• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.259-259
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• 2007

The low temperature sintering of dolomite type borates, $CaZr(BO_3)_2$[CZB] ceramics and their microwave dielectric properties were investigated The sintering temperature of CZB ceramics could be reduced from $1150^{\circ}C$ to $925^{\circ}C$ by the addition of sintering additive. $CaZrO_3$, $ZrO_2$ and $CaB_2O_4$ second phases were found in the CZB ceramics. The syntheses, sintering properties, microstructures, and dielectricnproperties of dolomite-type borates were examined by XRD, thermal analysis, electron microscopy, network analyzer, and the results are discussed intensively. The compatibility with silver electrode was also explored.

• Resources Recycling
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• v.23 no.2
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• pp.17-25
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• 2014

The thermal effect on the compositional change of the $SO_2$ absorption process product was investigated compared with the composition of raw material when dolomite is employed in place of lime in the scrubbing process based on thermodynamic estimation. It was considered that the equilibrium reactions which directly related with the formation of $CaSO_4$ and $MgSO_4$, the absorption process products, are those between $Ca^{2+}$ and $Ca(OH)_2$, $Mg^{2+}$ and $Mg(OH)_2$, and the secondary dissociation reaction of $H_2SO_4$. It was thought to be necessary to examine the enthalpy change for the formation reactions of $CaSO_4$ and $MgSO_4$ along with the thermal feature of the relative reactions to figure out the influence of temperature on the compositional change of absorption process products. The stable regions for $Ca(OH)_2$ and $Mg(OH)_2$ in Pourbaix diagram were found to be increased as temperature rises and the equilibrium reaction between $Ca^{2+}$ and $Ca(OH)_2$ was investigated to be more strongly influence by temperature change compared with the equilibrium reaction between $Mg^{2+}$ and $Mg(OH)_2$. The amounts of $CaSO_4$ and $MgSO_4$ were anticipated to be decreased with temperature considering the thermal characteristics for the equilibrium reactions regarding calcium, magnesium, and $H_2SO_4$. It was understood that the formation ratio between $CaSO_4$ and $MgSO_4$ is greater than the composition ratio between calcium and magnesium contained in dolomite at specific temperature and the decrease of the formation ratio of $CaSO_4$ and $MgSO_4$ with temperature was estimated to be diminished as the content of calcium in dolomite is increased. In addition, the extent of the change in the compositional ratio between absorption process products was examined to be reduced compared with the composition of raw material as the calcium content in dolomite is raised.

• Korean Journal of Remote Sensing
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• v.35 no.6_3
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• pp.1261-1271
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• 2019

In case of Korea, limestone is very useful in various industries. These limestones are mainly produced in Gangwon-do. The study area, which is located in Okgye-myeon, Gangneung-si, Gangwon-do, is Okcheon metamorphic belt where abundant limestone, dolomite stone, and high-grade limestone are produced. The purpose of this study is to distinguish between calcite and dolomite among the limestone which is one of the representative carbonate rocks using the spectral characteristics. For this study,spectral characteristics were measured in the field and laboratory using FieldSpec® 3 spectrometer equipment from Analytical Spectral Device Inc. (ASD). In the field, the reflectance was measured below 50 cm from rock surface, and in the laboratory, the reflectance was measured in the rock surface, the polished surface, and the rock powder. As a result, absorption wavelengths of calcite and dolomite were significantly different around 2,330 nm. In particular, the absorption wavelength band position of dolomite appeared before 2,330 nm wavelength compared to calcite. The study could be used as a basis data for analysis of high-grade calcite limestone.

• Journal of the Mineralogical Society of Korea
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• v.26 no.2
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• pp.87-99
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• 2013

The occurrence, mineralogical characteristics, and origin of the dolomite ores were investigated from major dolomite mines in South Korea. Mineralogical and textural properties of the ores and associated minerals were analyzed using X-ray diffraction, thin section petrography, and scanning electron microscopy. Dolomite ores were light to dark gray in color and mainly composed of dolomite in varying particle size with minor amounts of calcite, quartz and micas. Calcite, quartz, illite, feldspar, kaolin minerals, and chlorite occurred in local veins, dikes and alteration zones. Sepiolite and wollastonite occurred in the altered part of some mine. Asbestos minerals such as chrysotile and tremolite, however, were not identified in the present study. Reddish brown to yellow clay materials were mainly composed of illite, occasionally associated with kaolin minerals and smectite. These clay minerals might be a product of the local hydrothermal alteration related to the dyke intrusion and subsequent weathering. As well indicated in the previous studies, mineral composition, texture, and occurrence of the dolostone beds suggest their formation through the diagenesis of carbonate sediments deposited in the shallow sea during the Precambrian to Paleozoic period.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.6
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• pp.864-871
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• 2010

At the current situation of continuous utilization of heavy metal contaminated upland for agricultural purpose in Korea, minimizing transport of heavy metals from soil to crops is important for securing safety of human health. The present study (in field scale) examined the efficiency of several soil amendments (dolomite, steel slag, lime, zeolite, and compost) on reduction of phytoavailable heavy metals (Cd, Cu, Pb, and Zn) in soil through comparison with no amendment treatment and clean soil cover treatment. For determination of the phytoavailability, 1 M $NH_4NO_3$ extraction and red pepper cultivation were introduced. Among the amendments, in general, dolomite and steel slag were the most effective in reduction of metal (Cd, Pb, and Zn) phytoavailability resulting in less accumulation of these metals in shoot and fruit of red pepper. However, dolomite and steel slag treatment was not as effective as clean soil cover treatment which showed the least metal accumulation in red pepper fruit. Nevertheless, with taking into account the cost, treatment of dolomite or steel slag can be competitive method because the current study showed that dolomite or steel slag treatment reduced accumulated heavy metal concentration effectively in both shoot and fruit of red pepper compared to those from control soil and the concentration in fruit was within the standard value (<0.2 mg $kg^{-1}$ for both Cd and Pb).

• Journal of the Korean GEO-environmental Society
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• v.12 no.12
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• pp.71-78
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• 2011

This paper aims to present the evaluation of engineering characteristics and reusing possibility of waste powders produced in dolomite and limestone nonmetal mining by physical and mechanical experiments on compaction, uniaxial compressive strength, permeability, chemical composition, and so on. Granite soil, 2 types of limestone waste powder, and 1 type of dolomite waste powder were used for main materials, and cement and bentonite were used for admixed materials in this experiments. The findings based on the experimental results are the severe difference of chemical composition of the dolomite & limestone waste powder and the crushed rock waste powder, and the outstanding of engineering characteristics of the dolomite waste powder with high content of MgO compared with the limestone waste powder. The engineering properties on compaction, uniaxial compressive strength, and permeability are enhanced with increase of admixed ratio of waste powder on granite soil. From the experimental results, it can be suggested that the dolomite waste powder admixed with in-situ granite soil is useful as geo-materials with considering of distribution costs.

• Tunnel and Underground Space
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• v.5 no.1
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• pp.22-40
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• 1995

Thermomechanical characteristics of rocks such as thermal shock, thermal expansion, thermal cracking were experimentally investigaed using Iksan granite, Cheonan tonalite and Chung-ju dolomite to obtain the basic data for proper design and Chung-ju dolomite to obtain the basic data for proper design and stability analysis of underground structures subjected to temperature changes. The effect of thermal shock did not appear when the heating speed was under 3$^{\circ}C$/min. and there existed little difference between multi-staged cyclic heating and single-cycled heating. Thermal expansion of rocks was affected by mineral composition, crack porosity and the degree of thermal craking. In quartz-beraring multimineralic rocks such as Iksan granite and Cheonan tonalite, the thermal expansion coefficient increaseed continuously with temperature rise, but that of Chung-ju dolomite which was a monomineralic rock showed a constant value for the temperature above 250$^{\circ}C$, Chung-ju dolomite yielded the lowest critical threshold temperature(Tc) of 100$^{\circ}C$ and unstable thermal cracking was initiated above the new threshold temperature(Tc')of 300$^{\circ}C$. Above Tc' thermal cracks grew but they were not interconnected. Iksan granite showed closing of microcracks to the temperature of 100$^{\circ}C$, then expanded linearly to Tc of 200$^{\circ}C$. Above Tc, thermal cracking was initiated and progressed rapidly and almost all the grain boundaries were cracked at 600$^{\circ}C$. Cheonan tonalite also showed similar behavior to iksan granite except that Tc was 350$^{\circ}C$ and that thermal cracks propagated more rapidly. Thermal expansions calculated by Turner's equation were found to be valid in predicting the thermal expansion and cracking behavior of rocks.

• Journal of the Mineralogical Society of Korea
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• v.26 no.2
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• pp.111-118
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• 2013

Diagenetic black chert nodules occur in the Paleozoic dolostone in Susan, Jecheon, Korea. They reacted with dolomite to form alteration rim around the nodules during the contact metamorphism probably related to the intrusion of biotite granite. In the earlier stage of alteration, talc and calcite replaced both the chert and dolomite, which were subsequently replaced by tremolite. Significant mass of tremolite occurs along the horizon enriched with chert nodules. Scanning electron microscopy and optical microscopy of the tremolite specimens revealed the elongated morphology of diverse aspect ratios coexisting in several mm scale. Non-asbestiform tremolite columns were also common as well as asbestiform fibrous bundles. Quantitative estimation of asbestos should be more cautious for naturally occurring materials because all the tremolite particles in the outcrop are not asbestiform. The occurrence of asbestiform tremolite in the Susan area indicates that a combination of chert-bearing dolostone, heat source, and aqueous fluids is one of the geological environments for the formation of asbestiform tremolite.

• Clean Technology
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• v.25 no.2
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• pp.168-176
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• 2019

Spent coffee is one of biomass sources to be converted into bio-oil. However, the bio-oil should be further upgraded to achieve a higher quality bio-oil because of its high oxygen content. Deoxygenation under hydrotreating using different catalysts (catalytic hydrodeoxygenation; HDO) is considered as one of the promising methods for upgrading bio-oil from pyrolysis by removal of O-containing groups. In this study, the HDO of spent coffee bio-oil, which was collected from fast pyrolysis of spent coffee ($460^{\circ}C$, $2.0{\times}U_{mf}$), was carried out in an autoclave. The product yields were 72.16 ~ 96.76 wt% of bio-oil, 0 ~ 18.59 wt% of char, and 3.24 ~ 9.25 wt% of gas obtained in 30 min at temperatures between $250^{\circ}C$ and $350^{\circ}C$ and pressure in the range of 3 to 9 bar. The highest yield of bio-oil of 97.13% was achieved at $250^{\circ}C$ and 3 bar, with high selectivity of D-Allose. The carbon number distribution of the bio-oil was analyzed based on the concept of simulated distillation. The $C_{12}{\sim}C_{14}$ fraction increased from 22.98 wt% to 27.30 wt%, whereas the $C_{19}{\sim}C_{26}$ fraction decreased from 24.74 wt% to 17.18 wt% with increasing reaction time. Bio-oil yields were slightly decreased when the HZSM-5 catalyst and dolomite were used. The selectivity of CO was increased at the HZSM-5 catalyst and decreased at the dolomite.

• Economic and Environmental Geology
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• v.54 no.3
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• pp.365-372
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• 2021

Pebble-bearing clastic carbonate rock which has been found in and around the Jeongseon and Okgye through the field survey was studied in petrological and mineralogical characteristics. We define the clastic carbonate rocks as 'Dolomite-pebble bearing fine sand-sized dolostone, or grainstone', which are characterized by the existence of dolomite single grains and Mg-phengite, and by the subsequent formation of secondary calcite cements. These attributes correspond well with those of the typical Haengmae Formation from Haengmae-dong, Mitan-myeon, Jeongseon-gun, thus the carbonate rocks in the Jeongseon and Okgye areas must belong to the Haengmae Formation. The result suggests that the Haengmae Formation is an independent unit among the Paleozoic lithostratigraphic units in Taebaek basin and lies in the upper part of Jeongseon and Sukbyungsan Formations under the Hongjeom Formation of Pyeongan Supergroup.