• 제목/요약/키워드: dodecane

검색결과 114건 처리시간 0.025초

n-Dodecane 연료의 고온면 점화특성 (Ignition Characteristics of n-Dodecane Fuel Droplet on a Hot Surface)

  • 김성찬
    • 한국화재소방학회논문지
    • /
    • 제24권1호
    • /
    • pp.116-121
    • /
    • 2010
  • n-dodecane 연료 액적의 고온면 점화특성을 파악하기 위해 본 연구에서는 공기의 공급과 제어가 가능한 실험실 규모의 실험 장치를 제작하였다. 표면온도는 적외선 측정법에 의해 계측되었으며 적외선 측정법에 의해 계측된 온도는 k-type 열전대에 의해 측정된 온도와 비교하여 $10^{\circ}C$ 이내의 오차를 보였다. 각 공기 공급유량에 대하여 약 400회의 점화실험이 수행되었으며 점화실험결과로부터 점화확률 분포와 최소 점화온도에 관한 결과를 얻었다. 공기 공급유량이 3.0lpm인 경우를 제외하고 냉염과 열염 점화특성을 보였으며 공기 공급유량에 따라 냉염점화가 일어나는 온도범위가 큰 차이를 보였다. 실험결과 n-dodecane 연료의 최소고온면점화온도(MHSIT)는 공기공급 유량이 0.5lpm인 경우에 대하여 약 $300^{\circ}C$를 나타냈다. 본 연구에서는 외기조건에 따른 점화특성을 파악함으로써 초기 발화 메커니즘을 이해하고 조기화재 진압을 위한 시스템 설계의 기초적 자료로 활용된다.

ECN 연구용 고온 고압 정적 연소실에서의 n-dodecane 분무 및 연소 특성 (Spray and Combustion Characteristics of n-dodecane in a Constant Volume Combustion Chamber for ECN Research)

  • 김재헌;박현욱;배충식
    • 한국분무공학회지
    • /
    • 제19권4호
    • /
    • pp.188-196
    • /
    • 2014
  • The spray and combustion characteristics of n-dodecane fuel were investigated in a CVCC (constant volume combustion chamber). The selection of ambient conditions for the spray followed ECN (engine combustion network) guidelines, which simulates the ambient condition of diesel engines at start of fuel injection. ECN is a collaboration network whose main objective is to establish an internet library of well-documented experiments that are appropriate for model validation and the advancement of scientific understanding of combustion at conditions specific to engines. Therefore repeatability of the experiments with high accuracy was important. The ambient temperature was varied from 750 to 930 K while the density was fixed at around $23kg/m^3$. The injection pressure of the fuel was varied from 500 to 1500 bar. The spray was injected in both non-reacting ($O_2$ concentration of 0%) and reacting conditions ($O_2$ concentration of 15%) to examine the spray and the combustion characteristics. Direct imaging with Mie Scattering was used to obtain the liquid penetration length. Shadowgraph was implemented to observe vapor length and lift-off length at non-reacting and reacting conditions, respectively. Pressure data was analyzed to determine the ignition delay with respect to the spray and ambient conditions.

축소 노멀 도데케인 화학반응 메커니즘 개발 (Development of Reduced Normal Dodecane Chemical Kinetics)

  • 이상열;김규진;민경덕
    • 한국자동차공학회논문집
    • /
    • 제21권2호
    • /
    • pp.37-44
    • /
    • 2013
  • Generally, a reduced chemical mechanism of n-heptane is used as chemical fuel of a 3-D diesel engine simulation because diesel fuel consists of hundreds of chemical components and various chemical classes so that it is very complex and large to use for the calculation. However, the importance of fuel in a 3-D simulation increases because detailed fuel characteristics are the key factor in the recent engine research such as homogeneous charged compression ignition engine. In this study, normal paraffin, iso paraffin and aromatics were selected to represent diesel characteristics and n-dodecane was used as a representative normal paraffin to describe the heavy molecular weight of diesel oil (C10~C20). Reduced kinetics of iso-octane and toluene which are representative species of iso paraffin and aromatics respectively were developed in the previous study. Some species were selected based on the sensitivity analysis and a mechanism was developed based on the general oxidation scheme. The ignition delay times, maximum pressure and temperature of the new reduced n-dodecane chemical mechanisms were well matched to the detailed mechanism data.

표면처리 한 polysulfone 막으로 오일/물 에멀젼의 한외여과 특성 (The Ultrafiltration Characteristics of Oil/Water Emulsion Using Modified Polysulfone Membrane)

  • 정경환;이근우;김길정;정기정;김철
    • 에너지공학
    • /
    • 제8권1호
    • /
    • pp.119-126
    • /
    • 1999
  • 본 연구는 polysulfone 막을 표면처리 하여 오일 폐수를 한외여과 처리하였고 이때 fouling의 감소효과를 실험하였다. 고분자나 계면활성제를 polysulfone막에 흡착시켜 표면처리를 하였다. 다양하게 표면처리된 막으로 dodecane(0.1 v%)/물 에멀젼과 dodecane-계면활성제/물 에멀젼을 회분식 실험방법으로 수행하였다. SDS로 개질한 막으로 dodecane-계면활성제/물 에멀젼을 환외여과 처리하였을 때 fouling이 가장 작게 나타났고, 재사용에 좋은 방법으로 나타났다.

  • PDF

도데케인 연료액적의 초임계 상태 기화 특성 (Vaporization Characteristics of Dodecane Fuel Droplet in Supercritical Condition)

  • 고정빈;이관형;구자예;전창수;문희장
    • 한국분무공학회지
    • /
    • 제9권3호
    • /
    • pp.8-14
    • /
    • 2004
  • Characteristics of droplet vaporization at high ambient pressures and temperatures which are supercritical conditions is studied numerically by formulating one dimensional vaporization model in liquid dodecane and air. Modified Soave-Redlich-Kwong state equation is used to condider real gas effect. Non-ideal behavior of properties at near critical and supercritical conditions is considered in the high pressure condition. Characteristic spatial distribution of properties with various conditions of pressure and temperature is evaluated in order to understand vaporizing evolution.

  • PDF

Drop formation at submerged nozzles: Comparison of aqueous dispersed and organic dispersed cases for TBP-dodecane and nitric acid system

  • Roy, Amitava;Darekar, Mayur;Singh, K.K.;Shenoy, K.T.
    • Nuclear Engineering and Technology
    • /
    • 제51권3호
    • /
    • pp.761-768
    • /
    • 2019
  • Understanding the phenomena of formation of single drops is necessary to understand the hydrodynamics in solvent extraction equipment which are used for separation of nuclear materials. In this work, the phenomena of aqueous phase and organic phase drop formation at submerged nozzles are compared by conducting experiments with 30%TBP (v/v) in dodecane as the organic phase and nitric acid as the aqueous phase. Two different nozzles and three different nitric acid concentrations are used. For each nozzle and nitric acid concentration, velocity of the dispersed phase is varied. Drops of aqueous phase formed at downward oriented nozzles submerged in organic phase are observed to be smaller than the drops of organic phase formed at upward oriented nozzles submerged in aqueous phase. Correlations to estimate drop diameter are proposed.

화학적 토양세정에서의 가용기작과 조용매의 효과 (Solubilization Mechanism and Cosolvent Addition in Chemical Soil Washing)

  • 김현수;조대철
    • 한국산학기술학회:학술대회논문집
    • /
    • 한국산학기술학회 2002년도 춘계학술발표논문집
    • /
    • pp.260-263
    • /
    • 2002
  • 이 연구는 과량의 유분(dodecane)으로 오염된 토양을 효율적으로 정화시키기 위한 화학적 토양세정(soil flushing)에서 알코올 성분에 의한 유동성을 고찰한 것이다. 탄소수가 다른 알코올 (methanol, ethanol, butanol)과 Tween-80 계면활성제를 세정용액으로 사용하여 혼합비, 조용매 종류 및 체류시간에 따른 세정결과를 도시하였다. 조용매 사용시 세척효율은 최대 94%(Butanol/Tween-80(w/w)=0.1) 이었다. 체류시간의 연장은 재흡착되는 admicelle의 증가로 말미암아 세정효율을 감소시키는 것으로 나타났다.