• Title/Summary/Keyword: dispersion ability

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Impact of fine fillers on flowability, fiber dispersion, strength, and tensile strain hardening of UHPC

  • Chung-Chan Hung;Kuo-Wei Wen;Yueh-Ting Chen
    • Advances in concrete construction
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    • v.15 no.6
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    • pp.405-417
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    • 2023
  • While ultra-high performance concrete (UHPC) is commonly reinforced with micro straight steel fibers in existing applications, studies have indicated that the use of deformed steel macro-fibers leads to enhanced ductility and post-peak responses for UHPC structural elements, which is of particular importance for earthquake-resistant structures. However, there are potential concerns regarding the use of UHPC reinforced with macro-fibers due to the issues of workability and fiber distribution. The objective of this study was to address these issues by extensively investigating the restricted and non-restricted deformability, filling ability, horizontal and vertical velocities, and passing ability of UHPC containing macro hooked-end steel fibers. A new approach is suggested to examine the homogeneity of fiber distribution in UHPC. The influences of ultra-fine fillers and steel macro-fibers on the workability of fresh UHPC and the mechanics of hardened UHPC were examined. It was found that although increasing the ratio of quartz powder to cement led to an improvement in the workability and tensile strain hardening behavior of UHPC, it reduced the fiber distribution homogeneity. The addition of 1% volume fraction of macro-fibers in UHPC improved workability, but reduced its compressive strength, which is contrary to the effect of micro-fiber inclusion in UHPC.

Simulation of the Dispersion of Air Pollutants in the Shihwa Area (시화지구의 대기오염물질 확산에 관한 전산모사)

  • Song, Eun-Seok;Yoo, Jin-Bog;Kim, Byoung-Su;Yi, Sung-Chul;Hong, Min-Sun;Jang, Young-Kee
    • Journal of Environmental Impact Assessment
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    • v.7 no.1
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    • pp.35-48
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    • 1998
  • Gaussian type models have limitations on predicting a detailed description of the near flow and pollution leads over complex terrains under neutral atmospheric conditions. Also, most models used recently have lack of ability to include atmospheric reactions. The model based on the numerical solution of the time-averaged Navier-Stokes equations and conservation equations needs to be developed to improve the limitations mentioned above. When the model was applied to the Shihwa area where the tracer experiment had been carried out, the simulation results have a great difference from the experimental results. There are two reasons that make the difference between the results by the model and the experiment. First, the Shihwa area is not a complex terrain. Second, meteorological data is insufficient. Therefore, the model should be applied to predict the dispersion of air pollutants over complex terrain rather than flat terrain in order that the model could be verified because the model was developed for the prediction of the dispersion over a complex terrain.

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Change in Spatial Dispersion of Daphnia magna(Cladocera: Daphniidae) Populations Exposed to Organophosphorus Insecticide, Diazinon (유기인계 살충제 (다이아지논)에 대한 물벼룩, Daphnia magna (Cladocera: Daphniidae) 개체군의 공간분산 변이)

  • Lee, Sang-Hee;Ji, Chang-Woo;Chon, Tae-Soo
    • Environmental Analysis Health and Toxicology
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    • v.24 no.3
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    • pp.231-240
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    • 2009
  • We explored collective behaviors of indicator species to elucidate the effect of the chemical stress. After the treatments of an insecticide, diazinon, at low concentrations (1.0 and 10.0 ${\mu}g/L$), spatial dispersion patterns of Daphnia magna were checked in a test chamber. The I-index was used to characterize the movement data before (0~1 h) and after (1~2 h) the treatments in laboratory conditions. The slopes of the frequency distribution of I-index in semi-log scale decreased significantly, and the test populations appeared to be more dispersed with a lower degree of aggregation after the treatments. The index was feasible in indicating decrease in the ability of the specimens to keep desirable distances with neighbor individuals under chemical stress and showed a possibility of monitoring presence of toxic chemicals in environment through group behavior measurement.

A Study on tole Improvement of the Slurry Dispersibility in CMP (CMP 슬러리의 분산성 향상에 관한 연구)

  • Cho, Sung-Hwan;Kim, Hyoung-Jae;Kim, Ho-Youn;Kim, Heon-Deok;Seo, Kyoung-Jun;Jeong, Hae-Do
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.10
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    • pp.1535-1540
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    • 2001
  • This study presents the possibility of scratch reduction on wafer in CMP by applying the ultrasonic and megasonic energy into the slurry which might contain large abrasive particles. Experiments were conducted to verify the dispersion ability of agglomerated particles by applying ultrasonic, megasonic waves and analyze the particle distribution of used slurry in case, of sonic energy assisted or none. And the dispersion stability of megasonic waves was investigated through the experiment of stability of the dispersed slurry, Finally, to confirm that the distribution of particles in slurry by ultrasonic waves was actually related to scratches on wafer when CMP was done, tungsten blanket wafer was processed, by CMP to compare and investigate scratches on wafer.

Preparation of gold nanoparticle/single-walled carbon nanotube nanohybrids using biologically programmed peptide for application of flexible transparent conducting films

  • Yang, MinHo;Choi, Bong Gill
    • Carbon letters
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    • v.20
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    • pp.26-31
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    • 2016
  • In this study, we report a general method for preparation of a one-dimensional (1D) arrangement of Au nanoparticles on single-walled carbon nanotubes (SWNTs) using biologically programmed peptides as structure-guiding 1D templates. The peptides were designed by the combination of glutamic acid (E), glycine (G), and phenylalanine (F) amino acids; peptides efficiently debundled and exfoliated the SWNTs for stability of the dispersion and guided the growth of the array of Au nanoparticles in a controllable manner. Moreover, we demonstrated the superior ability of 1D nanohybrids as flexible, transparent, and conducting materials. The highly stable dispersion of 1D nanohybrids in aqueous solution enabled the fabrication of flexible, transparent, and conductive nanohybrid films using vacuum filtration, resulting in good optical and electrical properties.

Dispersion of Aqueous $Al_2O_3$Suspensions with Electrolytes; Influence of the Counter Ion

  • Cecile Pagnoux;Richard Laucournet;Thierry Chartier;Baumard, Jean-Francois
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.280-285
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    • 2000
  • The electrolyte, $(HO)_2C_6H_2(SO_3Na)_2H_2O $(Tiron), disperses efficiently alumina powder in aqueous media and stable suspensions with 60 vol% solid loading can be prepared. The strong adsorption of this additive is mainly due to the ability of the molecule to form chelate rings with the particle surface but electrostatic interactions between the surface charge and the anionic dispersant strongly influence the amount of Tiron adsorbed. By using a cationic exchange route to substitute the counter ion which neutralizes the sulfonate groups, new molecules of dispersant have been prepared, either with mineral cations as $Li^+,\; Na+^,\; NH_4^\;+$, or with organic cations as counter ion but organic counter ions lead to less to less viscous suspensions than $Na^+$ in particular when the number of carbon atoms of the aliphatic chain increases from 1 to 3.

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Catalyst Enhanced by Controlling Structure and Shape of Nanocrystals, Support Materials, and Hybrid System in DMFCs (나노입자의 구조와 모양, 담지체 및 하이브리드 시스템 제어를 통한 직접메탄올 연료전지의 촉매 개발)

  • Lee, Young Wook;Shin, Tae Ho
    • Ceramist
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    • v.22 no.2
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    • pp.189-197
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    • 2019
  • Direct methanol fuel cells (DMFCs) have found a wide variety of commercial applications such as portable computer and mobile phone. In a fuel cell, the catalysts have an important role and durability and efficiency are determined by the ability of the catalyst. The activity of the catalyst is determined by the structure and shape control of the nanoparticles and the dispersion of the nanoparticles and application system. The surface energy of nanoparticles determines the activity by shape control and the nanostructure is determined by the ratio of bi- and tri-metals in the alloy and core-shell. The dispersion of nanoparticles depends on the type of support such as carbon, graphen and metal oxide. In addition, a hybrid system using both optical and electrochemical device has been developed recently.

Calculation of the Dispersion Coefficient by the Dissolution Experiment of DNAPL Pool (DNAPL Pool의 용해실험에 의한 분산계수 산정)

  • 정경영;배열호;최상일
    • Journal of Korea Soil Environment Society
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    • v.1 no.1
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    • pp.19-27
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    • 1996
  • Nonaqueous phase liquids(NAPL) not readily dissolved in water exist as a separate fluid phase. Groundwater contamination by NAPL such as organic solvents and petroleum hydrocarbons becomes major public concerns because of their long-term persistence in the subsurFace and their ability to contaminate large volumes of wate. Dense.-than-water NAPL(DNAPL) spilled into the subsurface penetrate through the saturated zone and ultimately form DNAPL pools on the bottom of the aquifer. The dissolution of DNAPL from these pools depends on the molecular diffusion coefficient, the vertical dispersivity, the groundwater velocity, the solubility, and the pool length. In this study, the vertical transverse dispersion coefficients for simulating the dissolution of DNAPL from such pools were obtained from the dissolution experiment. Under the experimental conditions used, the vertical transverse dispersion coefficients calculated were 1.86$cm^2$/day, 2.90$cm^2$/day and 4.51$cm^2$/4ay for seepage velocities of 59.2cm/day, 94.3cm/day and 158.0cm/day, respectively. And the vertical transverse dispersivity was 0.03024cm.

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Tests on Superplasticizers for High Strength Concrete (고강도 콘크리트용 고성능감수제 성능평가)

  • 노재호;김기철;조일호;한정호;박연동
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.151-156
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    • 1994
  • This study is to investigate the quality of superplasticizers in domestic market. Therefore, the physico-chemical characteristics, the fluidity characteristics of fresh cement paste and mortar were tested. Also fresh and hardened properties of mortars and concretes using these superplasticizers were tested. From these results, differences of quality among superplasticizers are checked clearly in low water/cement ratio. And it is concluded that several superplasticizers have better dispersion ability than others in every tests. It has known that all samples are naphtalene sulfornate formaldehede types by the UV(ultra-violet) test.

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Simultaneous Removal of Cd &Cr(VI) by Fe-loaded zeolite in Column System (컬럼실험을 통한 Fe-loaded zeolite의 Cd& Cr(VI) 동시제거 반응성 평가)

  • Lee A-Ra;Lee Seung-Hak;Park Jun-Beom
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.151-154
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    • 2005
  • Laboratory column experiments for simultaneous removal of Cd and Cr(VI) are conducted using newly developed material, referred to as Fe-loaded zeolite, which has both reduction ability of iron and ion exchange ability of zeolite. Breakthrough curves were obtained from each column experiment, and described with advection-dispersion equation. Apparent parameters including $K_{app}\;and\;D_{app}$ were newly introduced for effectively describing the Cr(VI) breakthrough curve. $K_{app}$ decreased with increasing initial contaminant concentration and with decreasing flow rates. Whereas, $D_{app}$ were not significantly affected by initial contaminant concentration or flow rate.

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