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Effects of Recycled Washwater on Pollutant Removal and Particle Characteristics during Coagulation (회수수가 응집공정의 오염물질 제거 및 입자특성에 미치는 영향)

  • 문병현;김승현;박미선;이향인;이강춘
    • Journal of Environmental Science International
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    • v.11 no.9
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    • pp.955-960
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    • 2002
  • The recycled washwater, which has different water quality and is produced about 5 to 20% of the total water volume treated, affects the unit operation of water treatment, especially coagulation process. However, the effects of recycled washwater on unit operation of water treatment have not been fully investigated. In this study, effects of recycled washwater on coagulation process were investigated to find the optimum coagulation condition by analyzing turbidity, $UV_{254}$, TOC removal efficiencies. In addition, effects of recycled washwater on residual Al after coagulation were studied by analyzing soluble and particulate Al. The size distribution and fractal dimension of coagulated also analyzed. The recycled washwater was lower pH than the raw water. And the recycled washwater had higher $UV_{254}$, TOC and residual Al concentration than the raw water. Residual Al concentration of recycled washwater was about 50 times higher than that of raw water. Optimum coagulant dosages on the blending recycled washwater and the raw water for turbidity, $UV_{254}$ and Al removal were lower than that on the raw water. However, TOC removal increased by increasing coagulant dosage. The size and fractal dimension of coagulated particle produced in the blending recycled washwater were larger, which imply faster settling velocity, than those produced in the raw water only.

Isomalto-oligosaccharide Production from Maltose by Intact Cells of Aureobasidium pullulaans (Aureobasidium pullulaans를 이용한 Maltose로부터 Isomalto-oligosaccharides의 생산)

  • 윤종원;노지선송주연송승구
    • KSBB Journal
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    • v.9 no.2
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    • pp.122-126
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    • 1994
  • A new method for the production of isomalto-oligosaccharides from maltose was investigated using intact cells of Aureobasidium pullulaans which had been known to produce fructo-oligosaccharides. The cells showed transglucosylation activity producing isomalto-oligosaccharides at high concentrations of maltose, while they showed a hydrolytic activity at low concentrations of substrate when cultivated at $25^{\circ}C$. The optimum reaction conditions for the isomalto-oligosaccharide production were as follows: substrate concentration, 500g/l maltose; pH, 4.5; temperature, $65^{\circ}C$; cell dosage, 10 unit per gram substrate. Under optimized conditions, the maximum yield of isomalto-oligosaccharides achieved was around 48% (w/w). At the early period of reaction, panose was selectively produced from maltose, and thereafter isomaltotriose was synthesized by utilizing panose as a substrate when maltose consumption was discontinued.

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Enhanced alizarin removal from aqueous solutions using zinc Oxide/Nickel Oxide nano-composite

  • Basma E. Jasim;Ali J. A. Al-Sarray;Rasha M. Dadoosh
    • Analytical Science and Technology
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    • v.37 no.1
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    • pp.39-46
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    • 2024
  • Alizarin dye, a persistent and hazardous contaminant in aquatic environments, presents a pressing environmental concern. In the quest for efficient removal methods, adsorption has emerged as a versatile and sustainable approach. This study focuses on the development and application of Zinc Oxide/Nickel Oxide (ZnO/NiO) nano-composites as adsorbents for alizarin dye removal. These semiconducting metal oxide nano-composites exhibit synergistic properties, offering enhanced adsorption capabilities. Key parameters affecting alizarin removal, such as contact time, adsorbent dosage, pH, and temperature, were systematically investigated. Notably, the ZnO/NiO nano-composite demonstrated superior performance, with a maximum alizarin removal percentage of 76.9 % at pH 6. The adsorption process followed a monolayer pattern, as suggested by the Langmuir model. The pseudo-second-order kinetics model provided a good fit to the experimental data. Thermodynamic analysis indicated that the process is endothermic and thermodynamically favorable. These findings underscore the potential of ZnO/NiO nano-composites as effective and sustainable adsorbents for alizarin dye removal, with promising applications in wastewater treatment and environmental remediation.

Clomiphene Citrate on Male Infertility (남성 불임증 환자에 대한 Clomiphene의 효과)

  • Lee, Kang-Hyun;Lee, Hee-Yong
    • Clinical and Experimental Reproductive Medicine
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    • v.8 no.2
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    • pp.45-55
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    • 1981
  • Clomiphene citrate. antiestrogen, was given to 39 infertile males whose spermatogenesis were disturbed and the efficacy of the drug was evaluated at the Department of Urology in 1980. (Table 1). Patients were divided into 3 clinical observation groups such as group I composed of 19 cases of idiopathic azoospermia, group II consisted of 15 cases of oligospermia following the vasovasostomy, and group III comprised 5 cases of testicular azoospermia. (Table 2). Clinical characteristics of these patients were as follows: Age of the patients ranged from 26 to 43 years old with mean of 34, and that of their wives ranged from 24 to 41 years old with mean of 31. Duration of marital life ranged from 1 to 21 years with mean of 5 years. Sizes of testis ranged from 6 to 25 ml with mean of 16 ml. Coital frequency ranged from 0.5 to 6 per week with mean of 2.4 per week. Levels of plasma FSH ranged from 3.15 to 23.06 lU/1 with mean of 8.15 lU/1, those of LH ranged from 2.98 to 19.89 lU/1 with mean of 8.18 lU/1 and those of testosterone ranged from 3.09 to 9.97 ng/ml with mean of 6.48 ng/ml. (Table 3). Clomiphene citrate was given in dosage of 50 mg per day (in d.) orally to 31 patients for 3 to 9 months and in dosage of 100 mg per day (b.i.d.) orally to 8 patients for 3 to 9 months. (Table 8). Semen samples were analysed monthly on each patient by routine analysis techniques. For the assessment of the efficacy of Clomiphene citrate on faulty spermatogenesis following empirical criteria were used: For semen quality: Improvement (I) represents that semen parameter increased more than 25% from basal level after the treatment, Unchange (U) expresses that semen parameter increased less than 25% of basal level or not changed after the treatment and Deterioration (D) means that semen parameter decreased from basal level after the treatment. For fertility unit (total counts ${\times}$ motility ${\times}$ morphology ${\div}10^6$): Improvement (I) represents that fertility unit increased more than 10 units after the treatment, Unchange (U) expresses that fertility unit increased less than 10 units or not changed after the treatment, and Deterioration (D) means that fertility unit decreased after the treatment. (Table 4). Results obtained from the Clomiphene therapy were as follows: Changes of spermiograme before and after the Oomiphene therapy shown in the Table 5. Sperm counts increased from 23 to 31 ${\times}10^6$/ml in group I, from 17 to 29 ${\times}10^6$/ml in group II. Other parameters of spermiogramme were not changed significantly after the treatment. Fertility units increased from 14 to 18 units after the treatment in group I, and from 16 to 18 units after the treatment in group II. Effectiveness of Clomiphene citrate on spermatogenesis was summarised in the Tables 6 and 7. After the treatment, sperm count increased in 11 patients, motility increased in 6 patients, morphology increased in 4 patients and fertility units increased in 9 patients. No sperm could be produced by Clomiphene citrate in group III of testicular azoospermia. Dosage of 50 mg of Clomiphene citrate per day for 3 to 6 months was proved to be the most effective in the present series. (Table 8). Pregnancy occurred in 2 patients after the treatment. No particular side effects were noted by the treatment. Pharmacologic compounds used for male infertility were shown in the Table 9. Reported results of Clomiphene citrate were shown in the Table 10.

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A Study on the Effects of Cosubstrates on the Biological Treatment and the Decolorization Mechanisms of Dyeing Wastewater (염색폐수의 생물학적 처리에 미치는 cosubstrates의 영향 및 색도제거 기전 연구)

  • Kim, Mee-Kyung;Seo, Sang-Jun;Ahn, Jae-Hwan;Shin, Eung-Bai
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.7
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    • pp.738-745
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    • 2006
  • In this research, the decolorization mechanisms of dye wastewater were divided into two pathways, one was physicochemical sorption to biomass flocs and the other was biological removal by microbial metabolisms. Batch tests were conducted to examine the reaction conditions, anaerobic and aerobic conditions, types and dose of cosubstrates, and to confirm the mechanisms of decolorization through the biosorption tests using the activated sludge and the autoclaved deactivated sludge. From the tests, the decolorization efficiencies of dye wastewater were 102 ${\Delta}$unit/g MLSS under the aerobic condition and 123 ${\Delta}$unit/g MLSS under the anaerobic condition, and organic removals were 82 $mg{\Delta}$COD/gMLSS and 75 $mg{\Delta}$COD/gMLSS respectively. Acetate was the more efficient cosubstrate than the domestic wastewater in the decolorization step. In addition the removal of colors and organics was increased with cosubstrates dosage. And $20.3{\sim}37.3$ ${\Delta}$unit/g MLSS was removed by the autoclaved sludge and $102.0{\sim}159.0$ ${\Delta}$unit/g MLSS by the activated sludge. The physicochemical sorption was dominant in the beginning of biosorption tests, and the biological decolorization was increased with a cosubstrate in the course of time.

A Fundamental Study on the Development of Porous Concrete for Planting (식재용 다공질 콘크리트의 개발에 관한 기초적 연구)

  • 윤기원;이상태;김기철;황정하;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10b
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    • pp.912-915
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    • 1998
  • As a fundamental study on the development of porous concrete for planting, this study is designed to present the properties of porous concrete by varying the kinds of cement, paste to aggregate ratio and dosage of AE admixture. As the results of experiment, the void volumes show 30~33%, 25~ 28% and 17~22% respectively, with paste to aggregate ratio of 20%, 30% and 40%. And unit weight is 1700~1900kg/㎥ while compressive strengths 40~60, 8 0~100 and 120~150kg/$\textrm{cm}^2$. pH of concrete shows a sufficient value at which the plant could grow, when the concrete is permeated in Ammonium Phosphate Dibasic for more than 1 hour. In brief, it shows a possibility of development of porous concrete if the concrete is permeated with permeating in Ammonium Phosphate Dibasic for more than 1 hour when the blast furnace slag cement is used.

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Analysis of Drug Use Reviews in Pediatirc Inpatients (소아입원환자에서의 약물사용 평가)

  • Shin, Eun Jeong;Ha, Hun Joo;Shin, Wan Gyoon;Park, Kwang Jun
    • Korean Journal of Clinical Pharmacy
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    • v.15 no.1
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    • pp.27-33
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    • 2005
  • This study was intended to contribute towards the development of proper drug use system for pediatric patients by investigationg problems related to their medication and identifying drugs that need to be developed into low dosage tab-lets or syrups for pediatric use based on our analysis on the prescriptions for pediatric inpatients from 22 hospitals in South Korea on a day of Feb. 2003. The usage rates in the proportion of less than 0.5 and 1 per unit of oral solid formulation were $29.9{\%}$ and $54.3{\%}$ in hospitals with 1000 beds or more, 36.5 and $60.6{\%}$ in hospitals with 500 to less than 1000 beds, $60.8{\%}$ and $81.6{\%}$ in hospitals with less than 500 beds. Of the 63 oral solid formulation products that were used two or more times in the proportion oi less than 0.5 units, 34 products ($54.0{\%}$) were used as such despite the fact that syrups and lower dosage tablets or capsules were available in the market, and 24 products ($38.1{\%}$) so even when syrup formulations were available. Therefore, it would be desirable that pharmacist communities in charge of dispensing identify the most frequently crushed drugs or those that require special attention in choosing dispensing powders or solutions and develop dispensing guidelines that can be adopted by pharmacists in practice. Moreover government-led policies are needed to encourage development and manufacture of the formulations for pediatrics and to correct unsound prescription and dispensing practices such as using crushed forms of certain oral solid formulations although alternative formulations are available in the market.

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Application of the Response Surface Methodology and Process Optimization to the Electrochemical Degradation of Rhodamine B and N, N-Dimethyl-4-nitrosoanilin Using a Boron-doped Diamond Electrode (Boron-doped Diamond 전극을 이용한 Rhodamine B와 N, N-Dimethyl-4-nitrosoanilin의 전기화학적 분해에 반응표면분석법의 적용과 공정 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.36 no.4
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    • pp.313-322
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    • 2010
  • The aim of this research was to apply experimental design methodology to optimization of conditions of electrochemical oxidation of Rhodamine B (RhB) and N, N-Dimethyl-4-nitrosoaniline (RNO, indicative of the OH radical). The reactions of electrochemical oxidation of RhB degradation were mathematically described as a function of the parameters of current ($X_1$), NaCl dosage ($X_2$) and pH ($X_3$) and modeled by the use of the central composite design. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the removal efficiency of RhB and RNO and test variables in a coded unit: RhB removal efficiency (%) = $94.21+7.02X_1+10.94X_2-16.06X_3+3.70X_1X_3+9.05X_2X_3-{3.46X_1}^2-{4.67X_2}^2-{7.09X_3}^2$; RNO removal efficiency (%) = $54.78+13.33X_1+14.93X_2- 16.90X_3$. The model predictions agreed well with the experimentally observed result. Graphical response surface and contour plots were used to locate the optimum point. The estimated ridge of maximum response and optimal conditions for the RhB degradation using canonical analysis was 100.0%(current, 0.80 A; NaCl dosage, 2.97% and pH 6.37).

3D Architectures of LaVO4:Eu3+ Microcrystals via an EG-assisted Hydrothermal Method: Phase Selective Synthesis, Growth Mechanism and Luminescent Properties

  • Ding, Yi;Zhang, Bo;Ren, Qifang;Zhang, Qicai;Zha, Weiwei;Li, Xin;Chen, Shaohua;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.96-101
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    • 2017
  • In this article, pure $m-LaVO_4:Eu^{3+}$ and $t-LaVO_4:Eu^{3+}$ nanocrystals were prepared by an EG-assisted hydrothermal method with regular shapes. A series of controlled experiments showed that the pH value of a mixed solution, the volume ratio of $EG/H_2O$ and the dosage of the doped $Eu^{3+}$ all had an important effect on the sizes and shapes of the final products. Furthermore, the constitutional unit of the products changed from 0D to 2D with an increase in the EG dosage. The PL results showed that $t-LaVO_4$ doped with $Eu^{3+}$ ions had better luminescence properties than $m-LaVO_4$ due to its special structure. All of these results not only expand our understanding of the luminescence properties of lanthanide orthovanadates, but they also elucidate the principles of the crystal growth.

Optimization of the Turbidity Removal Conditions from TiO2 Solution Using a Response Surface Methodology in the Electrocoagulation/Flotation Process (전기응집/부상 공정에서 반응표면분석법을 이용한 TiO2 수용액의 탁도 처리조건 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.35 no.6
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    • pp.491-499
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    • 2009
  • The removal of turbidity from $TiO_2$ wastewater by an electrocoagulation/flotation process was studied in a batch reactor. The response surface methodology (RSM) was applied to evaluate the simple and combined effects of the three main independent parameters, current, NaCl dosage and initial pH of the $TiO_2$ solution on the turbidity removal efficiency, and to optimize the operating conditions of the treatment process. The reaction of electrocoagulation/flotation was modeled by use of the Box-Behnken method, which was used for the fitting of a 2nd order response surface model. The application of RSM yielded the following regression equation, which is an empirical relationship between the turbidity removal efficiency of $TiO_2$ wastewater and test variables in uncoded unit: Turbidity removal (%)=69.76+59.76Current+11.98NaCl+4.67pH+5.00Current${\times}$pH-160.11$Current^2-0.34pH^2$. The optimum current, NaCl dosage and pH of the $TiO_2$ solution to reach maximum removal rates were found to be 0.186 A, 0.161 g/l and 7.599, respectively. This study clearly showed that response surface methodology was one of the most suitable method to optimize the operating conditions for maximizing the turbidity removal. Graphical response surface and contour plots were used to locate the optimum point.