• Title/Summary/Keyword: dissolved agency

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Numerical Simulation of Groundwater Flow in Feterogenetic Rockmass of Unsaturated Condition (암반의 불균질성을 고려한 불포화대 지하수 유동 평가)

  • Ha, Jaechul;Lee, Jeong Hwan;Cheong, Jae-yeol;Jung, Haeryong
    • The Journal of Engineering Geology
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    • v.26 no.1
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    • pp.87-99
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    • 2016
  • We present the results of two-dimensional numerical simulations predicting the flow of groundwater in a fractured unsaturated zone. We applied the k-field distribution of permeability derived from discrete fracture network (DFN) modeling as the hydraulic properties of a model domain. To model an unsaturated zone, we set the depth from the ground surface to the underground aquifer. The rate of water infiltration into the unsaturated zone was divided into two parts, an artificial structure surface and unsaturated soil zone. The movement of groundwater through the unsaturated zone was simulated with particular emphasis on contaminant transport. It was clearly observed that the contaminants dissolved in groundwater transported vertically from the ground surface to the saturated zone.

Determination of lead content in the plastic by ICP and AAS using HI reduction - PbSO4 dissolution method (HI 환원-PbSO4용해법을 이용한 ICP와 AAS에 의한 플라스틱 중의 납 정량 방법)

  • Lee, Hyun-Ja;Kim, Sang-Kyung;Lee, Se-Jin;Lee, Hyun-A
    • Analytical Science and Technology
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    • v.17 no.5
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    • pp.369-374
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    • 2004
  • Plastic was decomposed with nitric acid after being carbonized by sulfuric acid. Then excess sulfuric acid and nitric acid was removed by evaporating and drying. Precipitated $SO{_4}^{-2}$ ion of $PbSO_4$ was resolved itself into $H_2S$ by HI in hydrochloric acid and was volatilized. Then $Pb^{+2}$ was dissolved and was measured by AAS and ICP. The test for reproducibility using PVC-Pb standard material (690-34610mg/kg) was conducted and the accuracy was more than 99.9% compared with the estimated concentration. The precision by AAS was 99.8% and that of ICP was 99.9%.

The Effect of Dissolved Oxygen on the Estival Mass Mortality of sea squirt, Halocynthia roretzi(Drasche) (여름철 우렁쉥이 대량폐사에 대한 용존산소의 영향)

  • NA Gui-Hwan;LEE Chae-Sung;CHOI Woo-Jeung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.1
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    • pp.52-58
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    • 1991
  • Mass mortality of Halocynthia roretzi has been occurred in culturing grounds of southern coast of Korea during the long period of summer drought and the unusal high water temperature in 1988. Especially Halocynthia roretzi was damaged severely in 2 years group. Therefore we verified these phenomena by observing the environmental factors of culturing grounds and by evaluating oxygen consumption rate in indoor experiment. In culturing grounds, the mortality rate was high in Namhae Mizo area where water temperature was the highest and the lowest in dissolved oxygen concentration as low as 3.76m/l in field observation. In indoor experiment, the higher the water temperature, the more mortality was occurred and the salinity above 30 had no effect on its mortality. In oxygen consumption rate experiment, the smaller needs more oxygen than larger one, i. e., oxygen demand per unit weight was higher in 2 years group than that of 3 years. The theoretical and the actual minimum oxygen demands(MOB) for preventing asphixation was 3.7ml/kg/h at $20^{\circ}C$ and 6.3ml/kg/h gat $25^{\circ}C$, But actual MOD was 4.3ml/kg/h at $25^{\circ}C$ in indoor experiment. It seemed that mass mortality of Halocynthia roretzi in summer was caused by metabolism disorder due to insufficient oxygen level influenced by the high water temperature and the high density of Halocynthia roretzi, which results in the paucity of oxygen especially in 2 years groups.

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Self-purification Capacity of Eutrophic Buk Bay by DO mass Balance (부영양화된 북만의 용존산소 수지에 의한 자정능력)

  • CHOI Woo-Jeung;NA Gui-Hwan;CHUN Young-Yell;PARK Chung-Kil
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.1
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    • pp.21-30
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    • 1991
  • In Summer, oxygen-deficient water masses were developed extensively in the closed eutrophic bays such as Chinhae Bay which results in mass mortality of marine organisms and severe decrease the production of the bay every year. Under the circumstances, this study was performed to investigate the oxygen depletion relating to eutrophication, and also to evaluate self-purfication capacity of Buk Bay by dissolved oxygen mass balance in 1988. The mean concentration of total inorganic nitrogen, phosphate phosphorus and chlorophyll-a were $11.06{\mu}g-at/l,\;0.80{\mu}g-at/l\;and\;1.11mg/m^3$ respectively, which were over eutrophication criteria. Oxygen-deficient water mass was formed in July with the minimum concentration of 2.08ml/l(mean) at the bottom of all stations and recovered slowly in August. The decay and reaeration coefficient calculated from dissloved oxygen sag curve were 0.222/day and 0.018ml/l/day, respectively. To maintain above 4ml/l of oxygen to prevent oxygen-deficient water mass, it is recommendable to supply as much as 0.856ml/l/day of dissolved oxygen or should be reduced the same mass loading of BOD from watershed by the construction of wastewater treatment plant.

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Spatial Variation of the Polar Front in relation to the Tsushima Warm Current in the East Sea (동해에서 쓰시마난류의 변동과 관련한 극전선의 공간적 변화)

  • 이충일;조규대;최용규
    • Journal of Environmental Science International
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    • v.12 no.9
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    • pp.943-948
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    • 2003
  • Variation of the polar front in the East Sea is studied using temperature and dissolved oxygen data obtained from Japan Meteorological Agency from 1972 to 1999. Variation of the polar front in the East Sea has a close relation to the variation of the Tsushima Warm Current (TWC). When the TWC spreads widely in the East Sea, polar front moves northward. The spatial variation of the polar front is greater in the southwestern area of the East Sea and the northern area of Tsugaru Strait where the variation of the TWC's distribution area is greater than those in others of the East Sea. Hence, in the southeastern area of the East Sea, that is, between near Noto peninsula and Tsugaru Strait, the spatial variation of the polar front is not so wide as in the southwestern area because the flow of TWC is stable.

Fabrication of Nano-sized Titanate Powders by an Ethylene Glycol Solution Route

  • Lee, S.J.;Lee, M.J.;Yoon, Y.S.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.440-441
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    • 2006
  • Several titanate powders ($Al_2TiO_5,\;SrTiO_3$, etc.) were synthesized by an ethylene glycol solution route. Titanium isopropoxide and nitrate salts were dissolved in stoichiometric proportions in liquid-type ethylene glycol without any precipitation. The parent precursor sols were dried to porous gels, and then the gels were calcined and crystallized. All synthesized titanate powders had stable crystallization behavior at low temperature and high specific surface area after a simple ball-milling process. A three-component PZT $(Pb(Zr_{0.52}{\cdot}Ti_{0.48})O_3)$ powder was also synthesized successfully by the ethylene glycol method. In this study, the characteristics of the multi-component titanate powders by the ethylene glycol method are examined.

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The Characterization of Floc Formation Under Various Pre-coagulation Conditions (응집-막분리 공정 적용시 전처리 응집조건에 따른 용존성 유기물 상(相)변화 특성)

  • Jung, Chul-Woo;Son, Hee-Jong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1139-1145
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    • 2008
  • The objectives of this research are to investigate the mechanism of coagulation affecting UF and find out the optimum conditions of the combined of coagulation with UF membrane filtration for NOM removal. During the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation (both rapid mixing and slow mixing) improved dissolved removal efficiency. Also, for combined coagulation to membrane process, flux reduction rate showed lower than only UF process. The rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane.

The Removal of Algae by Pre-oxidation (전산화 공정을 이용한 조류제거)

  • Son, Hee-Jong;Jung, Chul-Woo;Bae, Sang-Dae;Choi, Young-Ik;Kang, Lim-Seok
    • Journal of Environmental Science International
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    • v.18 no.3
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    • pp.289-298
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    • 2009
  • The blue-green algae which caused odor problem in the tap water are difficult to precipitate in sedimentation basin and clogged the filter void rapidly. The studies of this paper were not only oxidation, coagulation and sedimentation processes for effectively removing blue-green algae but yellow clay and polyamine for verification as coagulants aids. The results of this research are summarized as follows: Higher ozone dose(C) and longer contact time(T) were needed for a high degree of removing blue-green algae efficiency. the removal rate of blue-green algae was proportional to the $C\times T$ value. The removal percent of chlorophyll-a by sedimentation and filter without pre-ozonation was about 75% but 1 mg/L pre-ozonation could increase the removal percent of chlorophyll-a to 99% and more pre-ozonation could remove completely. Though the removal efficiency of turbidity could increased by high dose of chlorination, the dissolved organic carbon was increased. More chlorine dose from 4 to 10 mg/L dissolved organic carbon was decreased. Using yellow clay as coagulant aids increased density of floc so the settling velocity of floc become rising but polyamine could not increase settling velocity of floc though it could formated large floc.

The Evaluation of Fouling Mechanism on Cross Flow Precoagulation-UF Process (십자형 응집-UF 막분리 공정 적용시 전처리 응집조건에 따른 막오염 메카니즘 규명)

  • Jung, Chul-Woo;Son, Hee-Jong
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.639-645
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    • 2008
  • The objectives of this research are to (1) observe changes in particle size distribution due to formation of microflocs during coagulation process (2) identify the membrane fouling potential on cross flow system (3) investigate the mechanism of membrane fouling. The rate of flux decline for the hydrophobic membrane was significantly greater than for the hydrophilic membrane, regardless of pretreatment conditions. The pretreatment of the raw water significantly reduced the fouling of the UF membrane. Also, the rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane. That is, during the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation not only improved dissolved organics removal efficiency but also flux recovery efficiency.

SELF-PREPARATION OF BATHYTHERMOGRAPH SMOKED-GLASS SLIDE (Bathythermograph Smoked-glass slide의 간역제작법)

  • HUE Jong Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.1 no.2
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    • pp.135-137
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    • 1968
  • Bathythermograph (B. T) has been coumonly used to obtain a records of water temperature in the depth of 270m from the surface. We have, however, experienced some difficulties in obtaining smoked or coated glass which is used for the bathythermograph in this region, Therefore I introduce a easy method of preparing the smoked-glass slide. Preparing method is as follows. 1. Glass slides must be cleaned by dipping into the concentrated solution of sodium hydroxide ana hydrochloric acid then rinsing with hot water and polishing with a clean gauge. 2. The cleaned slide is immersed in the wax solution for coating, and dried on the filter paper. The Wax solution is prepared as follow : 1g of white wax is dissolved in 200CC of benzol or 1g of lard is dissolved in 300CC of gasoline. 3. A slide held in a fingertip is smoked on the flame of alcohol lamp, or Meter burner. When alcohol lamp is used the fuel alcohol must contain 1/5 of benzol, and when Meker burner is used, the air intake must be blocked up. The smoking on the glass slide should be light and uniform, after smoking the slide is cooled down. 4. The smoked glass slide is again dipped into the wax solution using a fingertip and the excessive wax solution on the slide is absorbed on the filter paper and drain off. 5. Thus prepared smoked slide can be used for B.T.

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