation. The pressure of the air pocket was compared to the results by the commercial CFD code, Fluent, and experiments. The present work also used the Bisection method to calculate the optimum cross-sectional area of the air ventilation holes, which did not make the pressure of the air pocket exceed the prescribed maximum value.

The Impact of the Competitiveness of Intermediate Software on Enterprise Results : a Case Study of Chinese Intermediate Software

  • Liu, Zi-Yang;Chen, Yi;Li, Hao
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2018.07a
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    • pp.258-261
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    • 2018
  • The purpose of this paper is to draw a conclusion on the impact of intermediate software on enterprise results. In this paper, product innovation and product reliability are especially used as analytical factors. An exploratory analytical study is conducted on the competitiveness of intermediate software, in the hope of gaining a new understanding of the competitiveness of intermediate software. Data are analyzed using such quantitative analytical tools as SPSS and AMOS. Using reliability analysis, validity analysis and structural equation model analysis, the final results are achieved. According to the analysis results, we can draw the following conclusions: the competitiveness of intermediate software has a positive impact on the innovation of software products. The competitiveness of intermediate software doesn't have a positive impact on the reliability of software products. Product innovation has a positive impact on enterprise results. Product reliability also has a positive impact on enterprise results. By analyzing the conclusions, we can make certain suggestions and draw implications on the competitiveness of China's software industry.

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