• Title/Summary/Keyword: dispersion stability

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Motion of WC Grains in the Liquid Matrix during Liquid Phase Sintering of WC-Co Alloys (WC-Co계의 액상소결시 코발트 액상 내에서 WC 입자의 움직임)

  • 김소나
    • Journal of Powder Materials
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    • v.3 no.3
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    • pp.196-200
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    • 1996
  • The dispersion of WC grains Into the interior of an eutectic liquid has been studied by superimposing the eutectic WC-85wt.%Co liquid on the top surface of presintered WC-l0wt.%Co alloy compacts. The heavy WC grains diffused into the interior of liquid from the WC-l0wt.%Co compacts. According to increasing the treating temperatures and times, the dispersion distance from WC-l0wt.%Co substrates increased. The fine WC grains diffused into the liquid faster than the coarse WC grains. The high microstructural stability of WC-Co alloys having the heavier WC grains dispersed in a lighter Co-rich liquid was attributed to Brownian motion of WC grains in liquid. The motion of WC grains in the liquid appears to be same with the colloid(the disperse phase) in a dispersing medium. The dihedral angle of 0 degree of WC-Co at. toy seems one of key parameters, which enables the WC-Co alloys to have high structural stability without settling the WC grains during liquid phase sintering.

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Correlation Research of Dispersion Factors on the Silica Sol Prepared from Fumed Silica (흄드실리카로부터 제조된 실리카졸의 분산인자 상관성 연구)

  • Park, Min-Gyeong;Kim, Hun;Lim, Hyung Mi;Choi, Jinsub;Kim, Dae Sung
    • Korean Journal of Materials Research
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    • v.26 no.3
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    • pp.136-142
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    • 2016
  • To study the dispersion factors of silica sol prepared from fumed silica powder, we prepared silica sol under an aqueous system using a batch type bead mill. The dispersion properties of silica sol have a close relationship to dispersion factors such as pH, milling time and speed, the size and amount of zirconia beads, the solid content of fumed silica, and the shape and diameter of the milling impellers. Especially, the silica particles in silica sol were found to show dispersion stability on a pH value above 7, due to the electrostatic repulsion between the particles having a high zeta potential value. The shape and diameter of the impellers installed in the bead mill for the dispersion of fumed silica was very important in reducing the particle size of the aggregated silica. The median particle size ($D_{50}$) of silica sol obtained after milling was also optimized according to the variation of the size and amount of the zirconia beads that were used as the grinding medium, and according to the solid content of fumed silica. The dispersion properties of silica sol were investigated using zeta potential, turbiscan, particle size analyzer, and transmission electron microscopy.

The Stability of Aging and Synthetic Development of Paper Mending Tape for Conservation of Archive Document (종이 기록물 보수용 테이프 점착제 합성 및 열화 안전성 연구)

  • Shin, Joung-Soon;Lee, Kwi-Bok
    • Journal of the Korean Graphic Arts Communication Society
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    • v.30 no.1
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    • pp.35-45
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    • 2012
  • Polyacrylate dispersion(emulsion) as adhesive material was superior in quality such as preservation characteristics and reversibility. The tapes for repairing archival documents manufactured with four different types of formulation resulted in pH 7~8.8, soluble solid 50~52%, and viscosity 1,300~2,500 cps. Sample 4 of those was most excellent. Probably, sample 4 included inorganic materials such as MgO, silica gel, and zeolite. For selecting carrier of tape, tracing papers, were applied for manufacturing tapes and tested for adhesive strength and peel strength. Adhesive strength of tracing papers, was 3.1~3.8(N/10mm), 2.2~2.8(N/10mm), and 1.7-2.3(N/10mm), respectively. Peel strength was similar in all samples. To determine characteristic of conservation to the selected carriers, stability of deterioration was examined at conditions of $105^{\circ}C$ and $80^{\circ}C$ 65% for 7 days.

Effect of Storage Temperature on the Dispersion Stability of O/W Nano-emulsions (O/W 나노에멀젼 분산안정성에 미치는 보관온도의 영향)

  • Lee, Ye-Eun;Yoo, In-Sang
    • KSBB Journal
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    • v.29 no.5
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    • pp.385-391
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    • 2014
  • In this study, the emulsion dispersion stability of optimizing storage temperature was investigated. The system was based on oil/water (O/W) emulsions. In order to evaluate the stability, mean diameter of droplet was measured as a function of temperature with various mixed hydrophilic lipophilic balance (HLB). In addition, the correlations between phase inversion temperature (PIT) and the optimum storage temperature were probed. In this system, majority of the smallest droplet was shown at temperature of $20^{\circ}C$ below PIT. Whether the temperature was increased or decreased from the optimum, size of the droplet increased. According to the mixed HLB, the particle size and optimum storage temperature were also affected. As the concentrations of surfactant were increased, the size of particle decreased with lower optimum temperature for storage. If the surfactant (4 wt%) were mixed with HLB, the optimum storage temperature was $21^{\circ}C$ for maintaining the size of smallest droplet at 108.3 nm in diameter. At above optimum condition, increased size of particle was observed approximately 4 % increases from 108.2 nm to 112.3 nm after 600 hours. The size of particle in emulsion was maintained stably without any considerable effect of Ostwald ripening phenomena at the optimum storage temperature with low polydispersity index.

Preparation and Characterization of Stable Suspensions of Ni Nanoparticles (Ni 나노 분말을 이용한 안정한 현탁액 제조 및 특성)

  • Lee Eun-Hee;Lee Min-Ku;Rhee Chang-Kyu
    • Journal of Powder Materials
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    • v.13 no.2 s.55
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    • pp.138-143
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    • 2006
  • In this study, the effects of the dispersants, i.e., Hypermer KD-2 and poly(l-vinyl-2-pyrrolidone) (PVP), and their concentration on the dispersion stability of Ni nanoparticles ($10nm{\sim}40nm$) in ethanol were investigated by using a visual inspection, a transmission profile (Turbiscan), and a zeta potential measurement. The transmission profiles measured by Turbiscan showed that the particle size increased over the entire height of the sample for suspensions with both the dispersants without showing any particle coalescence and sedimentation. The visual inspection also confirmed that the Ni suspensions with Hypermer KD-2 and PVP were very stable for more than a year. The zeta potential values varied from positive to negative with increasing the dispersant's concentration. The dispersion stability of the suspensions was not affected by both the dispersant's concentration and the zeta potential values. The observed suspension stability of Ni nanoparticles was attributed to the steric effect for the Hypermer KD-2 and to the bridging effect for the PVP.

Effects of Erythrosine on the Cholesterol Oxidative Stability in an Aqueous Model System (수용성 모형계에서 콜레스테롤의 산화 안정성에 대한 Erythrosine의 영향)

  • Chung, Man-Gon;Kim, Jong-Seung;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.28 no.1
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    • pp.197-202
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    • 1996
  • The effects of erythrosine on the oxidative stability of cholesterol in an aqueous model system were studied by depleted headspace oxygen and cholesterol oxidation products (COP). As the oncentration of erythrosine was increased, headspace oxygen depletion, 7-COP and total COP increased during storage at $25^{\circ}C$ for 50 hours under the fluorescent light. As the intensity of fluorescent light was increased, amounts of headspace oxygen depleted and COP formed in an aqueous cholesterol dispersion containing erythrosine also increased. Addition of ${\alpha}-,\;{\delta}-$, mixed-tocopherol and ${\beta}-carotene$ resulted in the enhanced oxidative stability of an aqueous cholesterol dispersion containing erythrosine during the fluorescent light storage.

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