• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.100-101
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• 2004

Many researches in Korea have been performed to understand the pollution of stream waters by acid mine drainage. However, few studies have been conducted regarding the effect of particulate and colloidal fractions on the transport of trace metals. To estimate harmful effects of trace metals, it is important to evaluate the particulate and colloidal metals as well as dissolved metals, because particulate and colloidal fractions of trace metals play an important role in transport of trace metals and may adversely affect habitats and organisms in riverine system. Colloids are solids with effective diameters in size range from 0.001 $\mu$m to 1 $\mu$m. According to Jone et al. (1974), metals in surface water, like Al, Fe, and Mn, require filtration with pore-size membranes smaller than 0.45 $\mu$m to define dissolved concentrations. The main objective of this study is to understand the effects of particulate, colloidal, and truly dissolved fractions on the transport and fate of trace metals in acid mine drainage. This study was conducted for the Onjeong creek in the Uljin mine area. Sampling was carried out in 13 sites, spatially covering the area from mine dumps to the downstream Onjeong reservoir. To examine the metal partitioning between particulate, colloidal, and truly dissolved fraction, we used successive filtration techniques consisting of conventional method (using 0.45 $\mu$m membranes) and tangential-flow ultrafiltration (using 0.001 $\mu$mm membranes). Ultrafiltration may seperate much smaller particles from aqueous phase (Josephson, 1984; Hernandez and Stallard, 1988). The analysis of metals were performed by inductively coupled plasma - atomic emission spectrometer (ICP-AES: model Perkin Elmer OPTIMA3000XL). Anions such as SO$_4$, Cl and NO$_3$ were measured with ion chromatograph (IC: model Dionex 120). Sample analysis is still in progress. The preliminary data show that the studied creek is severely polluted by Al, Fe, Mn, Pb and Zn. Toward upstream sites with relatively lower pH, less than 50% of Al and Fe occur in the sorbed form on particles or colloids, whereas more than 80% of Al and Fe occur in the sorbed form in downstream sites or tributaries with relatively higher pH. Less than 30% of Zn is present in particle or colloidal forms in the whole range of creek. Truly dissolved fraction of trace metals is negatively correlated with pH. The Kd values for Al, Fe and Zn consistently increase with increasing pH and decrease with increasing particle concentration.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.2
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• pp.215-221
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• 2004

Effluent of wastewater treatment plant is to be disinfected to protect drinking water sources. DOF (Dissolved Ozone Flotation) was developed to meet this purpose. DOF was developed by combining DAF system with ozone. DAF system has good floating power with numerous microbubbles, and ozone has strong oxidation capability. And DOF system has good floating power and strong oxidation capability simultaneously. When DOF was applied to secondary wastewater effluent, color of 11CU in raw water which was secondary effluent was reduced to 1CU by the DOF system. Removal rate of other water quality parameters treated by DOF were also higher than that by DAF, which were proved the strength of oxidation capability of ozone. When ozone concentration of 3.3mg/l were applied in DOF system, general aerobic bacteria were reduced to 5CFU/ml from TNTC (Too many Numbers To Count). With the same ozone concentration, total coliform were not detected at all. These figures are under the numbers of drinking water regulation. These microbes were the target parameters of DOF. It was proved that DOF was very effective in disinfection of wastewater treatment plant effluent as well as in removal of color, turbidity, and T-P.

• KSBB Journal
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• v.24 no.2
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• pp.207-211
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• 2009

In this study, the sensing membranes for detection of pH and dissolved oxygen(DO) were prepared by immobilizing 6-aminofluorescein or ruthenium complex onto the sol-gel matrixes of GPTMS, MTMS, and TEOS and then recoated with the mixture of hydrophobic sol-gel and graphite for light insulation. The pH and DO sensing membranes recoated with the light insulation layer showed a higher sensitivity than those without light insulation layer. The sensing membranes were immobilized on the wells of 24-well microplate and used to monitor the fluorescence intensity for pH and DO in E.coli JM109 and P.pastoris X-33 fermentation processes. The change of the fluorescence intensity in the DO sensing membrane agreed with the growth patterns of microorganisms, that the membranes are valuable to monitor the DO in fermentation processes. In the case of pH monitoring, the fluorescence intensity has showed good correlation to the off-line pH data, that the pH membranes are valuable to monitor pH values in fermentations.

• Korean Journal of Veterinary Research
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• v.30 no.1
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• pp.41-49
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• 1990

These experiments were carried out to develop a novel, simple, and rapid method to determine urinary sulfonamides using fluorescamine by spectrofluorometry. To get optimal conditions for the sulfonamide-fluorescamine reaction, sulfonamides such as sulfamethazine, sulfamerazine, sulfadimethoxine and sulfamonomethoxine, dissolved in buffers with various pH ranges were reacted with various concentrations of fluorescamine. and then, the fluorescence intensity and stability of the fluorophore were measured. To eliminate the interfering substances in urine, the fluorophore in buffers and urine with a definite pH range was extracted with some organic solvents. After then the fluorescence intensity was measured in organic and aquous phases. The results obtained were summarized as follows: 1. The maximal fluorescence of sulfonamides was presented in acidic state, pH 4.5~5.0, at 30 minutes after reaction. 2. The optimal concentration ratio of sulfamethazine and ffuorescamine was more than 1 : 40 in mole. 3. In pH 4.0, the intensity was maximal but was time-dependent, whereas in pH 8.0, the intensity was time-independent. 4. Sulfamethazine-fluorescamine conjugate could be dissolved in some of organic solvents in acidic state such as chloroform, n-butanol, and ethylacetate. 5. Sulfamethazine-flnorescamine conjugate in swine urine coule be extracted with ethylacetate in acidic state, pH 4.0~5.0.

• Korean Journal of Agricultural and Forest Meteorology
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• v.1 no.2
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• pp.110-118
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• 1999

This experiment was conducted to characterize the vertical transport trend of dissolved elements through throughfall, stemflow, effluent from Ao layer, and leachate out of soil profile on Pinus koraiensis stand in Experimental Forest of Kyunghee University, located in Kwangju, Kyunggi province for 12 months from July, 1998 to Jun, 1999. In addition, we investigated the content of dissolved elements and the factors influencing the water chemistry concentrations separately collected from the field. Water movement in the process of throughfall and stemflow from precipitation, and rainfall leached from Ao layer into soil water was governed by concentration of through fall, precipitation, rainfall intensity, seasonal variation, and other factors. Also, smaller changes of pH in soil water than that of dissolved elements in soil water could contribute buffer capacity, as well as balancing the concentration between cations and anions.

• Journal of Korean Society of Water and Wastewater
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• v.13 no.3
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• pp.91-100
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• 1999

Treatment conditions of DAF(Dissolved Air Flotation) and removal rates of VOCs(Volatile Organic Compounds) in mixed water of H raw water and VOCs were investigated. The used VOCs were benzene, toluene, ethylbenzene, and xylene in aromatic compounds and iso propyl mereaptan, n-butyl mereaptan, dimethyl disulfide, and iso butyl mercaptan in odors. The related parameters include water type, treatment method, clay concentration, pH condition, flocculation time, flotation time, per-cent recycle, water temperature, pressure. The removal rates of VOCs were different on treatment process and water condition. Treatment time was longer, removal rates of VOCs was higher. Water temperature was more important than pressure in DAF parameters. Molecular weight was related with removal rate in several kinds of VOCs were decraesed by competition of each component in II raw water. When algac blooming D water was treated by DAF, TCOD(Total chemical Oxygen Demand) and chorophyll a was removed over 96%.

• Journal of Korean Society of Forest Science
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• v.89 no.3
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• pp.342-355
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• 2000

This study was carried out to reveal the influence of discharge change on matters and stream water quality between pH, EC and dissolved matters obtained by observation of long-term and short-term on stream water quality and separated runoff components from stream water by using HYCYMODEL. From January in 1998 to September in 1999, it was estimated by relationships of character of water quality and discharge for the experimental watershed in Mt. Palgong. The results were summarized as follows : 1. Annual average pH values of stream water in 1998 and in 1999 were 6.48(6.22~6.89) and 6.52(5.75~7.18), respectively. The observed annual average pH values were maintaining identical values in general, but pH values decreased continuously during the four months after thinning in the experimental watershed. So thinning is suspected of the major cause for the decrease. 2. Annual average EC values of stream water in 1998 and in 1999 were $26.69(17.95{\sim}33.5){\mu}S/cm$ and $25.19(17.5{\sim}33.8){\mu}S/cm$, respectively. The observed annual average EC values were maintaining identical values in general. 3. As a result of the comparison of average dissolved ions of rainfall and stream water, $Na^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, $NO_3{^-}$, and $SO_4{^{2-}}$ showed minus values between incomings and outgoings. $Na^+$ and $NO_3{^-}$ among the dissolved ions of stream water showed the highest concentration out of cations and anions respectively. 4. By the change of pH value in stream water due to rainfall events, pH value decreased with increasing runoff as pH value increased before and after peak flow. 5. By the change of EC value in stream water due to rainfall events, EC value decreased with increasing runoff of first rainfall as EC value changed with runoff before and after peak flow. 6. As the runoff increased, the concentration of $Na^+$, $Ca^{2+}$, $K^+$, total cation, $Cl^-$, and $SO_4{^{2-}}$ in stream water lowered. On the other hand, the runoff decreased, their concentration in stream water tended to get high. But in terms of $NO_3{^-}$ and total anion, they turned out vice versa. $Mg^{2+}$ produced no reaction. 7. The base flow among runoff components separated by using HYCYMODEL influenced greatly on pH, EC, concentration of cation and anion.

• Journal of The Korean Society of Agricultural Engineers
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• v.51 no.2
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• pp.51-57
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• 2009

The purpose of this study was to investigate characteristics of behavior of nutrients such as TN (Total nitrogen), TDN (Total dissolved nitrogen), TP (Total phosphorus) TDP (Total dissolved phosphorous) in runoff water from a nonpoint source dominated watershed ($6.67\;km^2$). Regular and intensive flow measurement and water sampling were taken during two years (February 2002 to January 2004) in the Ingyeong River, a tributary of the Han River. The mean concentrations of nutrients during rainy days were significantly (p < 0.05) higher than those during dry days. The mean TDN/TN ratio in rainy days (95%) is almost identical to that in dry days (96%), but mean TDP/TP ratio in rainy days (24%) significantly decreased compared with that in dry days (66%), suggesting that dominant form of TP is shifted from dissolved form to particulate form. Accordingly, the measures (.eg. filter strips, cover crops) to reduce soil erosion for fallow upland in the rainy season should be taken to control particulate phosphorous.

• Journal of Korean Society on Water Environment
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• v.35 no.2
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• pp.165-180
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• 2019

Water quality data of 81 lakes in Korea, 2013 ~ 2017 were analyzed. Most water quality parameters showed left-skewed distribution, while dissolved oxygen showed normal distribution. pH and dissolved oxygen showed a positive correlation with organic matter and nutrients, which appeared to be a nonsense correlation mediated by the algae. The ratio of $BOD_5$ and $COD_{Mn}$ to CBOD was 21 % and 52 % in the freshwater lakes, respectively. TOC concentration appeared to be underestimated by the UV digestion method, when salinity exceeds $700{\mu}S\;cm^{-1}$. In terms of nitrogen/phosphorus ratio, the limiting factor for algal growth seemed to be phosphorus in most of the lakes. Chlorophyll ${\alpha}$ increased acutely with decrease of N/P ratio. However, it seemed to be a nonsense correlation mediated by phosphorus concentration, since the N/P ratio depended on phosphorus. The N/P ratio of brackish lakes was lower than that of the freshwater, at the same concentration of phosphorus. It is worth examining denitrification that occurs, in bottom layer and sediment, during saline stratification. $Chl.{\alpha}$ concentration decreased in the form of a power function with increase of mean depth. The primary reason is that deep lakes are mainly at the less-disturbed upstream. However, it is necessary to investigate the effect of sediment, on water quality in shallow lakes. Light attenuation in the upper layer, was dominated by tripton (non-algal suspended solids) absorption/scattering (average relative contribution of 39 %), followed by CDOM (colored dissolved organic matter) (average 37 %) and $Chl.{\alpha}$ (average 21 %).

• Journal of Korean Society of Water and Wastewater
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• v.14 no.4
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• pp.343-349
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• 2000

Techniques such as dissolved air flotation and electroflotation, which utilize micro bubbles, are increasingly used for water and wastewater treatment. Most studies have concentrated on particle characteristics. Pretreatments that manipulate particle size and zeta potential were considered important. A recent study, which modeled the collision mechanism between micro bubbles and particles in dissolved air flotation, suggested bubble characteristics should also be important. Hydrogen micro bubbles were generated electrolytically and their zeta potentials measured under various conditions using a novel electrophoresis method. Effects of several parameters were investigated. Bubble zeta potentials were found to be pH dependent, and to have a negative value around neutral pH, becoming zero or positive at lower pH. The pH at zero zeta potential was 5.0 under study conditions. Using artificial solution and tap water, at fixed pH, bubble zeta potentials varied with solution composition. Zeta potentia]s of bubbles were affected by the types of cations and anions in solution but not by the voltage applied. These findings will help improve efficiencies of particle removal processes that utilize micro bubbles. As bubble zeta potential varies with solution composition, it needs to be measured for each composition to understand those effects, which increase removal efficiency.