• Bulletin of the Korean Chemical Society
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• v.22 no.8
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• pp.842-846
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• 2001

Solvolyses of N-methyl-N-phenylcarbamoyl chlorides in aqueous binary mixtures of acetone, ethanol, methanol and in water, D2O, and 50% D2O-CH3OD are investigated at 25.0 $^{\circ}C.$ The Grunwald-Winstein plots of first-ord er rate constants for N-methyl-N-phenylcarbamoyl chlorides with YCl (based on 2-adamantyl chloride) show a dispersion phenomenon. The ring parameter (I) has been shown to give considerable improvement when it is added as an hI term to the original Grunwald-Winstein and extended Grunwald-Winstein correlations for the solvolyses of N-methyl-N-phenylcarbamoyl chlorides. This study has shown that the magnitude of l, m and h values associated with a change of solvent composition is able to predict the dissociative SN2 transition state. The kinetic solvent isotope effects determined in deuterated water are consistent with the proposed mechanism of the general base catalyzed and/or a dissociative SN2 mechanism channel for N-methyl-N-phenylcarbamoyl chlorides solvolyses.

• Steel and Composite Structures
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• v.32 no.2
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• pp.213-223
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• 2019

For the first time, longitudinal and transverse wave propagation of triclinic nanobeam is investigated via a size-dependent shear deformation theory including stretching effect. Furthermore, the influence of initial stress is studied. To consider the size-dependent effects, the nonlocal strain gradient theory is used in which two small scale parameters predict the behavior of wave propagation more accurately. The Hamiltonian principle is adopted to obtain the governing equations of wave motion, then an analytic technique is applied to solve the problem. It is demonstrated that the wave characteristics of the nanobeam rely on the wave number, nonlocal parameter, strain gradient parameter, initial stress, and elastic foundation. From this paper, it is concluded that the results of wave dispersion in isotropic and anisotropic nanobeams are almost the same in the presented case study. So, in this case, triclinic nanobeam can be approximated with isotropic model.

• Steel and Composite Structures
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• v.31 no.6
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• pp.641-653
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• 2019

In this paper, wave propagation is studied and analyzed in double-layered nanotubes systems via the nonlocal strain gradient theory. To the author's knowledge, the present paper is the first to investigate the wave propagation characteristics of double-layered porous nanotubes systems. It is generally considered that the material properties of nanotubes are related to the porosity and hygro-thermal effects. The governing equations of the double-layered nanotubes systems are derived by using the Hamilton principle. The dispersion relations and displacement fields of wave propagation in the double nanotubes systems which experience three different types of motion are obtained and discussed. The results show that the phase velocities of the double nanotubes systems depend on porosity, humidity change, temperature change, material composition, non-local parameter, strain gradient parameter, interlayer spring, and wave number.

• Structural Engineering and Mechanics
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• v.85 no.4
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• pp.501-510
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• 2023

Horizontally polarized shear waves (SH) have numerous applications in various scientific, engineering, and medical fields. The study deals with an investigation of SH-waves in a thin microstructural plate. The plate has been mathematically modelled by employing size dependent consistent couple stress theory, which involves a length parameter, known as characteristic length. Characteristic length is assumed to be of the order of internal microstructures of the material. Dispersion relations have been calculated for the propagation of SH-waves using different set of boundary conditions. Group velocity of the SH-waves has been calculated by using an analytical approach. The mathematical results obtained in the problem are discussed in detail and the impacts of characteristic length parameter and thickness of plate are presented on phase velocity of SH-waves through graphical illustrations.

• Geophysics and Geophysical Exploration
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• v.2 no.4
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• pp.202-208
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• 1999

We introduce a new acoustic parameter for the classification of seafloor sediments from chirp sonar acoustic profiling data. The acoustic parameter is defined as a derivative of the unwrapped phase of the Fourier transform of acoustic profiling data. Consequently, it represents the characteristics of attenuation by dissipative dispersion in sediments. And we estimated acoustic properties by geoacoustic modeling using Chirp data obtained from the different sedimentary facies. Our classification results, when compared with the results of analysis of sampled sediments, show that the acoustic parameter discriminates sedimentary facies and bottom hardness. Thus the method in this paper is expected to be an effective means of geoacoustic modeling of the seafloor.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.585-591
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• 2000

The wavelet transform is the most recent technique for processing signals with time-varying spectra. In this paper, the wavelet transform is utilized to improved the assessment and multi-resolution analysis of acoustic emission signals generating in partial discharge. This paper especially deals with the assessment of process statistical parameter using the features extracted from the wavelet coefficients of measured acoustic emission signals in case of applied voltage 20[kv]. Since the parameter assessment using all wavelet coefficients will often turn out leads to inefficient or inaccurate results, we selected that level-3 stage of multi decomposition in discrete wavelet transform. We applied FIR(Finite Impulse Response)digital filter algorithm in discrete to suppression for random noise. The white noise be included high frequency component denoised as decomposition of discrete wavelet transform level-3. We make use of the feature extraction parameter namely, maximum value of acoustic emission signal, average value, dispersion, skewness, kurtosis, etc. The effectiveness of this new method has been verified on ability a diagnosis transformer go through feature extraction in stage of acting(the early period, the last period) .

• Earthquakes and Structures
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• v.16 no.5
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• pp.563-573
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• 2019

When generating spectrum-compatible artificial ground motion in engineering practices, the effect of the variation in fitting parameters on the distribution of the peak ground displacement (PGD) has not yet drawn enough attention. In this study, a method for simulating ground motion matching for multiple targets is developed. In this method, a frequency-dependent amplitude envelope function with statistical parameters is introduced to simulate the nonstationarity of the frequency in earthquake ground motion. Then, several groups of time-history acceleration with different temporal and spectral nonstationarities were generated to analyze the effect of nonstationary parameter variations on the distribution of PGD. The following conclusions are drawn from the results: (1) In the simulation of spectrum-compatible artificial ground motion, if the acceleration time-history is generated with random initial phases, the corresponding PGD distribution is quite discrete and an uncertain number of PGD values lower than the limit value are observed. Nevertheless, the mean values of PGD always meet the requirement in every group. (2) If the nonstationary frequencies of the ground motion are taken into account when fitting the target spectrum, the corresponding PGD values will increase. A correlation analysis shows that the change in the mean and the dispersion values, from before the frequencies are controlled to after, correlates with the modal parameters of the predominant frequencies. (3) Extending the maximum period of the target spectrum will increase the corresponding PGD value and, simultaneously, decrease the PGD dispersion. Finally, in order to control the PGD effectively, the ground motion simulation method suggested in this study was revised to target a specified PGD. This novel method can generate ground motion that satisfies not only the required precision of the target spectrum, peak ground acceleration (PGA), and nonstationarity characteristics of the ground motion but also meets the required limit of the PGD, improving engineering practices.

• Journal of Environmental Science International
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• v.3 no.3
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• pp.241-252
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• 1994

Meteorological parameters In the atmospheric boundary layer and the vertical and horizontal dispersion parameters were determined by analyzing the data obtained by the special upper-air observations of one clear day for each season from October 1991 to August 1992. The concentration of the aklospheric pollutants over Taegu was analyzed by using the application of the Gaussian diffusion model. In the diurnal variation of diffusion of atmospheric pollutants, vertical diffusion due to turbulence is active in daytime while horizontal diffusion due to wind is active in nighttime. The mean concentration of pollutants in the side of downwind is higher during the daytime than the nighttime. Thus, the height of the mixed-layer at the nighttime considered as the most important parameter of the mean concentration of pollutants. In the seasonal variation of diffusion of atmospheric pollutants, vertical diffusion due to strong solar radiation is active in summer case day, and horizontal diffusion due to strong wind is active in winter case day. In winter case day, the mean concentration of pollutants in the side of downwind is maximum in the daytime. However, in summer case day, that is maximum in the nighttime.

• Journal of Korea Water Resources Association
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• v.37 no.4
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• pp.257-271
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• 2004

To evaluate behavior in representing solute transport in natural streams, the storage zone model of the axially periodic transient storage zones is developed. The periodic transient storage zone model and continuous storage zone model are verified using the parameters and the tracer concentration vs. time curves observed in laboratory channels. The periodic storage zone model best fit the measured concentration vs. time curves, while the continuous storage model fails to describe some fluctuations and the plateau region of the tail occurring in a discontinuous transient storage system. Dispersion data from Shingobee River, Minnesota, U. S. A. show that the concentration curves simulated by the proposed model fit the observed concentration curves well.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.2
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• pp.30.3-31
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• 2015

We present a kinematic analysis of 172 likely member galaxies of the Ursa Major Cluster. In order to understand the dynamical state of the cluster, we investigate the correlation of the cluster morphology with rotation, the velocity dispersion profile, and the rotation amplitude parallel to the global rotation direction. Both the minor axis and the rotation are very well-aligned with the global rotation axis in the outer region at half radius (> 0.5 $R_{max}$), but not in the inner region. The cluster exhibits low velocity dispersion and rotation amplitude profiles in the inner region, but higher in the outer. Both profiles exhibit outwardly increasing trends, suggesting an inside-out transfer of angular momentum of dark matter via violent relaxation, as revealed by a recent off-axis major-merging simulation. From Dressler-Schectman plots in the plane of galactic positions, and velocity versus position angle of galaxy, we are able to divide the Ursa Major Cluster into two substructures: Ursa Major South (UMS) and Ursa Major North (UMN). We derive a mass of $3.2{\times}10^{14}M_{\odot}$ for the cluster through the two-body analysis by the timing argument with the distance information (37 for UMN and 36 for UMS) and the spin parameter of ${\lambda}=0.049$. The two substructures appear to have passed each other 4.4 Gyr ago and are moving away to the maximum separation.