• Title/Summary/Keyword: distribution coefficient($K_D$)

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Deposition Properties of $^{137}Cs$ in Marine Sediments

  • Park, G.;Lin, X.J.;Kim, W.;Kang, H.D.;Lee, H.L.;Kim, Y.;Doh, S.H.;Kim, D.S.;Yun, S.G.;Kim, C.K.
    • Journal of Radiation Protection and Research
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    • v.28 no.4
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    • pp.353-360
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    • 2003
  • The concentration of $^{137}Cs$, the particle size, and the contents of TOC, H, N and S were measured for sediments collected in the adjacent sea to Yangnam, Korea. The concentrations of $^{137}Cs$ in sediments are in the range of $^{137}Cs$ for sediments strongly depend on particle size and TOC content of sediments. The results of multiple regression analysis suggest that humic substances may have great influence on the deposition of $^{137}Cs$ in sediment.

Settling Characteristics of Natural Loess Particles in Seawater (해수 중에서 자연상태 황토입자의 침강특성)

  • KIM Sung-Jae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.6
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    • pp.706-712
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    • 1999
  • PSD (particle size distribution) for 2,000 mg/$\ell$ natural loess in seawater showed normal distribution cure at 0 minute settling time, accompanying with very large particle distribution range with its mean particle diameter of 31.6 $\mu$m and coencient of variance of $72.6\%$, With elapsed time it showed that the PSD was rapidly changed from normal distribution cure to abnormal distribution curve, steepened the right-hand side of it and its coefficient of variance was getting increased because of rapid settling of large size particles, Cumulative weight distribution showed that 2,000 mg/$\ell$ natural loess in seawater was almost $100\%$ constituted of particles bigger than 20 $\mu$m in diameter. Ratio of $V_s/(D_{bm})^{1/2}$ for loess particles in seawater was increased with increase of particle size in geometrical progression. Almost all loess particles in seawater had Stokes settling velocity not less than 2,255 times of Brownian diffusion coefficient, There was almost to EDL (about 0.4 nm) around natural loess particles in seawater, Thus, there was always LVDW attractive force between loess particles approaching each other in seawater, and almost no EDL repulsive force. Loess particles were not always in the condition of easy floe formation. Concentration of natural loess in seawater increasing from 400 mg/$\ell$ to 10,000 mg/$\ell$, characteristics of the settling was changed from Type I settling (discrete settling) to Type II settling (flocculation settling). PVD (particle volume distribution) showed that natural loess particles in seawater were largely constituted of two types of particles, such as rapidly settling particles and suspended and dispersed particles for a long time. Amount of the latter was much less than that of the former.

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The Coupled Electro-Thermal Field Analysis for Predicting Over-Current Protector Behavior

  • Bae, Jae-Nam;Lee, Sung-Gu;Han, Jung-Ho;Chung, Hae-Yang;Lee, Ju
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.7
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    • pp.43-48
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    • 2008
  • The characteristics of heat transfer of the bimetal disc for over-current protection device is specified. Bimetal consists of two metals which have a different thermal expansion coefficient. To analyze the thermal characteristics, temperature distribution when bimetal acts as a switch is calculated. As usual, heat source is applied to the bimetal and electric current is heat source in the over-current protection switch. In this paper, thermal distribution are obtained by solving a coupled electro-thermal field with 3D finite element method.

Improved Closure Approximation for Numerical Simulation of Fiber Orientation in Fiber-Reinforced Composite (단섬유 보강 복합재료에서의 섬유배향의 수치모사를 위한 개선된 근사모델)

  • D.H. Chung;T.H. Kwon
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.202-216
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    • 1998
  • Improved version of previous 'Orthotropic' closure approximation, termed 'ORW' has been numerically developed using new homogeneous flow data. Previous 'Orthotropic' closure approximation, i.e., ORF or ORL showed non-physical oscillation for interaction coefficient $C_1$<0.001 at simple shear flow. It also shows non-physcial oscillation and under-prediction compared with 'Distribution Function Calculation' at non-homogeneous flow of center-gated disk. These phenomena are mainly due to the flow data of 'Distribution Function Calculation' which were used for least-square optimization. ORW obtained by fitting flow data of low interaction coefficient does not show non-physical oscillation and results in reasonably good behaviors at non-homogeneous flows as well as homogeneous flows. Fitting function forms have not been found to improve overall behaviors. It has been found that considering all the eigenvalues of orientation tensor (including the third eigenvalues) might end up with a better closure approximation than just considering the first and second eigenvalues. It is, however, very important and yet difficult to select appropriate function forms of eigenvalues. Numerical simulation including coupling and in-plane velocity gradient effects were performed for injection mold filing process with a film-gated strip and a center-gated disk using ORW and various other closure approximations for comparisons. Although ORW is in excellent agreement with 'Distribution Function Calculation', the predicted results seem to have consistent error in comparison with experimental data. The diffusivity term with constant interaction coefficient might have to be further investigated in order to accurately describe orientation states.

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Flow Characteristics and Optimal Design for RDT Sparger (원자로배수탱크내 Sparger에 대한 유동특성 및 최적설계)

  • Kim, Kwang-Chu;Park, Man-Heung;Park, Kyoung-Suk;Lee, Jong-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1390-1398
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    • 1999
  • A numerical analysis for ROT sparger of PWR(Pressurized Water Reactor) is carried out. Computation is performed to investigate the flow characteristics as the change of design factor. As the result of this study, RDT sparger's flow resistance coefficient is K=3.53 at the present design condition if engineering mar&in is considered with 20%, and flow ratio into branch pipe is $Q_s/Q_i=0.41$. Velocity distribution at exit is not uniform because of separation in branch pipe. In the change of inlet flow rate and section area ratio of branch pipe for main pipe, flow resistance coefficient is increased as $Q_s/Q_i$ decreasing, but in the change of branch angle and outlet nozzle diameter of main pipe, flow resistance coefficient is decreased as $Q_s/Q_i$ decreasing. As the change rate of $Q_s/Q_i$ is the larger, the change rate of flow resistance coefficient is the larger. The change rate of pressure loss is the largest change as section area ratio changing. The optimal design condition of sparger is estimated as the outlet nozzle diameter ratio of main pipe is $D_s/D_i=0.333$, the section area ratio is $A_s/A_i=0.2$ and the branch angle is ${\alpha}=55^{\circ}$.

Removal of Sorbed Naphthalene from Soils Using Nonionic Surfactant (비이온성 계면활성제를 이용한 토양내 수착된 나프탈렌의 제거)

  • Ha, Dong-Hyun;Shin, Won-Sik;Oh, Sang-Hwa;Song, Dong-Ik;Ko, Seok-Oh
    • Journal of Environmental Science International
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    • v.19 no.5
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    • pp.549-563
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    • 2010
  • The environmental behaviors of polycyclic aromatic hydrocarbons (PAHs) are mainly governed by their solubility and partitioning properties on soil media in a subsurface system. In surfactant-enhanced remediation (SER) systems, surfactant plays a critical role in remediation. In this study, sorptive behaviors and partitioning of naphthalene in soils in the presence of surfactants were investigated. Silica and kaolin with low organic carbon contents and a natural soil with relatively higher organic carbon content were used as model sorbents. A nonionic surfactant, Triton X-100, was used to enhance dissolution of naphthalene. Sorption kinetics of naphthalene onto silica, kaolin and natural soil were investigated and analyzed using several kinetic models. The two compartment first-order kinetic model (TCFOKM) was fitted better than the other models. From the results of TCFOKM, the fast sorption coefficient of naphthalene ($k_1$) was in the order of silica > kaolin > natural soil, whereas the slow sorbing fraction ($k_2$) was in the reverse order. Sorption isotherms of naphthalene were linear with organic carbon content ($f_{oc}$) in soils, while those of Triton X-100 were nonlinear and correlated with CEC and BET surface area. Sorption of Triton X-100 was higher than that of naphthalene in all soils. The effectiveness of a SER system depends on the distribution coefficient ($K_D$) of naphthalene between mobile and immobile phases. In surfactant-sorbed soils, naphthalene was adsorbed onto the soil surface and also partitioned onto the sorbed surfactant. The partition coefficient ($K_D$) of naphthalene increased with surfactant concentration. However, the $K_D$ decreased as the surfactant concentration increased above CMC in all soils. This indicates that naphthalene was partitioned competitively onto both sorbed surfactants (immobile phase) and micelles (mobile phase). For the mineral soils such as silica and kaolin, naphthalene removal by mobile phase would be better than that by immobile phase because the distribution of naphthalene onto the micelles ($K_{mic}$) increased with the nonionic surfactant concentration (Triton X-100). For the natural soil with relatively higher organic carbon content, however, the naphthalene removal by immobile phase would be better than that by mobile phase, because a high amount of Triton X-100 could be sorbed onto the natural soil and the sorbed surfactant also could sorb the relatively higher amount of naphthalene.

A Parametric Study on the Sorption of U(VI) onto Granite (U(VI)의 화강암 수착에 대한 매개변수적 연구)

  • Min-Hoon Baik;Won-Jin Cho;Pil-Soo Hahn
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.2
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    • pp.135-143
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    • 2004
  • An experimental study on the sorption of U(VI) onto a Korean granite was performed as a function of the geochemical parameters such as contact time, pH, ionic strength, and carbonate concentration using a batch procedure. The distribution coefficient,$K_d$, was about 1-200 mL/g depending on the experimental conditions. The sorption of U(VI) onto granite particles was greatly dependent upon the contact time, pH, and carbonate concentration, but insignificantly dependent on the ionic strength. It was noticed that the sorption of U(VI) onto granite particles was highly correlated with the uranium speciation in the solution, which was dependent on the pH and carbonate concentrations. It was deduced from the kinetic sorption experiment that a two-step first-order kinetic behavior could dominate the kinetic sorption of U(VI) onto granite particles. In the alkaline range of a pH above 7, U(VI) sorption was greatly decreased and this might be due to the formation of anionic U(VI)-carbonate aqueous complexes as predicted by the speciation calculations.

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Experimental and numerical study on the earth pressure coefficient in a vertical backfilled opening

  • Jian Zheng;Li Li
    • Geomechanics and Engineering
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    • v.36 no.3
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    • pp.217-229
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    • 2024
  • Determining lateral earth pressure coefficient (EPC) K is a classic problem in geotechnical engineering. It is a key parameter for estimating the stresses in backfilled openings. For backfilled openings with rigid and immobile walls, some suggested using the Jaky's at-rest earth pressure coefficient K0 while other suggested taking the Rankine's active earth pressure coefficient Ka. A single value was proposed for the entire backfilled opening. To better understand the distributions of stresses and K in a backfilled opening, a series of laboratory tests have been conducted. The horizontal and vertical normal stresses at the center and near the wall of the opening were measured. The values of K at the center and near the wall were then calculated with the measured horizontal and vertical normal stresses. The results show that the values of K are close to Ka at the center and close to K0 near the wall. Furthermore, the experimental results show that the horizontal stress is almost the same at the center and near the wall, indicating a uniform distribution from the center to the wall. It can be estimated by analytical solutions using either Ka or K0. The vertical stress is higher near the center than near the wall. Its analytical estimation can only be done by using Ka at the center and K0 near the wall. Finally, the test results were used to calibrate a numerical model of FLAC2D, which was then used to analyze the influence of column size on the stresses and K in the backfilled opening.

A new quasi-3D sinusoidal shear deformation theory for functionally graded plates

  • Benchohra, Mamia;Driz, Hafida;Bakora, Ahmed;Tounsi, Abdelouahed;Adda Bedia, E.A.;Mahmoud, S.R.
    • Structural Engineering and Mechanics
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    • v.65 no.1
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    • pp.19-31
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    • 2018
  • In this paper, a new quasi-3D sinusoidal shear deformation theory for functionally graded (FG) plates is proposed. The theory considers both shear deformation and thickness-stretching influences by a trigonometric distribution of all displacements within the thickness, and respects the stress-free boundary conditions on the upper and lower faces of the plate without employing any shear correction coefficient. The advantage of the proposed model is that it posses a smaller number of variables and governing equations than the existing quasi-3D models, but its results compare well with those of 3D and quasi-3D theories. This benefit is due to the use of undetermined integral unknowns in the displacement field of the present theory. By employing the Hamilton principle, equations of motion are obtained in the present formulation. Closed-form solutions for bending and free vibration problems are determined for simply supported plates. Numerical examples are proposed to check the accuracy of the developed theory.