• Title/Summary/Keyword: double-porosity

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Strengthening of Fiber-Reinforced $\gamma$-LiAlO$_2$ Matrixes for Molten Carbonate Fuel Cell by Laminatin (용융탄산염 연료전지용 화이버 강화 $\gamma$-LiAlO$_2$ 매트릭스의 적층에 의한 강도 증진)

  • 현상훈;조성철;홍성안
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.107-115
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    • 1999
  • Microstructural variation and strengthening effects with lamination methods of alumina fiber-reinforced ${\gamma}$-LiAlO2 matrixes for Molten Carbonate Fuel Cell(MCFC) were studied. The porosities of all matrix laminated by hot-pressing of two green sheets under 1 kg/$\textrm{cm}^2$ at 45$^{\circ}C$ for 1 min and by double-casting which the second layer cast on the first green sheet dried for 3.5h were more than 50%. The strength of the Al2O3 fiber-reinforced matrix prepared by lamination was enhanced by 70% in comparison with the non-laminated matrix (115 gf/$\textrm{mm}^2$) and the strength-directionality due to fiber-orientation also could be removed. The strength of matrixes laminated by triple-casting was higher than that of the double-cast matrix, but triple-cast matrix showed the directionality with the casting direction, and furthermore its porosity was less than 50%. Although the strength of matrixes laminated by double-casting (195 gf/$\textrm{mm}^2$) is slightly less than that of matrixes laminated by hot-pressing (212 gf/$\textrm{mm}^2$), the double-casting method was evaluated to be more efficient laminating process in MCFC matrix processing.

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Preparation of novolac-type phenol-based activated carbon with a hierarchical pore structure and its electric double-layer capacitor performance

  • Lee, Dayoung;Jung, Jin-Young;Park, Mi-Seon;Lee, Young-Seak
    • Carbon letters
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    • v.15 no.3
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    • pp.192-197
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    • 2014
  • A hierarchical pore structured novolac-type phenol based-activated carbon with micropores and mesopores was fabricated. Physical activation using a sacrificial silicon dioxide ($SiO_2$) template and chemical activation using potassium hydroxide (KOH) were employed to prepare these materials. The morphology of the well-developed pore structure was characterized using field-emission scanning electron microscopy. The novolac-type phenol-based activated carbon retained hierarchical pores (micropores and mesopores); it exhibited high Brunauer-Emmett-Teller specific surface areas and hierarchical pore size distributions. The hierarchical pore novolac-type phenol-based activated carbon was used as an electrode in electric double-layer capacitors, and the specific capacitance and the retained capacitance ratio were measured. The specific capacitances and the retained capacitance ratio were enhanced, depending on the $SiO_2$ concentration in the material. This result is attributed to the hierarchical pore structure of the novolac-type phenol-based activated carbon.

HISTOMORPHOMETRIC STUDY OF DENTAL IMPLANTS WITH DOUBLE ACID-ETCHED AND ANODIC OXIDIZED SURFACE IN THE RABBIT TIBIA (토끼 경골에서 치과용 임프란트의 이중 산부식 및 양극 산화 표면처리에 따른 조직계측학적 연구)

  • Han, Ye-Sook;Kim, Il-Kyu;Chang, Keum-Soo;Park, Tae-Hwan;Jeon, Won
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.28 no.5
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    • pp.434-444
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    • 2006
  • This study was performed to evaluate the effects of three different implant surface treatments to the bone formation during osseous healing period under unloading conditions. Machined, double-acid etched and anodic oxidized implants were inserted into tibia of 3.0 - 3.5 kg NZ white male rabbits and 2 animals of each group were sacrificed at 2, 4 and 8 weeks. The specimens containing implant was dehydrated and embedded into hard methylmethacrylate plastic. After grinding to $50{\mu}m$, the specimens were stained with Villanueva bone stain. From each specimen, histomorphometric evaluation and the bone implant contact rate were analysed with optical microscope. The results were as follows; 1. In the scanning electronic microscopic examination, machined surface implant had several shallow and paralleled scratches on plain surface, double acid-etched implant had lots of minute wrinkles, rough valley and also irregularly located craters that looked like waves, anodic oxidized surface implant had porosity that minute holes were wholly distributed on the surface. 2. After 2 weeks of implantation, the percentages of bone-to-implant contact in the machined implant, double acid-etched implant and anodic oxidized implant were 26.85%, 62.64% and 59.82%, after 4 weeks of implantation they were 64.29%, 77.85% and 75.23%, and after 8 weeks they were 82.66%, 85.34% and 86.39%. 3. After 2 weeks of implantation, the percentages of bone area between threads in the machined implant, double acid-etched implant and anodic oxidized implant were 21.55%, 42.81%, and 40.33%, after 4 weeks of implantation they were 49.32%, 62.60% and 75.56%, and after 8 weeks they were 71.62%, 87.73% and 83.94%. In summary, percentages of implant surface contacted to bone trabeculae and bone formation area inside threads in double acid-etched implants and anodic oxidized implants were greater than machined implants in early healing stage. These results suggest that double acid-etched and anodic oxidized surface implants could reduce the healing period for osseointegration and may enable to do early function.

A Study on the Sound Absorbing Performance of Parallel Perforated Plate Systems (병렬 다공판 시스템의 흡음성능에 관한 연구)

  • Hur, Sung-Chun;Lim, Jung-Bin;Ro, Sing-Nam;Lee, Dong-Hoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.11b
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    • pp.902-907
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    • 2002
  • An equivalent electroacoustic circuit approach of estimating the sound absorption coefficient for parallel perforated plate system is proposed. The proposed approach is validated by comparing the calculated absorption coefficients of a parallel single layer perforated plate system with the values measured by the two-microphone impedance tube method for various porosity and the number of perforated plate. The sound absorbing performances of parallel and series perforated plate systems are compared and discussed from a standpoint of frequency bandwidth with sound absorption. The proposed approach is further extended to the parallel double layer perforated plate system.

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Prediction and Measurement of Sound Transmission Loss for Multi-layered Acoustical Materials (다중층 음향 재료의 투과손실 예측과 측정)

  • Park, So-Hee;Park, Chul-Min;Chae, Ki-Sang;Kang, Yeon-June
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.17 no.11
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    • pp.1013-1020
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    • 2007
  • In this paper, the predictions and measurements of sound transmission loss(STL) are discussed for various types of acoustical materials and carpets. Random incidence sound transmission losses are measured by the sound intensity method. The in-house software HONUS2005 is used to predict TL and estimate the various physical properties such as the flow resistivity, the structure factor, the porosity, the Possion's ratio, and etc. After this estimation, various multi-layered materials with a steel plate are measured and predicted. In particular, Carpets are assumed to be membranes to predict acoustical performance. To confirm this assumption, double and triple-layered cases are also observed including two different kinds of carpets.

Algin Impregnated Vascular Graft I. In Vitro Investigation

  • Lee, Jin-Ho;Shin, Bung-Chul;Khang, Gil-Son;Lee, Hai-Bang
    • Journal of Biomedical Engineering Research
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    • v.11 no.1
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    • pp.97-104
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    • 1990
  • Microvel double velour graft impregnated with a biodegradable algin was studied as a new vascular graft. It is blood tight but still retains high porosity. Thls graft does not need to be preslotted with blood before implantation and has good tissue ingrowth and biological healing properties. The algin impregnated vascular graft was investigated by "in vitro" tests in this study. It was characterl zed by ESCA analysis, SEM observation, and measurements of water permeability, algin coating weight, mechanical properties and whole blood clotting time. The water permeability of the graft was reduced more than 99% and the whole blood clotting time was fast more than three times by the algin impregnation treatment. "In vivo" performance examinations of the algin impregnated graft are on progress.aft are on progress.

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Analysis of Seawater Intake System using the RNG k-𝜖 Algorithm (RNG k-𝜖 알고리즘을 이용한 해수취수시스템 분석)

  • Kim, Ji-Ho;Kim, Tae-Won;Lee, Seung-Oh;Park, Young-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6447-6454
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    • 2013
  • Seawater intake systems have significant problems due to seawater pollution, suspended solids, unstable intake and maintenance etc. An underground type seawater intake system was newly developed to overcome the existing weaknesses and was facilitated in Gyukpo port. In this study, to check the performance of the new system, the samples for water quality and the 3-D numerical modeling test were conducted. The five times test included the COD, total nitrogen, total phosphorus, pH, and suspended solid for the intake system. The analyses show that the COD, total nitrogen, total phosphorus, PH showedminor changes before and after. On the other hand, the change in suspended solids was significant and water was purified below 5 mg/l, first level fisheries water, after. The numerical model adopted the RNG $k-{\epsilon}$ algorithm and the CFX model based on the finite volume method. The porosity algorithm was used to reproduce filtered-sand, outer diameter, and thickness. The numerical results showed that the double pipe is advantageous in that it provides a uniform pressure between the inner and outer pipe for the flow to be stable. In addition, the use of multiple intake pipes did not interfere with the discharge reduction of 0.98 at the both intake pipes compared with the central intake pipe.

Improving Physical Fouling Tolerance of PES Filtration Membranes by Using Double-layer Casting Methods (PES 여과막의 물리적 막오염 개선을 위한 기공 구조 개선 연구)

  • Chang-Hun Kim;Youngmin Yoo;In-Chul Kim;Seung-Eun Nam;Jung-Hyun Lee;Youngbin Baek;Young Hoon Cho
    • Membrane Journal
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    • v.33 no.4
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    • pp.191-200
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    • 2023
  • Polyethersulfone (PES) is a widely employed membrane material for water and industrial purification applications owing to its hydrophilicity and ease of phase separation. However, PES membranes and filters prepared using the nonsolvent induced phase separation method often encounter significant flux decline due to pore clogging and cake layer formation on the dense membrane surfaces. Our investigation revealed that tight microfiltration or loose ultrafiltration membranes can be subject to physical fouling due to the formation of a dense skin layer on the bottom side caused by water intrusion to the gap between the shrank membrane and the substrate. To investigate the effect of the bottom surface porosity on membrane fouling, two membranes with the same selective layers but different sub-layer structures were prepared using single and double layer casting methods, respectively. The double layered PES membrane with highly porous bottom surface showed high flux and physical fouling tolerance compared to the pristine single layer membrane. This study highlights the importance of physical optimization of the membrane structure to prevent membrane fouling.

Variation of Geomechanical Characteristics of Granite and Orthogneiss in Wonju Area due to Accelerated Artificial Chemical Weathering Tests (강원도 원주일대에 분포하는 화강암 및 화강편마암의 화학풍화실험에 의한 물성 변화 연구)

  • Woo, Ik;Um, Jeong-Gi;Park, Hyuck-Jin
    • Tunnel and Underground Space
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    • v.19 no.3
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    • pp.213-225
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    • 2009
  • The purpose of the study is to evaluate the effects of chemical weathering on the granite and orthogneiss in Wonju area based on accelerated artificial chemical weathering. The rock samples were scrutinized the variation of index properties and ion exchanges caused by artificial chemical weathering which was implemented with leaching test for 170 days using double soxhlet extractor. The differential weathering and decrease of p wave velocity were obtained by weathering process without significant changes of porosity. In case of granite samples, the uniaxial compression strength was reduced by 20% and 16% for the F-grade and SW-grade, respectively. For MW-grade granite, however, was not able to examine the effect of strength reduction due to lack of sample number. Also, for orthogneiss, it is difficult to compare the values of uniaxial compressive strength between before and after the test because of its strong anisotropy.

Performance of Electric Double Layers Capacitor Using Activated Carbon Materials from Rice Husk as Electrodes

  • Nguyen, Tuan Dung;Ryu, Jae Kyung;Bramhe, Sachin N.;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.23 no.11
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    • pp.643-648
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    • 2013
  • Activated carbon (AC) was synthesized from rice husks using the chemical activation method with KOH, NaOH, a combination of (NaOH + $Na_2CO_3$), and a combination of (KOH + $K_2CO_3$) as the chemical activating reagents. The activated carbon with the highest surface area (around $2000m^2/g$) and high porosity, which allows the absorption of a large number of ions, was applied as electrode material in electric double layer capacitors (EDLCs). The AC for EDLC electrodes is required to have a high surface area and an optimal pore size distribution; these are important to attain high specific capacitance of the EDLC electrodes. The electrodes were fabricated by compounding the rice husk activated carbons with super-P and mixed with polyvinylidene difluoride (PVDF) at a weight ratio of 83:10:7. AC electrodes and nickel foams were assembled with potassium hydroxide (KOH) solution as the electrolyte. Electrochemical measurements were carried out with a three electrode cell using 6 M KOH as electrolyte and Hg/HgO as the reference electrode. The specific capacitance strongly depends on the pore structure; the highest specific capacitance was 179 F/g, obtained for the AC with the highest specific surface area. Additionally, different activation times, levels of heating, and chemical reagents were used to compare and determine the optimal parameters for obtaining high surface area of the activated carbon.