• Earthquakes and Structures
• /
• 제15권4호
• /
• pp.369-382
• /
• 2018

A free vibration analysis and wave propagation of functionally graded porous beams has been presented in this work using a high order hyperbolic shear deformation theory. Unlike other conventional shear deformation theories, a new displacement field that introduces indeterminate integral variables has been used to minimize the number of unknowns. The constituent materials of the beam are assumed gradually variable along the direction of height according to a simple power law distribution in terms of the volume fractions of the constituents. The variation of the pores in the direction of the thickness influences the mechanical properties. It is therefore necessary to predict the effect of porosity on vibratory behavior and wave velocity of FG beams in this study. A new function of the porosity factor has been developed. Hamilton's principle is used for the development of wave propagation equations in the functionally graded beam. The analytical dispersion relationship of the FG beam is obtained by solving an eigenvalue problem. Illustrative numerical examples are given to show the effects of volume fraction distributions, beam height, wave number, and porosity on free vibration and wave propagation in a functionally graded beam.

• 한국전자거래학회지
• /
• 제16권2호
• /
• pp.19-37
• /
• 2011

인터넷의 발달과 함께 온라인을 통한 상거래 활동은 급증해 왔다. 전자상거래 초기에 기존의 오프라인 업체들과 온라인 업체들 간의 가격수준 및 편차에 대한 연구들이 많이 이루어졌으나, 전자상거래가 활성화되고 성숙된 지금은 이러한 채널 유형별 비교보다는 전자상거래 업체들의 가격변화 행태에 대한 연구가 필요하다. 이에 따라 본 연구에서는 전자상거래 상에서 제품이 판매되기 시작한 시점부터 시간이 흐름에 따라 가격이 어떻게 변화하는지를 분석하였다. 가격비교 사이트로부터 가격자료를 수집하여 분석에 활용하였다. 이를 통해 시간이 흐를수록 최저가와 평균가격이 하락하는 것을 보였으며, 최고가는 시간이 흐를수록 오히려 상승하는 패턴을 보였다. 최고가의 상승에는 판매업체 수 증가가 양의 영향을, 출시 이후 기간이 음의 영향을 미치는 것을 보였으며 이 두 가지의 영향력에 따라 제품군별로 상이한 상승 패턴을 보였다. 또한, 제품군의 유형별로도 판매업체 수에 따라 상이한 가격변화 패턴을 보였다.

• Korean Membrane Journal
• /
• 제7권1호
• /
• pp.1-18
• /
• 2005

The permeate flux decline due to membrane fouling can be addressed using a variety of theoretical stand-points. Judicious selection of an appropriate theory is a key toward successful prediction of the permeate flux. The essential criterion f3r such a decision appears to be a detailed characterization of the feed solution and membrane properties. Modem theories are capable of accurately predicting several properties of colloidal systems that are important in membrane separation processes from fundamental information pertaining to the particle size, charge, and solution ionic strength. Based on such information, it is relatively straight-forward to determine the properties of the concentrated colloidal dispersion in a polarized layer or the cake layer properties. Incorporation of such information in the framework of the standard theories of membrane filtration, namely, the convective diffusion equation coupled with an appropriate permeate transport model, can lead to reasonably accurate prediction of the permeate flux due to colloidal fouling. The schematic of the essential approach has been delineated in Figure 5. The modern approaches based on appropriate cell models appear to predict the permeate flux behavior in crossflow membrane filtration processes quite accurately without invoking novel theoretical descriptions of particle back transport mechanisms or depending on adjust-able parameters. Such agreements have been observed for a wide range of particle size ranging from small proteins like BSA (diameter ${\~}$6 nm) to latex suspensions (diameter ${\~}1\;{\mu}m$). There we, however, several areas that need further exploration. Some of these include: 1) A clear mechanistic description of the cake formation mechanisms that clearly identifies the disorder to order transition point in different colloidal systems. 2) Determining the structure of a cake layer based on the interparticle and hydrodynamic interactions instead of assuming a fixed geometrical structure on the basis of cell models. 3) Performing well controlled experiments where the cake deposition mechanism can be observed for small colloidal particles (< $1\;{\mu}m$). 4) A clear mechanistic description of the critical operating conditions (for instance, critical pressure) which can minimize the propensity of colloidal membrane fluting. 5) Developing theoretical approaches to account for polydisperse systems that can render the models capable of handing realistic feed solutions typically encountered in diverse applications of membrane filtration.

• 열처리공학회지
• /
• 제22권3호
• /
• pp.155-161
• /
• 2009

An investigation of the deformation behavior of ${\gamma}'-Ni_3Al$ single crystals containing fine dispersion of disordered ${\gamma}$ particles was performed for several different crystal orientations. Deformation structures were observed by the weak-beam method of transmission electron microscopy (TEM). The critical resolved shear stress (CRSS) for (111) [$\bar{1}$01] slie. increases with increasing temperature in the temperature range where (111) slip operates. The CRSS for (111) [$\bar{1}$01] slip is dependent on crystal orientation in the corresponding temperature range. The temperature where the strenjlth reaches a maximum is dependent on crystal orientation; the higher the ratio of the Schmid factors of (010) [$\bar{1}$01] to that of (111) [$\bar{1}$01], the higher the peak temperature. The peak temperatures were increased by the precipitation of y particles for the samples of all orientations. Electron microscopy of deformation induced dislocation arrangements under peak temperature has revealed that most of dislocations are straight screw dislocations. The mobility of screw dislocations decreases with increasing temperature. Above the peak temperature, dislocations begin to cross slip from the (111) [$\bar{1}$01] slip system to the (010) [$\bar{1}$01] slip system, thus decreasing the strength.

• 한국재료학회지
• /
• 제23권5호
• /
• pp.281-285
• /
• 2013

In the present work, ZnO nanofibers were applied to electrode materials for the detection of cholesterol. ZnO nanofibers were synthesized using the electrospinning technique with zinc acetate as a precursor. Electrospinning-synthesized ZnO nanofibers were uniformly distributed by properly controlling the electrospinning parameters. After the calcination treatment, nanofibers of pure ZnO phase were synthesized. Then, these fibers were successfully placed on Au-coated glass substrates by dispersion of ZnO nanofibers in ethanol, dropping, and drying, in sequence. Cholesterol oxidase was then immobilized onto the surface of the ZnO nanofibers. To enhance the immobilization, Nafion was additionally applied. The sensing performances of the fabricated ZnO nanofibers-based sensors were analyzed by cyclic voltammetry in terms of cholesterol concentration ranging from 100 to 400 mg/dl. In the I-V curves, measured by cyclic voltammetry, the ZnO nanofiber-based sensor showed a proportional current behavior with cholesterol concentrations in phosphate buffered saline solution. The sensitivity was measured and found to be $30.7nA/mM{\cdot}cm^2$, which is comparable to the values reported in the literature. After not only optimizing the shape of the ZnO nanofibers but also improving the adhesion nature between the ZnO nanofibers and the Au conducting layer, these fibers can be a good candidate for electrode materials in devices used to detect low concentrations of cholesterol in blood.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
• /
• pp.217-217
• /
• 2011

Recently, demand for thermally stable metal nanoparticles suitable for chemical reactions at high temperatures has increased to the point to require a solution to nanoparticle coalescence. Thermal stability of metal nanoparticles can be achieved by adopting core-shell models and encapsulating supported metal nanoparticles with mesoporous oxides [1,2]. However, to understand the role of metal-support interactions on catalytic activity and for surface analysis of complex structures, we developed a novel catalyst design by coating an ultra-thin layer of titania on Pt supported silica ($SiO_2/Pt@TiO_2$). This structure provides higher metal dispersion (~52% Pt/silica), high thermal stability (~600$^{\circ}C$) and maximization of the interaction between Pt and titania. The high thermal stability of $SiO_2/Pt@TiO_2$ enabled the investigation of CO oxidation studies at high temperatures, including ignition behavior, which is otherwise not possible on bare Pt nanoparticles due to sintering [3]. It was found that this hybrid catalyst exhibited a lower activation energy for CO oxidation because of the metal-support interaction. The concept of an ultra-thin active metal oxide coating on supported nanoparticles opens-up new avenues for synthesis of various hybrid nanocatalysts with combinations of different metals and oxides to investigate important model reactions at high-temperatures and in industrial reactions.

• 한국분말재료학회지
• /
• 제8권3호
• /
• pp.151-156
• /
• 2001

MgO based nanocomposite powder including ferromagnetic iron particle dispersions, which can be available for the magnetic and catalytic applications, was fabricated by the spray pyrolysis process using ultra-sonic atomizer and reduction processes. Liquid source was prepared from iron (Fe)-nitrate, as a source of Fe nano-dispersion, and magnesium (Mg)-nitrate, as a source of MgO materials, with pure water solvent. After the chamber were heated to given temperatures (500~$^800{\circ}C$), the mist of liquid droplets generated by ultrasonic atomizer carried into the chamber by a carrier gas of air, and the ist was decomposed into Fe-oxide and MgO nano-powder. The obtained powders were reduced by hydrogen atmosphere at 600~$^800{\circ}C$. The reduction behavior was investigated by thermal gravity and hygrometry. After reduction, the aggregated sub-micron Fe/MgO powders were obtained, and each aggregated powder composed of nano-sized Fe/MgO materials. By the difference of the chamber temperature, the particle size of Fe and MgO was changed in a few 10 nm levels. Also, the nano-porous Fe-MgO sub-micron powders were obtained. Through this preparation process and the evaluation of phase and microstructure, it was concluded that the Fe/MgO nanocomposite powders with high surface area and the higher coercive force were successfully fabricated.

• 수산해양기술연구
• /
• 제37권4호
• /
• pp.296-301
• /
• 2001

기존의 솔레노이드 밸브는 전자부품에 기계적 운동요소를 포함하여 비선형성을 내포하고 있으나, MC 성분의 ER유체를 이용하면, 유동체의 통과부분을 전기장 제어를 통하여 솔레노이드 밸브 기능을 대신할 수 있는 메카니즘을 구현할 수 있을 것으로 사료된다. 유기성인 MC성분 ER유체를 유압시스템에 솔레노이드 밸브 역할에 적용하기 위해, 부과하는 직류 전기장의 사이클 수에 따른 기계적특성에 대한 평가는 다음과 같다. MC성분 ER유체의 전단속도비에 대한 전단응력 분포변화는 2.0kV/mm까지 전기장을 인가했을 경우, 횡축의 전단속도가 증가하여도 종축의 전단응력은 거의 변하지 않았다. 60만 사이클을 반복한 후 ITMC25의 전단응력 실험결과, 2.0kV/mm 이상 전기량을 인가하면 2차원적인 곡선의 형태를 형성하지만 표준편차의 평가치가 오차한계 이내이므로 직선으로 판단하여도 무리가 없을 것으로 사료되었다. 구리 전극으로 전기장을 부과한 경우 MC 성분의 ER유체는 0.1~$0.3{\mu}m$까지의 표면거칠기를 나타냈고, 알루미늄 전극을 사용한 경우는 전기장 부과 초기에 $0.3{\mu}m$의 표면거칠기가 $0.2{\mu}m$로 감소하였으나 40만 사이클의 전기장 부과 이후는 약간의 요철변화가 있었다.(이 논문의 결론 부분임)

• 공업화학
• /
• 제23권1호
• /
• pp.65-70
• /
• 2012

소재의 물리적 변형을 야기할 수 있는 구조 변화 분자에 관한 연구는 잠재적인 응용 분야가 다양하며 매우 흥미로운 분야이다. 특히, 광응답성 물질은 비접촉식 에너지 전달이 가능하여 비파괴, 국소 조사, 원격 제어가 가능하다. 본 논문에서는 광응답성 물질인 아조 발색단의 고분자 내 위치에 따른 물리적, 광학적 성질을 조사하고, 이를 수용성 젤인 폴리비닐알코올에 분산시켜 자외선-가시광선 조사에 따른 이중 안정성 거동을 조사하였다. 신축 배향된 아조벤젠 고분자에 비편광 자외선을 상온에서 조사하여 비등방성 광변형을 시연한 결과, 아조벤젠 고분자 블렌드의 물리적 변형 성능은, 이제까지 보고되었던 많은 아조벤젠 가교 액정 탄성체의 광변형 성능보다 우수한 것으로서, 곁가지 아조벤젠 고분자 필름의 $15^{\circ}$ 구부러짐 변형이 상온에서도 관찰될 정도로 매우 뛰어나며 그 변형이 가역적이었다. 이와 같이, 화학적 접근 방식보다 쉽게 얻을 수 있는 아조벤젠/고분자 블렌드 필름의 성능이 매우 우수하여, 치수 변형이 필요한 다양한 시스템에 응용할 수 있다.

• 한국통신학회논문지
• /
• 제29권6B호
• /
• pp.575-583
• /
• 2004

본 논문에서는 MTS 정체 프레임워크를 윈도우 기반 정체 제어, 특히 TCP로 확장하고 TCP의 대역폭 소비 반응의 적극성을 LTS 자기유사성 네트워크 상태의 함수 형태에서 연구한다. RTT가 결정한 피드백 루프의 시간 한계를 초과하는 정보의 형태로 조정하는 LTS 제어모듈과 TCP를 연계시키는 방법으로 연구하며, 또 정보는 개연적인 특성을 갖고 여러 시간대에 걸쳐 분산되는 기존 윈도우를 기반으로 실현되기 때문에, 이를 효과적으로 활용할 수 있는 방법으로 개선하고, MTS TCP의 성능을 자기 유사성 트래픽의 물리적 모델링에 기반 한 시뮬레이션을 벤치마크 환경을 통해 수행된다. 본 논문은 자기유사성 트래픽 조건에서 프로토콜 스택의 전송 프로토콜 변화의 영향을 파악 및 평가하는 방법론을 활용하고, 과중한 워크로드 조건에서 시뮬레이션을 통해 성능 개선을 평가 비교한다.