• Title/Summary/Keyword: dodecane

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Cubic Equation of State Analysis for the Prediction of Supercritical Thermodynamic Properties of Hydrocarbon Fuels with High Critical Compressibility Factor (고 임계 압축인자를 갖는 탄화수소 연료의 초임계 열역학적 물성 예측을 위한 상태방정식 분석)

  • Jae Seung Kim;Jiwan, Seo;Kyu Hong Kim
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.5
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    • pp.24-34
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    • 2022
  • In order to predict the cooling performance of a regenerative cooling channel using hydrocarbon fuel operating in the supercritical region, it is essential to predict the thermodynamic properties. In this study, a comparative analysis was performed on two-parameter equations of state (SRK(Soave-Redlich-Kwong), PR(Peng-Robinson) equations of state) and three-parameter equations of state (RK-PR equations of state) to appropriately predict density and specific heat according to the critical compressibility factor of polymer hydrocarbons. Representatively, n-dodecane fuel with low critical compressibility factor and JP-10 fuel with high critical compressibility factor were selected, and an appropriate equation of state was presented when predicting the thermodynamic properties of the two fuels. Finally, the prediction results of density and specific heat were compared and verified with NIST REFPROP data.

Effect of Chain Matching between Hydrocarbon and Fatty Acid on High Pressure Rheology

  • Ohno, N.;Mukai, R.;Rahman, Md.Z.;Shibata, K.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.83-84
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    • 2002
  • For estimation of chain-matching phenomena between normal paraffin as a solvent and straight-chain fatty acid as an additive, the density measurement of n-dodecane, n-tetradecane and n-hexadecane were carried out at oil temperature 313K and pressure up to 1.3 GPa. Their solidification pressure were easily determined by the appearance of molecular crystal, abrupt volumetric contraction and generation of heat of solidification and showed minima under the matching condition. The bulk modulus K of molecular crystal was evaluated using phase diagram. The bulk modulus showed maxima under the each matching condition. The chain matching effect on the bulk modulus beyond the scope of the interfacial phenomena are confirmed.

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SPRAY CHARACTERISTICS OF DIRECTLY INJECTED LPG

  • Lee, S.W.;Y. Daisho
    • International Journal of Automotive Technology
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    • v.5 no.4
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    • pp.239-245
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    • 2004
  • It has been recognized that alternative fuels such as Liquid Petroleum Gas (LPG) show less polluting combustion characteristics than diesel fuel. Furthermore, engine performance is expected to be nearly equal to that of the diesel engine if direct-injection stratified-charge combustion of the LPG can be adopted in the spark-ignition engine. However, spray characteristics of LPG are quite different from those of diesel fuel. understanding the spray characteristics of LPG and evaporating processes are very important for developing efficient and low emission LPG engines optimized in fuel injection control and combustion processes. In this study, the LPG spray characteristics and evaporating processes were investigated using the Schlieren and Mie scattering optical system and single-hole injectors in a constant volume chamber. The results show that the mixture moves along the impingement wall that reproduced the piston bowl and reaches in ignition spark plug. LPG spray receives more influence of ambient pressure and temperature significantly than that of n-dodecane spray.

유기인산 추출제 CMPO에 의한 Am(III) 추출특성 연구

  • 양한범;임재관;이일희;유재형;박현수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.559-564
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    • 1996
  • 다작용기 유기인산 추출제인 octyl(phenyl)-N, N-diisobutyl carbamoylmethylphosphine oxide(CMPO)의 Am(III)에 대한 추출특성을 조사하였다. 0.2M CMPO-1.4M TBP/n-dodecane 추출제, 추출온도 30 $^{\circ}C$, 수용액의 질산농도 2M인 조건에서 Am(III)은 95.8%가 추출되었다. CMPO 추출제에 첨가되는 TBP 농도가 0.5M 까지는 Am(III)의 추출율이 감소시키는 영향을 나타냈으나, 0.5M 이상인 영역에서는 Am(III) 추출율에 미치는 영향이 작게 나타났다. 그리고 Am(III) 추출에 미치는 옥살산농도의 영향은 옥살산농도가 증가할수록 Am(III)의 추출율이 감소하였으며 추출온도가 높을수록 Am(III) 추출율이 감소하는 실험결과를 얻었다. CMPO 추출제는 제 3상을 매우 잘 형성하여 특징을 나타냈으며 이를 방지할 수 있는 조건을 규명하였다.

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Combustion characteristics of the heater for the vehicle (디젤을 이용한 차량용 히터의 연소특성)

  • Lee, Sang-Seok;Lee, Jin-Seok;Lee, Do-Hyung;Suk, Kyung-Ho
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.253-256
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    • 2006
  • Most heater being used in vehicles has been used to a cabin heating by being supplied from a heat loss of the engine coolant for heat source efficiency. Recently, the heat loss is reduced by high efficiency in the engine. It becomes to require the combustion heater that directly bums the heater used in vehicles to provide heat source of the heater. The purpose of this study is to research a burner which will applicate combustion heater by the numerical analysis. There are the 5 different types of burners, which is designed by differently each design of the swirler. N-DODECANE by used the burner fuel is performed by numerical analysis in every 5 burner. The burner's efficiency testing is evaluated on the basis of the Exhaust gas temperature.

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The Extraction of Nb from Nitric Acid Solution by Mixture of Tributylphosphate(TBP) and Dibutylphosphate(DBP) (窒酸溶液에서의 Tributylphosphate (TBP), Dibutylphosphate (DBP)混合物에 依한 Nb의 抽出)

  • Yung Kook Kim
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.38-41
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    • 1963
  • Nb is one of the trouble-some fission products in the reprocessing of nuclear fuels. In this paper, the extraction of Nb from 1, 2, 3, 4, 6 and 9N $HNO_3$ solution by mixtures of TBP and DBP in dodecane are reported. Sums of the concentration of TBP and DBP are kept to 20%. When the concentrations of DBP are lower the $2{\times}10^{-2}%$, distribution ratios are almost same, and ratios increase abruptly and the slope is about 2.5 at between $2{\times}10^{-2}$ to $4{\times}10^{-1}%$, then slope falls down to about 0.5. There is aging effect on mixture of TBP and DBP.

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Effect of pH and Iron/Manganese Ion on TiO2 Mediated Photocatalytic Inactivation of Index Microorganisms (LNAPL을 이용한 지중 산소전달 향상: (I) Abiotic Condition)

  • Ha, Jeong-Hyub;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.3
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    • pp.307-311
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    • 2004
  • The objective of this work is to evaluate the hypothesis that a good technique for supplying oxygen to the saturated zone in the presence of light nonaqueous phase liquid (LNAPL) pool contamination at the water table is to pass air through the unsaturated zone above the pool. This hypothesis was evaluated in experimental studies performed using a bench-scale, sand-tank reactor, Steady-state abiotic experiments in the sand-tank reactor with air flowing through the reactor headspace demonstrated that oxygen supply through the water table interface into the saturated zone was enhanced when an LNAPL (dodecane) pool was present at the water table. These experimental results confirmed the hypothesis that an LNAPL pool can serve as a high concentration oxygen source to the oxygen-limited area beneath the pool and, as a result, enhance the in situ biodegradation rate.

A novel drying process for oil adsorption of expanded graphite

  • Park, Soo-Jin;Lee, Seul-Yi;Kim, Ki-Seok;Jin, Fan-Long
    • Carbon letters
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    • v.14 no.3
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    • pp.193-195
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    • 2013
  • Expanded graphite (EG) was prepared using a drying process for application as an oil-adsorbent: the morphology, expansion volume, and oil absorption capacity of the EG were investigated. The expanded volume of the EG increased with an increasing reaction time and heat treatment temperature. The oil adsorption capacity of the EG was 45 g of n-dodecane per 1 g of EG. It is noted that the drying process of EG is a useful technique for a new oil-adsorbent.

Di-(2-ethylhexyl)phosphoric acid 추출제에 의한 Am(III), Eu(III) 및 Np(Ⅵ)의 상호분리연구

  • 양한범;임재관;이일희;유재형;박현수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.853-858
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    • 1995
  • $^{152}$EU, $^{241}$Am 및 $^{241}$Np를 선정하여 추출제 di-(2-ethylhexyl)phosphoric acid (DEHPA)로 이들 세가지 핵종의 상호 분리공정에 대해 연구하였다. 추출공정에서 질산농도는 0.IM이고 추출 제DEHPA/n-dodecane 농도가 IM 일때, $^{152}$Eu 및 $^{241}$Am, $^{241}$Np 핵종 모두 99.9% 이상 추출되었다. $^{241}$Am 핵종의 역추출을 위한 제 1 역추출공정에서 역추출제인 0.05M di-ethylenetriamine pentaacetic acid (DTPA)와 1.5M 젖산 (lactic acid) 혼합용액의 pH가 3.6 일때 $^{152}$Eu과 $^{241}$Am의 상호분리비와 역추출율이 가장 좋았다. $^{152}$Eu의 역추출을 위한 제 2 역추출단계에서 역추출제인 질산용액의 최적농도는 6M이며, 이때 $^{152}$Eu은 99%가 역추출되었다.$^{241}$Np 핵종의 역추출을 위한 제 3 역추출공정에서 역추출제는 0.5M 옥살산이며, 이때 $^{241}$Np은 92%가 역추출되었다.

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Water Permeation Flux of Oil-Emulsion through Surface-Modified Polysulfone Membrane (표면개질된 폴리설폰 막에 대한 오일에멀젼의 수투와 플럭스)

  • Song, Kun-Hoo;Kim, Kang-Hee;Cho, Seong-Heon;Lee, Kwang-Rae
    • Journal of Industrial Technology
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    • v.23 no.A
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    • pp.187-191
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    • 2003
  • A hollow-fiber type polysulfone UF membrane was surface-coated with hydroxyethylmethacrylate (HEMA). The effect of various coating parameters on permeation flux, such as concentration ratio of AIBN/HEMA, solvent(water or methanol), and UV irradiation time, was investigated. The water permeation flux of oil-emulsion increased with concentration ratio of AIBN/HEMA, and increased with UV irradiation time. The flux of the membrane coated in solution using methanol as a solvent was greater than that of the membrane coated in solution using water as a solvent. The flux of both the coated and the uncoated membrane declined with the operation. The flux decline means that the membrane fouling by oil-emulsion occurs. However, the fouling of the coated membrane was much less than that of the uncoated membrane.

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