• Title/Summary/Keyword: dispersed concentration

Search Result 317, Processing Time 0.025 seconds

Fabrication of CNT/PVDF Composite Film and Its Electrical Properties (CNT/PVDF 압전 복합막의 제작과 전기적 특성)

  • Lee, Sunwoo;Jung, Nak-Chun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.26 no.8
    • /
    • pp.620-623
    • /
    • 2013
  • The carbon nanotube / poly-vinylidene fluoride (CNT/PVDF) composite films for the nano-generator devices were fabricated by spray coating method using the CNT/PVDF solution, which was prepared by adding PVDF pellets into the CNT dispersed N-Methyl-2-pyrroli-done (NMP) solution. The flexible CNT/PVDF composite films were investigated by the scanning electron microscopy, which revealed that the CNTs were uniformly dispersed in the PVDF matrix and thickness of the films was approximately $20{\mu}m$. Fourier transform infra-red spectra were used to investigate crystal structure of the as-spray-coated CNT/PVDF films, and we found that they revealed extremely large portion of the ${\beta}$ phase PVDF. The capacitance of the CNT/PVDF films increased by adding CNTs into the PVDF matrix, and finally saturated. However, the resistance didn't show any saturation effect in the CNT concentration range of 0~4 wt%. Finally, the resulting nano-generator devices revealed reasonable current output after given mechanical stress.

DEVELOPMENT OF INTERFACIAL AREA TRANSPORT EQUATION

  • ISHII MAMORU;KIM SEUNGJIN;KELLY JOSEPH
    • Nuclear Engineering and Technology
    • /
    • v.37 no.6
    • /
    • pp.525-536
    • /
    • 2005
  • The interfacial area transport equation dynamically models the changes in interfacial structures along the flow field by mechanistically modeling the creation and destruction of dispersed phase. Hence, when employed in the numerical thermal-hydraulic system analysis codes, it eliminates artificial bifurcations stemming from the use of the static flow regime transition criteria. Accounting for the substantial differences in the transport mechanism for various sizes of bubbles, the transport equation is formulated for two characteristic groups of bubbles. The group 1 equation describes the transport of small-dispersed bubbles, whereas the group 2 equation describes the transport of large cap, slug or chum-turbulent bubbles. To evaluate the feasibility and reliability of interfacial area transport equation available at present, it is benchmarked by an extensive database established in various two-phase flow configurations spanning from bubbly to chum-turbulent flow regimes. The geometrical effect in interfacial area transport is examined by the data acquired in vertical fir-water two-phase flow through round pipes of various sizes and a confined flow duct, and by those acquired In vertical co-current downward air-water two-phase flow through round pipes of two different sizes.

Electrorheological Properties of Water Activated Silica Gel Suspensions (수분 활성 실리카 겔 분산계의 전기유변학적 특성)

  • 안병길;최웅수;권오관;문탁진
    • Tribology and Lubricants
    • /
    • v.13 no.3
    • /
    • pp.115-123
    • /
    • 1997
  • The electrorheological (ER) behavior of suspensions in silicone oil of silica gel powder (average particle size 49 $\mu$m) absorbed water was investigated at room temperature with electric fields up to 2.4 KV/mm. In this paper, for development of succcessful ER fluids used for wide temperature range later, we would like to know a fundamental understanding of water on ER effect. As a first step, the ER fluids involving water activated silica gel were measured not only the electrical characteristics such as dielectric constant, current density and electrical conductivity but also the rheological properties on the strength of electric field, the quantity of dispersed phase and absorbed water. From the experimental results that water absorbed to the particles directly affects to the surface charge density of electric double layer model proposed by Schwarz and makes dielectric constant and current density of ER fluids increase. The current density and dynamic yield stress $($\tau$_y)$ of water activated silica gel suspensions was in exponential proportion to the strength of electric field, the quantity of dispersed phase and absorbed water. And the optimum water quantity and weight concentration of silica gel for electrorheological effect were 4-5 wt% and 15 wt%, respectively.

Improvement Effect of Water Quality along the Water Discharged Area by Water Dispersion from the Sewage Disposal Plant (하수처리장 분산방류에 의한 방류수역의 수질개선효과)

  • Kim, Dong-Soo;Park, Jong-Tae;Kim, Yong-Gu;Park, Sung-Chun
    • Journal of Environmental Science International
    • /
    • v.17 no.1
    • /
    • pp.113-118
    • /
    • 2008
  • [ $6{\sim}13mg/L$ ] base water concentration on monthly BOD has been kept at the Geukrak bridge point for this research target and it indicates the water quality under the existed rank. Due to this present condition of water quality, the demage of ecology from the upper stream to the lower one of the bridge could be conjectured. Moreover, nonstructural extinction of the ecology seems to have gotten worse between both the streams of Yeoungsan River. On this research, eco-corridor between the upper stream and the lower stream of the river should be ensured, the ecological demage needs to be cut off, a dispersed discharge method which the existed method of the 1st sewage plant in Gwangju was enhanced to should be inducted for the procuring of various water ecosystem, and the conditions by the scenario suggested from this research could be applied to a water quality model. then, analysis the improvement effect of the water quality adjacent the river. From the test result, Case3-Type1 scenario is thought to be the best one. From the test result with Case3-Type1 when the concentrated discharge was never done, 0.07 mg/L of BOD concentration was increased at the lower stream where Yeoungbon B point (Haksan Bridge) is but the water improvement effect of $0.24{\sim}2.87mg/L$ is thought to have been done at the area of water deterioration.

Preparation of Mono-dispersed Polyamide 6(Nylon 6) Micro-particle (단분산린 Polyamide 6(Nylon 6) 미세입자의 제조)

  • Cho, Hangu-Gu;Kim, Hyung-Joong
    • Polymer(Korea)
    • /
    • v.31 no.4
    • /
    • pp.322-328
    • /
    • 2007
  • Mono-dispersed polyamide 6(Nylon 6) micro-particles sized in $4{\sim}5\;{\mu}m$ diameter were prepared by dispersion polymerization of ${\varepsilon}-caprolactam$ in liquid paraffin as a dispersion medium. Potassium metal(K) as a catalyst was separately added twice over the anionic ring-opening polymerization of ${\varepsilon}-caprolactam$. The size, shape, and size-distribution of prepared particles were varied with the concentration of anti-coagulant as well as the amount of initiator and catalyst. As the initiator concentration was in the range of $0.97{\sim}1.17\;wt%$ in monomer, about 90.6% of yield was accomplished. In addition, the highest yield of well-spherically shaped micro-particles was achieved by adding about $1.3{\sim}1.4\;wt%$ of catalyst.

Study on the Electro-Optic Characteristics Depending on UV Condition in the Normally Scattering(NS)/Normally Transparent(NT) Polymer Dispersed Liquid Crystal Mode (Normally Scattering(NS)/Normally Transparent (NT) 고분자 분산형 액정 모드에서 UV 조건에 따른 전기 광학특성 연구)

  • Kim, M.S.;Seo, Y.H.;Lee, M.H.;Rhee, J.M.;Lee, T.S.;Lee, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.07b
    • /
    • pp.1050-1053
    • /
    • 2003
  • Polymer dispersed liquid crystal mode can be classified into two cases, normally scattering mode (NS) and normally transparent (NT) mode according to an initial state. Electro-optic characteristic NS/NT PDLC mode can be improved by controlling the factors to influence the phase separation. In case of NS PDLC mode, we inspected change of a phase separation as a function of curing temperature for the mixture of E7 and NOA65 with different ratios. When the LC concentration is less than polymer such as LC : NOA65 = 40 : 60wt%, the PDLC cell is influenced strongly by the curing temperature. However, when LC concentration is much less than polymer such as LC : NOA65 : 80 : 20wt%, it is influenced slightly by the curing temperature. In case of NT PDLC mode, we observed change of a phase separation as a function of the ratio of the mixture and UV conditions such as curing temperature, UV intensity The cell made with strong UV intensity and curing temperature of $20^{\circ}C$, in case that the ratio of LC to polymer is 70:30wt%, showed good electro-optic characteristics.

  • PDF

Study on the Design of Contraceptive Agent(I) (피임제(避妊劑) 제형(製型) 개발(開發)에 관(關)한 연구(硏究)(I))

  • Kim, S.H.;Choi, J.S.;Baik, C.S.
    • Journal of Pharmaceutical Investigation
    • /
    • v.11 no.3
    • /
    • pp.14-20
    • /
    • 1981
  • One of the major objectives in the developments of a progesterone I.U.D. is to prepare devices which release drug at a constant rate for extended periods. A constant release rate is achived by maintaining drug concentration at a constant valve via the introduction of rate limiting membrane to solute diffusion at the surface of the devices. In this study, progesterone dispersed at monolithic device were prepared from polyhydroxy ethyl methacrylate. Constant release rate were obtained with device which were soaked in on ethanol-hexan solution. The release rate was dependant upon the concentration of the ethanolic solution in the soaking solution. This devices offer significant potential for futher development of hydrogel in the intrauterine contraception device for controlled release of progesterone.

  • PDF

Effects of Acrylonitrile and Acrylamide on Nitrile Hydratase Action of Brevibacterium sp. CH1 and CH2

  • Lee, Cheo-Young;Hwang, Jun-Sik;Chang, Ho-Nam
    • Journal of Microbiology and Biotechnology
    • /
    • v.1 no.3
    • /
    • pp.182-187
    • /
    • 1991
  • The effects of acrylonitrile and acrylamide on the enzyme action of nitrile hydratase of Brevibacterium sp. CH1 and CH2 strains used for the biotransformations of nitriles were studied. The excessive substrate (acrylonitrile) and product (acrylamide) inhibited the enzyme activity competitively. In comparison with 0.2 mol/l of CH1 strain, the substrate inhibition of CH2 strain began to appear only at a high acrylonitrile concentration of 0.91 mol/l. In a packed bed reactor, dispersed plug flow model was proposed and this model was proved to be valid by the experiment. Also acrylamide productivity decreased sharply when acrylamide concentration in the substrate solution exceeded 20% (wt/v).

  • PDF

Pervaporation Separation of Water/Ethanol Mixtures through PBMA/anionic PAA IPN Membrane

  • Jin, Young-Sub;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1996.10a
    • /
    • pp.86-87
    • /
    • 1996
  • IPN (Interpenetrating Polymer Network) is a mixture of two or more crosslinked polymers with physically interlocked network structures between the component polymers. IPN can be classified as an alloy of thermosets and has the characteristics of thermosets such as the thermal resistance and chemical resistance and also has the characteristics of polymer alloys with enhanced impact resistance and amphoteric properties. The physical interlocking during the synthesis restricts the phase separation of the component polymer with chemical pinning process, thus the control of morphology is possible through variations of the reaction temperature and pressure, catalyst concentration and crosslinking agent concentration. Finely dispersed domain structure can be obtained through IPN synthesis of polymer components with gross immiscibility. In membrane applications, particularly for the separation of liquid mixtures, crosslinked polymer component with specific affinity to the permeate is needed. With the presence of the permeant-inert polymer component, the mechanical strength and the selectivity of the membranes are enhanced by restricting the swelling of the transporting polymer component networks.

  • PDF

An Experimental Study on the Shear Buckling of a Composite Plate with Bead and Hole (비드와 원공을 갖는 복합재 평판의 전단 좌굴 실험에 관한 연구)

  • 임효식;김주언;황정선
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.3 no.1
    • /
    • pp.146-154
    • /
    • 2000
  • Buckling behavior was studied for the square plate with bead and hole under shear load. Plates were made to examine the effect of bead and hole to the material, aluminum and composite, the effect of flange angle, bead height and bead radius of curvature. There was little difference between buckling loads obtained by the experiment and Rayleigh-Ritz method to the plate. Buckling load could be increased highly when stress concentration to the hole was dispersed effectively using flange. A well-designed plate using bead and flange showed 3 times as much as stiffness to the plate without bead and flange.

  • PDF