• Journal of the Mineralogical Society of Korea
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• v.18 no.2
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• pp.117-125
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• 2005

It is common to find lots of organic and inorganic precipitates inside of industrial cooling system. Analytical instruments including ICP-AES, IC, XRD, and SEM were used to investigate the effects of application of Mg on reaction among coolant, precipitates and suspended matters within chiller system. Magnesium (Mg) has a decreasing effect on total dissolved material in the coolant suggesting a significant improvement of quality of coolant. Disappearance of most organic materials in the cooling devices also suggests an inhibitive effect on the growth of organic matters.

• Journal of Environmental Health Sciences
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• v.27 no.2
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• pp.60-66
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• 2001

Natural organic matters(NOMs) are found everywhere such as soil, surface and ground waters and consist of both humic and nonhumic components, and their heterogeneith makes each source unique. This study was carried to evaluate the removal characteristics of NOMs by mixing coagulants and the variation of apparent molecular weight distribution(AMWD) in coagulation process. Ratio of optimum coagulants dosage for removal of DOC and turbidity by mixing coagulants was 1.83 mM F $e^{3+}$/mM $Al^{3+}$. DOC removal increased at lower pH. The pH6 control focused on the removal of organic matters could reduce the amount of coagulant consumption by 2 to 3 times based on the pH8.5 of natural water. The dissolved organic matters in the natural water from the mid-stream of Han River were composed of the low molecular weight(LMW,<1 K) of 59.7%, and the medium and high molecular weight(M.HMW, 1~30 K) of 40.3%, respectively. At pH6, the DOC removal efficiencies of LMW(<1 K) and M.HMW(1~30 K) in coagulation process were 27~35%, 62~72%, respectively. The fraction smaller than 1 K was not eliminated to a noticeable degree, while the fraction of 1~30 K was relatively well removed. In conclustion, mixing coagulants were fairly effective in the removal of natural organic matter.r.

• Membrane Journal
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• v.21 no.2
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• pp.127-140
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• 2011

The effects of $TiO_2$ photocatalyst coating bead concentration, water-back-flushing period (FT), and back-flushing time (BT) were investigated in hybrid process of ceramic ultrafiltration and photocatalyst for advanced drinking water treatment in this study. Photocatalyst coating bead concentration was changed in the range of 10~40 g/L, FT in 2~10 min and BT in 6~30 sec. Then, we observed the effects on resistance of membrane fouling $(R_f)$, permeate flux (J) and total permeate volume $(V_{\Upsilon})$ during total filtration time of 180 min. As decreasing photocatalyst coating bead concentration, $R_f$ increased and J decreased. $V_{\Upsilon}$ was the highest value of 8.85 L at 40 g/L of photocatalyst coating bead concentration. At FT change experiment, $R_f$ decreased and J increased as decreasing FT. Then $R_f$ decreased and J increased according to increasing BT at BT change experiment. Because at NBF (no back-flushing) dramatic membrane fouling reduced membrane pore size, turbid and dissolved organic matters ($UV_{254}$ absorbance) could be removed efficiently. Therefore, treatment efficiencies of turbidity and dissolved organic matters were the highest at NBF. Then by cleaning effect of photocatalyst coating bead, the treatment efficiencies of turbidity and dissolved organic matters increased as decreasing FT and increasing BT.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.2
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• pp.242-246
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• 2004

Dissolved air flotation (DAF) is an effective solid/liquid separation process for low density particles, such as algal flocs, humus materials and clay particles produced from low turbidity water. The fraction of humic substances for natural organic matters (NOMs) are considered problematic in water because it can readily react with chlorine to form harmful by-products (trihalomethanes) and can be exposed to undesirable color, tastes and odors in drinking water. A broad class of NOMs includes fulvic acid, humic acid and humin. This paper will discuss the results from a study that performed with a DAF pump process using synthetic wastewater contained humic substance. Batch jar tests were performed to evaluate coagulant dose and recycle ratio on flotation efficiency.

• Journal of environmental and Sanitary engineering
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• v.16 no.3
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• pp.34-41
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• 2001

It is well known that bioassay on the low organic matters in water have developed from the two methods. One is assimilable organic carbon(AOC) that makes use of the maximum growth biomass of the pure strains for the standard substrates, the other is biodegradable dissolved organic carbon(BDOC) that determines the fraction of dissolved organic carbon(DOC) available for microbial utilization. The purpose of this study was to upgrade the measurement method of BDOC in natural water or drinking water. BBOC was determined by means of the bacterial growth and the DOC decrease at the same time. The origin inoculums were used to the suspended bacteria from Han River water, The initial optimum biomass and incubation time for initial DOC were induced by variation of nutrient repression and inoculums. The time reached to minimum DOC was selected as incubation time. The initial optimum biomass for Han river water was about 1000~5000 CFU/mL, respectively. In a sufficient biomass, suitable incubation time was about 3~5 day. It was indirectly calculated BDOC on maximum growth rate by measuring growth yield of indigenous bacteria. But it was difficult to adapt growth yield coefficient because of irregular bacterial growth. The measured 3 day BDOC was close to BDOC calculated with our proposed experimental equation between DOC and BDOC. It shows that the quantification of BDOC with this experimental equation can be used indirectly.

• Journal of Korean Society on Water Environment
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• v.37 no.5
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• pp.355-362
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• 2021

This study investigated the fate of dissolved organic matter (DOM) in a water reclamation facility (WRF) in Korea. The WRF consists of coagulation, sedimentation, microfiltration, and reverse osmosis (RO) components. The production capacity of WRF is 90,000 m³/day. The reclaimed water is reused as industrial water. We also characterized DOM in raw, processed, and finished waters based on analysis of dissolved organic carbon (DOC), ultraviolet absorbance at 254 nm (UVA₂₅₄), fluorescence excitation emission matrix (FEEM), and DOC fractions via liquid chromatography-organic carbon detection (LC-OCD). Based on the results of DOC, UVA₂₅₄, and FEEM analyses, neither the coagulation/sedimentation nor the microfiltration at the WRF effectively removed DOM. The RO process removed more than 94% of DOM. The raw water (i.e., secondary treated effluent obtained from a wastewater treatment plant) exhibited tryptophan-like peaks, which are a promising marker of wastewater, in the FEEM analysis. Coagulation and microfiltration failed to eliminate the wastewater marker, whereas RO completely removed it. The raw water also carried high levels (89.4%) of hydrophilic and low-molecular weight substances, which are difficult to remove via coagulation-sedimentation or microfiltration. Humic substance was a major component of the hydrophilic fractions. Based on the LC-OCD analysis, RO effectively removed the humic and polymeric materials from DOM.

• Journal of Wetlands Research
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• v.14 no.4
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• pp.629-635
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• 2012

This study was conducted to evaluate the removal behaviors of DOM(dissolved organic matter) and phosphorus in eutrophic lake water by coagulation process with PAC(powdered activated carbon). It was observed that the removal characteristic of soluble matter was different from that of dissolved one, and the removal of DOM was effected by both pH and coagulant dosage. It was founded that PAC could increase the removal efficiency by an adsorption of DOM in coagulation process. A formation of soluble and colloidal matters resulted in the degradation of phosphorus removal efficiency in a chemical precipitation process. The phosphorus removal efficiency could be enhanced by an absorption of colloidal matter and dissolved complex with PAC addition. In addition, the PAC addition caused the increase of floc density in coagulation process, that led to the rise of sedimentation rate, and resulted in a significant improvement of solid-liquid separation efficiency.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.9
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• pp.893-899
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• 2008

Changes in spectroscopic characteristics and pyrene binding coefficients of terrestrial dissolved organic matters(DOM) were investigated during microbial incubation. The incubation studies were conducted for 21 days using a leaf litter DOM and a soilderived DOM with an inoculum from a river. The dissolved organic carbon(DOC), the specific UV absorbance(SUVA), the synchronous fluorescence spectra, and the pyrene organic carbon-normalized binding coefficient(K$_{oc}$) of the DOM were measured at the incubation days of 0, 3, 7, 14 and 21. After the 21-day incubation, DOC were reduced to 61% and 51% of the original concentrations of the litter DOM and the soil-derived DOM, respectively. Comparison of the spectroscopic characteristics before and after the incubation revealed that the SUVA, the fulvic-like fluorescence(FLF), the humic-like fluorescence(HLF) of the different DOM were enhanced by the incubation whereas the protein-like fluorescence(PLF) was reduced. This indicates that more aromatic and humic-like compounds were enriched during the biodegradation process while biodegradable and weak carbon structures were depleted. Irrespective of the DOM sources, SUVA values showed a positive relationship with pyrene K$_{oc}$ with a correlation coefficient of 0.97. The FLF and HLF also exhibited good correlations with K$_{oc}$ values although different regression equations were obtained from the different DOM. Our results suggest that the selected spectroscopic characteristics could be good estimation indices for the changes of the binding reactivity of DOM for hydrophobic organic contaminants during biodegradation process.

• Journal of Korean Society on Water Environment
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• v.20 no.1
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• pp.55-62
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• 2004

This study was carried out to investigate the formation of DBPs(Disinfection By-products) such as trihalomethane(THMs) and haloacetic acid(HAAs) by chlorination in raw water and finished water of Water Treatment Plant(WTP). The formation of THMs was increased with the increase of pH and reaction time. HAAs was found as a high formation at a pH 7 and low formation at pH 9. THMFP(Trihalomethane Formation Potential) was the highest formation potential in raw water of Pu-1 and the lowest in raw water of Pa-1. In case of HAAFP(Haloacetic acid formation potential), So-1 showed the highest value, while Pa-1 showed the lowest value. It was investigated the relationship between HAAs and organic matters which were described as DOC(dissolved organic carbon) and $UV_{254}$. In both DOC and $UV_{254}$ versus HAAFP, Pu-1 showed the good correlation coefficients($r^2$) with 0.95 and 0.84, respectively. For three WTP investigated, DBPs(THMs + HAAs) was shown over the range of $42.00{\sim}49.36{\mu}g/L$. This result might be due to the different characteristic of organic matters in raw water and the difference of chlorine dosage for a water treatment.

• Journal of Korean Society on Water Environment
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• v.25 no.5
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• pp.697-703
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• 2009

In this study, changes in the composition of dissolved organic carbon (DOC) were investigated using water samples collected at a downstream site of the Namhan River near the Lake Paldang ($N37^{\circ}24^{\prime}05.33^{{\prime}{\prime}}E127^{\circ}32^{\prime}25.01^{{\prime}{\prime}}$) during a heavy rain event from July 23 to July 28, 2008. The DOC concentrations varied from 1.68 to 3.18 mg/L with the maxium value at a peak of the river water level. Each DOC sample was fractionated into three compositions including hydrophilic (Hi), hydrophobic acid (HoA) and hydrophobic neutral (HoN) fractions. The results showed that HoA was most abundant fractions, constituting 47.2~56.5% of DOC. Refractory dissolved organic carbon (R-DOC) contents were also determined by measuring the DOC concentration after 28-day dark incubation of the samples. R-DOC content was in the range from 83 to 99% of DOC and it was significantly correlated with HoA contents (r = 0.91, p<0.005), while it did not exhibit such a good correlation with the fractions of Hi and HoN (p>0.02). Our results suggest that the HoA, which is associated with humic substances, may be a major composition of refractory organic matters in rivers during storm events.