• Title/Summary/Keyword: discharge capacity improvement

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Study on electrochemical performances of sulfur-containing graphene nanosheets electrodes for lithium-sulfur cells

  • Son, Ki-Soo;Kim, Seok
    • Carbon letters
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    • v.15 no.2
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    • pp.113-116
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    • 2014
  • Due to their morphology, electrochemical stability, and function as a conducting carbon matrix, graphene nanosheets (GNS) have been studied for their potential roles in improving the performance of sulfur cathodes. In this study, a GNS/sulfur (GNS/S) composite was prepared using the infiltration method with organic solvent. The structure, morphology and crystallinity of the composites were examined using scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. The electrochemical properties were also characterized using cyclic voltammetry (CV). The CV data revealed that the GNS/S composites exhibited enhanced specific-current density and ~10% higher capacity, in comparison with the S-containing, activated-carbon samples. The composite electrode also showed better cycling performance for multiple charge/discharge cycles. The improvement in the capacity and cycling stability of the GNS/S composite electrode is probably related to the fact that the graphene in the composite improves conductivity and that the graphene is well dispersed in the composites.

Influence of the impeller inlet angles on flow pattern and characteristics of mixed-flow pump (사류 임펠러의 입구각 변화가 내부유동 및 펌프특성에 미치는 영향)

  • Lee, Seon-Gi
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.8
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    • pp.1034-1045
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    • 1997
  • For the improvement of the pump characteristics in the partial capacity range, it must be verified that the influence of the impeller design factor on the internal flows and the influence of the impeller internal flows on the pump characteristics. In this paper, in order to understand the influence of inlet angles on flow conditions and characteristics of a mixed flow pump, experiments were carried out for three kinds of impeller, which have the same outlet angle distributions and meridional section shapes. Results show that separation and stall in the partial capacity range can be controlled by the inlet angles. The relationship between the separation - stall at the impeller leading edge and the discharge flow conditions is clarified.

Electrochemical properties of all solid state Li/LiPON/Sn-substituted LiMn2O4 thin film batteries

  • Kong, Woo-Yeon;Yim, Hae-Na;Yoon, Seok-Jin;Nahm, Sahn;Choi, Ji-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.409-409
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    • 2011
  • All solid-state thin film lithium batteries have many applications in miniaturized devices because of lightweight, long-life, low self-discharge and high energy density. The research of cathode materials for thin film lithium batteries that provide high energy density at fast discharge rates is important to meet the demands for high-power applications. Among cathode materials, lithium manganese oxide materials as spinel-based compounds have been reported to possess specific advantages of high electrochemical potential, high abundant, low cost, and low toxicity. However, the lithium manganese oxide has problem of capacity fade which caused by dissolution of Mn ions during intercalation reaction and phase instability. For this problem, many studies on effect of various transition metals have been reported. In the preliminary study, the Sn-substituted LiMn2O4 thin films prepared by pulsed laser deposition have shown the improvement in discharge capacity and cycleability. In this study, the thin films of LiMn2O4 and LiSn0.0125Mn1.975O4 prepared by RF magnetron sputtering were studied with effect of deposition parameters on the phase, surface morphology and electrochemical property. And, all solid-state thin film batteries comprised of a lithium anode, lithium phosphorus oxy-nitride (LiPON) solid electrolyte and LiMn2O4-based cathode were fabricated, and the electrochemical property was investigated.

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The performance and quality improvement of Lithium ion Batteries

  • Xiaoping Li
    • 한국전기화학회:학술대회논문집
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    • 2004.11a
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    • pp.75-108
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    • 2004
  • The market, development and trend of Lithium ion Batteries in China are introduce briefly. Early, Chinese manufactories were busy to expand and many new battery factories have been built up. Now, the relatively large companies pay more attentions on comprehensive quality improvement, therefore the production processing and facilities have been also modified in some extent. The recent technology progresses focus on High capacity (energy density), High rate, High average voltage, High safety, High temperature properties, Long cycle life, Low temperature properties, Low self discharge, Low cost, Super-large, Super-small, Super-thin, Consistency, Customization, and Environment friendly processing, simply $H_5L_4S_3C_2E_1$. Lithium ion polymer batteries which all batteries packaged with soft lamination film are named as in China have a quick growth and emphasized here because of their advantages ins $H_5L_4S_3C_2E_1$ for which it is quite difficult to be realized at the same time. Some of research works such as listed above are introduced. The other contends related to application trend of Lithium ion batteries and projects carrying out are also included.

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The Ecological Modeling for Estimation of Carrying Capacity in Masan Bay in 2002 summer (2002년 하계 마산만의 수질개선을 위한 환경용량산정 모델링)

  • Hong, Sok Jin;Lee, Won Chan;Park, Sung Eun;Jung, Rea Hong;Cho, Yoon Sik;Park, Jong Su;Kim, Dong Myung
    • Journal of Wetlands Research
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    • v.9 no.2
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    • pp.57-69
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    • 2007
  • This study focused on coastal water quality response to land-based and sediment pollution loads and estimation of the carrying capacity in Masan Bay using an ecological model with the data in summer of 2002. A residual current was simulated to have a slightly complicated pattern with ranging from 0.1 to 1.5 cm/s. In Masan Bay, pollutant materials cannot flow from the inner to the outer bay easily because of residual currents flow southward at surface and northward at the bottom. The simulation results of COD distribution showed high concentrations over 3 mg/L in the inner part of Masan Bay related pollutant discharge. For improvement seawater quality grade I in Masan Bay, it is necessary to reduce the organic and inorganic loads from point sources by more than 80%. For improvement seawater quality grade II, it is necessary to reduce the organic and inorganic loads from point sources by more than 50% and ameliorate severe polluted sediment. The carrying capacity for COD is 2.32 ton/day and 7.16 ton/day for each grade.

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The Coating Effects of Al2O3 on a Li[Li0.2Mn0.54Co0.13Ni0.13]O2 Surface Modified with (NH4)2SO4

  • Oh, Ji-Woo;Oh, Rye-Gyeong;Hong, Jung-Eui;Yang, Won-Geun;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1516-1522
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    • 2014
  • A series of 20 wt % $(NH_4)_2SO_4$ and 3 wt % $Al_2O_3$ surface treatments were applied to $Li[Li_{0.2}Mn_{0.54}Co_{0.13}Ni_{0.13}]O_2$ substrates. The $Li[Li_{0.2}Mn_{0.54}Co_{0.13}Ni_{0.13}]O_2$ substrates were synthesized using a co-precipitation method. Sample (a) was left pristine and variations of the 20 wt % $(NH_4)_2SO_4$ and 3 wt % $Al_2O_3$ were applied to samples (b), (c) and (d). XRD was used to verify the space group of the samples as R$\bar{3}$m. Additional morphology and particle size data were obtained using SEM imagery. The $Al_2O_3$ coating layers of sample (b) and (d) were confirmed by TEM images and EDS mapping of the SEM images. 2032-type coin cells were fabricated in a glove box in order to investigate their electrochemical properties. The cells were charged and discharged at room temperature ($25^{\circ}C$) between 2.0V and 4.8V during the first cycle. The cells were then charged and discharged between 2.0V and 4.6V in subsequent cycles. Sample (d) exhibited lower irreversible capacity loss (ICL) in the first charge-discharge cycle as compared to sample (c). Sample (d) also had a higher discharge capacity of ~250 mAh/g during the first and second charge-discharge cycles when compared with sample (c). The rate capability of the $Al_2O_3$-coated sample (b) and (d) was lower when compared with sample (a) and (c). Sample (d), coated with $Al_2O_3$ after the surface treatment with $(NH_4)_2SO_4$, showed an improvement in cycle performance as well as an enhancement of discharge capacity. The thermal stability of sample (d) was higher than that of the sample (c) as the result of DSC.

Single-phase SRM Drive for Torque Ripple Reduction and Power Factor Improvement (토크리플 억제와 역률개선을 위한 단상 SRM의 구동시스템)

  • Ahn Jin-Woo;Liang Jianing
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.55 no.8
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    • pp.389-395
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    • 2006
  • In the single-phase switched reluctance motor (SRM) drive, the required DC source is generally supplied by the circuit consisting of bridge rectifier with diodes and many filter capacitances connected with AC source. Although the peak torque ripple of SRM is small because of large capacity of the capacitance, the charge and discharge time swhich the AC source acts on the capacitance are small and the peak current will pass on the side of source, so power factor and system efficiency decrease. Therefore a novel SRM drive system is presented in this paper, which includes drive circuit realizing reduction of torque ripple and improvement of power factor and switching topology. The proposed drive circuit consists of one switching part and diodes which can separate the output of AC/DC rectifier from the large capacitance and supply power to SRM alternately in order to realize reduction of torque ripple and improvement of power factor through the turn on and turn off of switching part. In addition, the validity of method is tested by simulation and experiment.

Connection algorithm of Real Time Digital Simulator with HTS SMES for power quality improvement (전력품질 개선을 위한 초전도 에너지 저장장치와 실시간 전력계통 시뮬레이터의 연계 알고리즘 개발)

  • Kim, A-Rong;Kim, Dae-Won;Kim, Gyeong-Hun;Kim, Jin-Geun;Park, Min-Won;Yu, In-Keun;Sim, Ki-Deok;Kim, Seock-Ho;Seong, Ki-Chul
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.601_602
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    • 2009
  • Superconducting Magnetic Energy Storage (SMES) system is one of the key technologies to overcome the voltage sag, swell, interruption and frequency fluctuation by fast response speed of current charge and discharge. In order to evaluate the characteristics of over mega joule class grid connected High Temperature Superconducting (HTS) SMES system, the authors proposed an algorithm by which the SMES coil could be connected to the Real Time Digital Simulator (RTDS). Using the proposed algorithm, users can perform the simulation of voltage sag and frequency stabilization with a real SMES coil in real time and easily change the capacity of SMES system as much as they need. To demonstrate the algorithm, real charge and discharge circuit and active load were manufactured and experimented. The results show that the current from real system was well amplified and applied to the current source of simulation circuit in real time.

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A Study on the Improvement of Means of Egress Based on NFPA 101 (NFPA 101 피난 안정성 평가에 기초한 피난 규정 개선 방향 연구)

  • Kyeung-Ho Kang;Suck-Hwan Joung
    • Journal of the Korea Safety Management & Science
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    • v.25 no.1
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    • pp.31-38
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    • 2023
  • The object of this study is to evaluate whether the means of egress of Jechon Sports Center and Miryang Sejong Hospital, where massive fire human casualties occurred in 2017 and 2018 respectively, comply with NFPA 101(Life Safety Code), and to suggest the need for supplementation of domestic means of egress regulations. The study evaluated the number and arrangement of the means of egress, travel distance, common path of travel, dead end and discharge from exit for each building by applying the means of egress regulations of NFPA 101. As a result of the evaluation through NFPA 101, the travel distance was appropriate, but some of the other items except for the travel distance did not meet NFPA 101. The regulations that need to be supplemented are 1)occupant load calculation 2)egress capacity calculation 3)continuous concept of means of egress 4)concept of common path of travel. It is especially necessary to revise the requirement for fire door of the evacuation floor(normal 1st floor) of the stairwell in case of below the five story building.

Improvement in Cycle Characteristics using PVP Based Direct Carbon Coating During High-Rate Charge and Discharge of Li[Ni0.93Co0.07]O2 Nanofibers: Application for Lithium Secondary Batteries

  • Hae In Kim;Hyun Ju Jang;Thuy Thi Bich Tran;Jong-Tae Son;Eui Jeong Park
    • Journal of Electrochemical Science and Technology
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    • v.14 no.2
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    • pp.139-144
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    • 2023
  • In this study, carbon-coated porous nanofibers were prepared via electrospinning and the performance of Li[Ni0.93Co0.07]O2 (NC) synthesized by electrospinning (E-NC) and co-precipitation (C-NC) was compared. E-NC had a discharge capacity of 206 mAh g-1 at 0.1C (17 mA/g), which is 10% higher than that of C-NC (189.2 mAh g-1). E-NC shows a high-rate performance of 118.32 mAh g-1 (61.7%) at 5C (850 mA/g), which is 50% higher than that of C-NC (78.22 mAh g-1 = 45.7%). Charge transfer of the carbon-coated porous nanofiber E-NC decreased by 35% compared to C-NC after 20 cycles as observed using electrochemical impedance spectroscopy. The results of this study show that the nanofiber structure with carbon coating shortens the Li-ion diffusion path, improves electrical conductivity, resulting in excellent rate performance.