• Title/Summary/Keyword: dissolving

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Recovery of Copper Powder from MoO3 Leaching Solution (MoO3 침출공정 폐액으로부터 동분말의 회수기술)

  • Hong, Hyun-Seon;Jung, Hang-Chul;Kim, Geun-Hong;Kong, Man-Sik
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.351-357
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    • 2009
  • A two-step recovery method was developed to produce copper powders from copper chloride waste solution as byproducts of MoO$_3$ leaching process. The first step consisted of replacing noble copper ions with external Fe$^{3+}$ ions which were formed by dissolving iron scraps in the copper chloride waste solution. The replaced copper ions were subsequently precipitated as copper powders. The second step was cementation of entire solution mixture to separate (pure) copper powders from aqueous solution of iron chloride. Cementation process variables of temperature, time, and added amount of iron scraps were optimized by using design of experiment method and individual effects on yield and efficiency of copper powder recovery were investigated. Copper powders thus obtained from cementation process were further characterized using various analytical tools such as XRD, SEM-EDS and laser diffraction and scattering methods.Cementation process necessitated further purification of recovered copper powders and centrifugal separation method was employed, which successfully yielded copper powders of more than 99% purity and average 1$\sim$2$\mu$m in size.

Reduction Method of Porosity Formed by Instability of Keyhole in High Power $CO_2$ Laser Welding (고출력 $CO_2$레이저 용접에서 키홀의 불안정으로 발생한 기공의 절감방법)

  • 김정일;조민현
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.4
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    • pp.464-471
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    • 2002
  • Porosity formation in partial penetration welds by high power lasers is a serious problem in industry. There are two main causes that induce porosity formation. One form of porosity is due to gases (e.g. hydrogen, oxygen) dissolving into the weld pool because of the high temperature and then the rapid solidification traps gases as a bubble in the weld metal. The second problem is voids formed by the keyhole collapsing due to unstable keyhole fluid dynamics. The voids that form at the bottom of the keyhole are relatively large and irregular in shape compared to the gas bubbles; this void formation is the primary concern in this paper. The reduction of voids formed by keyhole collapse is achieved by improving the stability of keyhole. Two methods to improve keyhole stability are discussed in this paper: pulse modulation and beam incident angle. Pulse modulation of the laser beam was performed between 100 Hz and 500 Hz to find out the optimum frequency for the keyhole dynamics. The incident beam angle changed the impact angle of the laser beam to the work surface in a range of 0 to 25 degrees. Glycerin in a semi-solidified state is used as a medium for performing the welding because its transparency allows of visualization of the keyhole.

Dyeing of Wool at Low Temperature - focusing on solubility parameter$(\delta)$ - (양모의 저온 염색(1) - 용해도 파라미터$(\delta)$를 중심으로 -)

  • 도성국
    • Textile Coloration and Finishing
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    • v.15 no.6
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    • pp.55-62
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    • 2003
  • Wool fabrics were dyed with the aqueous solution of C. I. Red Acid 114 mixed with methanol dissolving three kinds of barely water soluble ketones, acetophenone, 2-pentanone, and 3-pentanone. The steric hinderance and the orientation of the bigger hydrophobic part of the solvated dye molecules to the fiber slowed down the dying rate, however, loosening the wool molecule, say a little swelling, disaggeregating the dye molecules, and attaining the higher dye concentration on the fiber surface by the added solvents increased the amount of dye on the fabric. The higher concentration or/and the higher dyeing temperature helped loosen fiber molecules and made it easier for the solvated dye molecules to penetrate into the inside of the fiber. Acetophenone, the most influential solvent used, showed that the ability to loosen fiber molecules was the most important of all the three positive solvent actions mentioned above. The considered mechanism provided before reflected the fact that the dye uptake on the fabric dyed with the solvents included, except for 0.034M and 0.051M of acetophenone, was even lower than that without any solvents at $50^\circ{C}$, but all the solvents added to the dye bath increased the dye uptake on the fiber at $70^\circ{C}$.

The Stability of Water-soluble and Fat-soluble vitamin in milk by Heat treatments (수용성비타민과 지용성비타민의 가열에 대한 안정성)

  • 허정윤;황인경
    • Korean journal of food and cookery science
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    • v.18 no.5
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    • pp.487-494
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    • 2002
  • This study was conducted to investigate the thermal stability of water-soluble and fat-soluble vitamins dissolved in water and milk by various heat treatments. Vitamin samples were prepared by dissolving them in water and milk at various concentrations, and were heat treated for 30 min at 65$\^{C}$, 15 sec at 85$\^{C}$, 5 sec at 100$\^{C}$, 121$\^{C}$ at 15 min, the levels of residual vitamin were measured by using HPLC. Milk samples were fortified with vitamins before and after UHT treatment. As heating over 100$\^{C}$, riboflavin in water were destructed more than 92% but fortified in milk showed less than 20% destruction, suggesting that riboflavin was protected by milk components. Also retinol heated ever 100$\^{C}$ was more stable in milk than in water. L-Ascorbic acid and cholecalciferol(D$_3$) showed a similar destruction rate in water and in fortified milk. L-ascorbic acid was easily destructed by UHT treatment. Destruction of thiamin and tocopherol was increased in fortified milk. Among tour capsulated water-soluble vitamins, L-ascorbic acid was much more stable compared with powder form. Nicotinic acid and folic acid either in capsule or powder form showed a slight destruction by heat treatment. The results suggested that the fortification of unstable vitamins such as L-ascorbic acid, thiamin, tocopherol and cholecalciferol(D$_3$) should be made in milk after heat treatment.

Rheological behavior and wall slip of dilute and semidilute CPyCl/NaSal surfactant solutions

  • Kibum Sung;Han, Min-Soo;Kim, Chongyoup
    • Korea-Australia Rheology Journal
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    • v.15 no.3
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    • pp.151-156
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    • 2003
  • In this research, experimental studies were performed to examine the rheological behavior of equimolar solutions of cetylpyridinium chloride (CPyCl) and sodium salicylate (NaSal) solutions with concentration. The surfactant solutions were prepared by dissolving 2 mM/2 mM - 80 mM/80 mM of surfactant/counterion in double-distilled water. It has been observed that the zero shear viscosity shows abrupt changes at two critical values of C^*$ and C^{**}$. These changes are caused by the switching of relaxation mechanism with concentration of CPyCl/NaSal solutions at those concentrations. The wall slip velocities of dilute and semidilute CPyCl/NaSal solutions show a dramatic increase with shear rate where the shear viscosity exhibits shear thickening behavior for dilute solutions and shear thinning behavior for semi-dilute solutions, respectively. Considering that the dramatic increase in wall slip velocity should be related to the formation of shear-induced structure (SIS) in the surfactant solution, the shear thickening behavior of semi-dilute solutions is caused by elastic instability unlike the case of dilute solutions.

Chemical and Mechanical Properties of Yellow Poplar Pulp Produced by Formic Acid- Hydrogen Peroxide Pulping (개미산-과산화수소 펄핑에 의하여 생산된 백합나무 펄프의 화학적 및 역학적 특성 분석)

  • Sim, Jaehoon;Kim, Jeong-Ho;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.6-12
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    • 2013
  • TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

A Study on the Hybrid Algorithm for Scene Change Detection (장면전환검출을 위한 Hybrid 알고리즘에 관한 연구)

  • 이문우;박종운;장종환
    • Journal of the Korea Computer Industry Society
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    • v.2 no.4
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    • pp.507-520
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    • 2001
  • In this paper, a hybrid algorithm for well detecting both abrupt and gradual scene changes is proposed. This algorithm examines only the candidate intervals for speedup using the binary tree method and skips the intervals that are not candidate. For accuracy, the temporal difference of variance is used to detect the gradual scene changes while the temporal difference of histogram is used to detect the abrupt scene changes. Experimental results show that the proposed hybrid algorithm using the binary tree method works up about 10 times faster that the sequential method and is effective in detecting abrupt scene change and gradual transitions including dissolving and fading.

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Ubiquitous Architectural Framework for UbiSAS using Context Adaptive Rule Inference Engine

  • Yoo, Yoon-Sik;Huh, Jae-Doo
    • Proceedings of the Korea Society of Information Technology Applications Conference
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    • 2005.11a
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    • pp.243-246
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    • 2005
  • Recent ubiquitous computing environments increasingly impact on our lives using the current technologies of sensor network and ubiquitous services. In this paper, we propose ubiquitous architectural framework for ubiquitous sleep aid service(UbiSAS) in the subset of ubiquitous computing for refreshing of human's sleep. And we examine technical feasibility. Human can recover his health through refreshing sleep from fatigue. Ubiquitous architectural framework for UbiSAS in digital home offers agreeable sleeping environment and improves recovery from fatigue. So we present new concept of ubiquitous architectural framework dissolving stress. Specially, we apply context to context-aware framework module. This context is transferred to context adaptive inference engine which has service invocation function in intelligent agent module. Ubiquitous architectural framework for UbiSAS using context adaptive rule inference engine without user intervention is technical issue. That is to say, we should take sleep comfortably during our sleeping. And sensed information during sleeping is changed to context-aware information. This presents significant information in context adaptive rule inference engine for UbiSAS. This information includes all sleeping state during sleeping in context-aware computing technique. So we propose more effective and most suitable ubiquitous architectural framework using context adaptive rule inference engine for refreshing sleep in this paper.

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Application of Ojuck-san in Hyungsang Medicine (오적산의 형상의학적 고찰)

  • Kang Kyung Hwa;Kang You Shik;Lee Yong Tae
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.18 no.2
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    • pp.389-395
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    • 2004
  • Conclusion are drawn from the clinical cases susceptible to Ojuck-san(吳積散) in Hyungsang medicine, as follows ; Ojuck-san is effective to those diseases caused by cold and damp(寒濕). Because cold and damp belongs to Yin pathogeny, Ojuck-san is mainly applied to Yin syndrome of Bangkwang type persons. Ojuck-san is effective in dissolving five kinds of masses accumulated in abdomen, so that it is preferential to the patients who have masses around the umbilicus or in lower abdomen. Ojuck-san is referred in the following chapters of Dongeuibogam(東醫寶鑑) ; uterus, chest, abdomen, loin, upper limbs, lower limbs, cold, and damp. Ojuck-san is applicable to the persons with the following characteristics in Hyungsang; Jijjucksang(地積象), woman, Bangkwang type, fish type, Hyul type, Ki type, Gualeum meridian type, pale lip, bluish thenar eminence, big mouth, smudgy face, thick leg, potbelly and big hips.

Insecticidal Efficacy of Porteresia coarctata (Roxb.) on Bio-chemical Alteration of Spodoptera litura (Fab.)

  • Bhattacharyya Atanu;Goswami Arunava;Dihidar Shankar;Adhikari Sujit;Banerjee Sudip Kumar;Talapatra Soumendra Nath;Barik Bikas Ranjan;Bhattacharya Subir Kumar;Chandra Asit Kumar
    • International Journal of Industrial Entomology and Biomaterials
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    • v.14 no.1
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    • pp.9-13
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    • 2007
  • Hexane extract of Porteresia coarctata (Roxb.) exhibits a toxic effect on the tissues of Spodoptera litura (F) while fed at the dose of 1000 and 2000 ppm thoroughly mixing with castor leaves (Ricinus communis L) after dissolving in DMSO at late fourth instar whereas only DMSO treated castor leaves were fed to control group. The larvae were put to rear at $28^{\circ}C{\pm}1^{\circ}C$, $76{\pm}4%$ R.H. under 12 L + 12 D photoperiodic regime. In test group insects substantial reduction of protein and DNA content was marked in fat body and midgut tissues compared to DMSO treated control group. The significant biochemical alterations in the midgut tissues and fat body of test group insects indicate the insecticidal property of the said plant extract that could be tested in facilitating the phenomenal stride in Integrated Pest Management.