• Title/Summary/Keyword: dissolved gas in oil

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Antioxidative Effectiveness of Methanol Extract in Galla Rhois (오배자(Rhus japonica Linne) Methanol 추출물의 황산화효과)

  • 김태철;이기동;윤형식
    • Journal of Food Hygiene and Safety
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    • v.7 no.2
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    • pp.107.1-112
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    • 1992
  • Free-, soluble- and insoluble phenolic acids were extracted from defatted Galla Rhois. The extracts were then dissolved in equal amounts of an soybean oil, and POV (peroxide value) of the resulting substrates, portion of the soybean oil (control) and 0.02% BHT were measured by AOM (active oxygen method) test at 97.8$^{\circ}C$ for 40 hours through Rancimat method. Induction period of control, BHT, free phenolic acids, soluble phenolic acids and insoluble phenolic acids by the Rancimat method were 4.8, 10.5, 23.9 and 30.5hr. The phenolic acids separated and tentati-vely identified by gas chromatography were catechol, gallic acid, vanillin, protocatechuic acid, syri-ngic acid, ferulic acid.

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A Fault Diagnosis Method of Oil-Filled Power Transformers Using IEC Code based Neuro-Fuzzy Model (IEC 코드 기반의 뉴로-퍼지모델을 이용한 유입변압기 고장진단 기법)

  • Seo, Myeong-Seok;Ji, Pyeong-Shik
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.65 no.1
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    • pp.41-46
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    • 2016
  • It has been proven that the dissolved gas analysis (DGA) is the most effective and convenient method to diagnose the transformers. The DGA is a simple, inexpensive, and non intrusive technique. Among the various diagnosis methods, IEC 60599 has been widely used in transformer in service. But this method cannot offer accurate diagnosis for all the faults. This paper proposes a fault diagnosis method of oil-filled power transformers using IEC code based neuro-fuzzy model. The proposed method proceeds two steps. First, IEC 60599 method is applied to diagnosis. If IEC code can't determine the fault type, neuro-fuzzy model is applied to effectively classify the fault type. To demonstrate the validity of the proposed method, experiment is performed and its results are illustrated.

Fault Diagnosis of Oil-filled Power Transformer using DGA and Intelligent Probability Model (유중가스 분석법과 지능형 확률모델을 이용한 유입변압기 고장진단)

  • Lim, Jae-Yoon;Lee, Dae-Jong;Ji, Pyeong-Shik
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.65 no.3
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    • pp.188-193
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    • 2016
  • It has been proven that the dissolved gas analysis (DGA) is the most effective and convenient method to diagnose the transformers. The DGA is a simple, inexpensive, and non intrusive technique. Among the various diagnosis methods, IEC 60599 has been widely used in transformer in service. But this method cannot offer accurate diagnosis for all the faults. This paper proposes a fault diagnosis method of oil-filled power transformers using DGA and Intelligent Probability Model. To demonstrate the validity of the proposed method, experiment is performed and its results are illustrated.

Study on the Dissolution Characteristics of Liquid $CO_2$ Released by Fixed Pipeline (고정 파이프라인에서 분사된 액체 이산화탄소 용해특성 연구)

  • 김남진;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.9
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    • pp.863-871
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    • 2004
  • The use of fossil fuels like coal, oil and natural gases around the world causes an increase of the carbon dioxide content in the atmosphere. In order to reduce the concentration of the greenhouse gas, the idea of carbon dioxide sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect. Therefore, in the present study, calculations of the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth by fixed pipeline are performed. The results show that carbon dioxide droplets change to carbon dioxide bubbles in gas phase around 500m in depth, and the droplets are completely dissolved below 500 m in depth if the liquide carbon dioxide is released both at 1,000 m in depth with the initial diameter of 0.007m or less and at 1,500m in depth with the diameter of 0.011m or less.

Rapid Gas Chromatographic Screening of Vegetable Oils for Free Fatty Acids (기체크로마토그래피법에 의한 식물성 유지내 유리 지방산의 신속한 스크리닝)

  • Kim, Jung-Han;Kim, Kyoung-Rae;Chai, Jeong-Young;Oh, Chang-Hwan;Park, Hyung-Kook
    • Korean Journal of Food Science and Technology
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    • v.25 no.4
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    • pp.373-378
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    • 1993
  • A rapid gas chromatographic profiling method for the simultaneous analysis of free fatty and other acids was applied to vegetable oils. Oil samples were dissolved in dichloromethane and the free acids were extracted with saturated $NaHCO_3$ solution. The aqueous extract was acidified and then loaded onto the Chromosorb P column for the extraction. The acids were eluted with diethyl ether selectively from Chromosorb P column and were treated with triethylamine to prevent the losses of volatile acids. Several long chain fatty acids were detected from soybean oil, rice-bran oil, sesame oil and perilla oil. Various organic acids including odd number fatty acids were detected in crude oil, especially sesame oil. Arachidic acid from perilla oil and vanillic acid from sesame oil, which were not reported before were detected. The content ratio of free linoleic acid to oleic acid was $1.02{\sim}1.18$, which was similar to the reported data. When the GC profile of organic acids were simplified to their corresponding retention index spectra of bar graphical forms, they presented characteristic pattern of each vegetable oil that can be quickly recognized.

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Improvement in Transformer Diagnosis by DGA using Fuzzy Logic

  • Dhote, Nitin K.;Helonde, J.B.
    • Journal of Electrical Engineering and Technology
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    • v.9 no.2
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    • pp.615-621
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    • 2014
  • Power transformer is one of the most important equipments in electrical power system. The detection of certain gases generated in transformer is the first indication of a malfunction that may lead to failure if not detected. Dissolved gas analysis (DGA) of transformer oil has been one of the most reliable techniques to detect the incipient faults. Many conventional DGA methods have been developed to interpret DGA results obtained from gas chromatography. Although these methods are widely used in the world, they sometimes fail to diagnose, especially when DGA results falls outside conventional method codes or when more than one fault exist in transformer. To overcome these limitations, fuzzy inference system (FIS) is proposed. 250 different cases are used to test the accuracy of various DGA methods in interpreting the transformer condition.

Corrosion Behaviour of DH36 Steel Used for Oil Platform in Splash Zones

  • Liu, J.G.;Li, Y.T.;Hou, B.R.
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.190-194
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    • 2015
  • The splash zone is the most corrosive area of the marine environment, and the corrosion of steel structures exposed in this area is a serious concern. DH36 steel is one of most commonly used steels for offshore oil platforms in China, and its corrosion behaviour in splash zones was studied in this paper. Polarization curves were obtained from the corroded steel exposed in this area while the morphologies and rusts of the rust steel were characterized using scanning electron microscopy and X-ray diffraction. Double rust layers were formed in the splash zone. The inner layer contained magnetite and fine flaky lepidocrocite, and the outer layer was composed of accumulated flaky lepidocrocite and a small amount of goethite. In the wet period, the iron dissolved and reacted with lepidocrocite, and magnetite appeared, while the magnetite was oxidized to lepidocrocite again during the dry period. Electrochemical reduction and chemical oxidization cycled in intermittent wetting and drying periods, and magnetite and lepidocrocite were involved in the reduction reaction, leading to serious corrosion.

Application of gas sensor for measuring dissolved hydrogen gas in oil (유중 수소가스측정을 위한 가스센서 적용성 연구)

  • Sun, J.H.;Han, S.B.;Kim, K.H.;Kang, D.S.
    • Proceedings of the KIEE Conference
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    • 2007.04b
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    • pp.125-127
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    • 2007
  • 본 논문에서는 세 가지 종류의 가스센서를 사용하여 수소가스에 대한 정량화 및 선택도를 향상시키기 위한 연구를 수행하였다. 여러 가지 수소가스 농도에 대한 각 가스센서들의 출력을 측정하였고 높은 출력과 분해능특성을 보이는 농도범위를 분석한 결과 세 가지 종류의 센서의 사용은 10,000ppm까지의 광대역의 수소 가스농도를 신뢰성 있게 측정할 수 있는 가능성을 보여주었다. 또한 어떠한 농도의 메탄(CH4) 및 일산화탄소에 대한 출력과 수소에 대한 출력을 비교한 결과 세 가지 센서의 출력을 조합하면 수소가스의 선택성을 향상시킬 수 있는 것으로 나타났다.

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The Characteristics of Shallow Groundwater in Petroleum Contaminated Site and the Assessment of Efficiency of Biopile by Off-gas Analysis (유류오염지역의 지하수 수질특성과 토양가스 분석을 통한 바이오파일의 효율평가)

  • Cho, Chang-Hwan;Sung, Ki-June
    • Journal of Soil and Groundwater Environment
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    • v.18 no.2
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    • pp.36-44
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    • 2013
  • The objectives of this study were to identify the characteristics of shallow groundwater from the oil-contaminated site for a long period and to evaluate the applicability of biopile technology to treat the soil excavated from it. The eight monitoring wells were installed in the contaminated site and pH, Electrical Conductivity (EC), Dissolved Oxygen (DO), Oxidation Reduction Potential (ORP), Temperature and the concentrations of major ions and pollutants were measured. The VOCs in soil gas were monitored during biopile operation and TPH concentration was analyzed at the termination of the experiment. The pH was 6.62 considered subacid and EC was 886.19 ${\mu}S/cm$. DO was measured to be 2.06 mg/L showing the similar characteristic of deep groundwater. ORP was 119.02 mV indicating oxidation state. The temperature of groundwater was measured to be $16.97^{\circ}C$. The piper diagram showed that groundwater was classified as Ca-$HCO_3$ type considered deep groundwater. The ground water concentration for TPH, Benzene, Toluene, Xylene of the first round was slightly higher than that of the second round. The concentration of carbon dioxide of soil gas was increased to 1.3% and the concentration of VOCs was completely eliminated after the 40 days. The TPH concentration showed 98% remediation efficiency after the 90 days biopile operation.

Electrical resistivity monitoring of a scale model experiment for geological $CO_2$ sequestration (전기비저항에 의한 지중저장 이산화탄소 거동관측 모의실험)

  • Park, Mi-Kyung;Jang, Han-Nu-Ree;Kim, Hee-Joon;Wang, Soog-Yun;Lee, Min-Hee
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.06a
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    • pp.173-178
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    • 2007
  • Time-lapse electrical resistivity measurements have been made in a scale model experiment for geological $CO_2$ sequestration in aquifer. Three types of $CO_2$ injection are tested in a water tank filled with glass beads. These are $CO_2$ dissolved into filtered tap water, $CO_2$ gas, and mineral oil. The mineral oil is a substitute for liquid phase of supercritical $CO_2$. For reconstructing three-dimensional resistivity images, we measure potential differences at 32 potential dipoles on the top surface of the tank due to two current dipoles on the front and back sides. The resultant resistivity images clearly show the movement of injected $CO_2$ in aquifer.

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