• Title/Summary/Keyword: direct limit

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The Coordination of Pyridyl-N to Pentacyanoferrate for the Electrochemical Detecting Small Organic Molecules

  • Choi, Young-Bong;Jeon, Won-Yong;Kim, Hyug-Han
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.595-599
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    • 2013
  • The coordination of pyridyl-N to pentacyanoferrate for the detection of small organic antigens in solution is presented. The unique contribution of this paper is the direct conjugation of pyridyl-N in small organic antigens to pentacyanoferrate. Pentacyanoferrate is promising as an electrochemical label owing to its good electro-chemical properties, which can be utilized to generate an electrical signal in homogeneous electrochemical immunoassays. The facilely synthesized pyridyl-N to pentacyanoferrate was characterized by the electrochemical and spectroscopic methods. Hippuric acid (HA) has been detected competitively on the interaction of free HA and pentacyanoferrate-(4-aminomethylpyridine-hippuric acid) (Fe-HA) to its antibody, with the detection limit of 0.50 ${\mu}g\;mL^{-1}$. While pentacyanoferrate-based immunoassay is in its simplicity and infancy, the proposed immunoassay offers attractive opportunities for developing pyridyl-N-based the electrochemical detection of small organic antigens in the health care area.

A Study on the MPPT Control Method for Grid-connected Multi-String Three-Phase Three-Level PV Inverter (계통연계형 멀티스트링 3상 3레벨 태양광 인버터의 MPPT 제어방법에 관한 연구)

  • Kim, Jinsoo;Yang, Oh
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.4
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    • pp.43-48
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    • 2014
  • Two-level inverter has some disadvantages like high harmonics contained in the output current, efficiency limit and stress to switching device as IGBT and FET. Many researches have reported multi-level inverter to complement two-level inverter of problems. In this paper, we suggest MPPT algorithm of multi-string three-level solar inverter that considered nowadays. We added midpoint controller in order to implement the MPPT algorithm because the three-level inverter has to need midpoint controller and procured the stability of direct current link. We verify the superiority of multi-string T-Type inverter and the algorithm we suggested with solar irradiance variation experiment and MPPT efficiency measurement. The MPPT efficiency was confirmed with a high efficiency more than 99.97%.

Presentation of the Efficient Leakage Detection by the Measurement of Indirect Media-Propagated AE Signal (간접 매체로 전파된 AE신호 측정을 통한 효과적인 누설 검출기법 제시)

  • 이성재;김전하;강명창;김정석
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.9
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    • pp.63-68
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    • 2004
  • The high pressure vessels that are constructed by welding process have many welding lines and most of the leakage defects are occurred on these welding lines. The acoustic emission(AE) technique has adopted to detect the defect location and leakage on welding parts, but the AE signal in leakage are incomplete due to the attenuation, reiteration, instability and limit of defect size. To overcome these troubles, the experiments in this study are conducted to measure the indirect media-propagated AE signal perpendicular to the leakage hole. The AE signals that are acquired from the direct and indirect media are analyzed, and the reliability of the indirect media-propagated AE signal are examined experimentally. By AE signal investigation, this method can be adopted to detect efficiently the leakage in welding parts.

Direct Earthquake Design Using Secant Stiffness (할선강성을 이용한 직접내진설계)

  • 박홍근;엄태성
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2003.09a
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    • pp.239-246
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    • 2003
  • A new earthquake design method performing iterative calculations using secant stiffness was developed. The proposed design method has the advantages of convenience and stability in numerical analysis because it uses elastic analysis. At the same time, the proposed design method can accurately estimate the strength and ductility demands on the members because it performs the analysis on the inelastic behavior of structure using iterative calculation. In the present study, the procedure of the proposed design method was established, and a computer program incorporating the proposed method was developed. Design examples using the proposed method were presented, and its advantages were presented by the comparisons with existing design methods using elastic or inelastic analysis. The proposed design method, as an integrated method of analysis and design, can address the earthquake design strategy devised by the engineer, such as ductility limit on each member, the design concept of strong column - weak beam, and etc. Through iterative calculations on the structure preliminarily designed only with member sizing, the strength and ductility demands of each member can be directly calculated so as to satisfy the given design strategy As the result economical and safe design can be achieved.

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A Study of Demand Response Resource in Ancillary Service (계통보조서비스에서 부하자원의 활용방안에 대한 고찰)

  • Kim S.C.;Yoo S.Y.;Kim H.J.;Kim H.J.;Park J.B.;Sin J.R.
    • Proceedings of the KIEE Conference
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    • summer
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    • pp.663-665
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    • 2004
  • There are some demand response program which is Direct Load Control and so on in Korea. These are used to manage lack of power stability or shift peak time for shading load. It is very important not only using stability power system but controling and scheduling power system on the whole. Interruptible loads are essential resources to solve lack of energy and limit of constructing generator On recently days, Demand Response Program's reliability is recognized as ancillary or reserve service in many country. This paper presents a necessity to apply demand resource to our ancillary program. For this reason, it is introduce overseas ancillary program using load resource.

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Determination of Pd(II) and Pt(II) Metal Cyano Complexes Using Capillary Electrophoresis

  • Lee, Hue-Jin;Lee, Sang-Ho;Chung, Koo-Soon;Lee, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • v.15 no.11
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    • pp.945-949
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    • 1994
  • Mixtures of cyano complexes of palladium(II) and platinum(II) were separated by capillary electrophoresis using a fused silica capillary as a separation column and 30 mM phosphate buffer (pH 7) containing 15 wt. % acetonitrile as a running buffer. By virtue of the high ionic mobilities of the negatively charged cyano complexes of Pd(II) and Pt(II), they were separated using a cathodic injection and anodic detection scheme. The metal complexes eluted through the capillary were detected by direct UV absorption at 214 nm. A linear relationship between peak area and concentration was obtained for both ions and the detection limit was lower than $10^{-14}$ mole. The proposed method was applied to real sample, e.g., anode slime obtained from an electrolytic copper refinary, as a method for the simultaneous determination of palladium and platinum.

Assay of Midazolam in Human Plasma by Gas-Liquid Chromatography with Nitrogen-Phosphorus Detection

  • 신호상;홍춘표;Yun-Suk Oh-Shin;강보경;이경옥;이규범
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.524-526
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    • 1998
  • A sensitive and specific method is described for the determination of midazolam in human plasma. The drug was extracted from 1 mL of carbonate buffered plasma (pH 9.6) with 8 mL of diethyl ether. Famprofazone was used as internal standard. The organic phase was evaporated to dryness. The residue was dissolved in methanol for the direct analysis by gas chromatograph-nitrogen phosphorus detector system. In the concentration range of 1-5000 ng/mL, the calibration curve was linear. The coefficients of variation from the precision test were <6% at the range of the concentration of 0.10-2.00 μg/mL and the detection limit for midazolam in 1 mL of plasma was o.5 ng. This assay is more sensitive, selective, simple and rapid than earlier methods. Plasma midazolam concentrations were determined by this method after administration of midazolam.

TOWARD AN ACCURATE APPROACH FOR THE PREDICTION OF THE FLOW IN A T-JUNCTION: URANS

  • Merzari, E.;Khakim, A.;Ninokata, H.;Baglietto, E.
    • Nuclear Engineering and Technology
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    • v.41 no.9
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    • pp.1191-1204
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    • 2009
  • In this study, a CFD methodology is employed to address the problem of the prediction of the flow in a T-junction. An Unsteady Reynolds Averaged Navier-Stokes (URANS) approach has been selected for its low computational cost. Moreover, Unsteady Reynolds Navier-Stokes methodologies do not need complex boundary formulations for the inlet and the outlet such as those required when using Large Eddy Simulation (LES) or Direct Numerical Simulation (DNS). The results are compared with experimental data and an LES calculation. In the past, URANS has been tried on T-junctions with mixed results. The biggest limit observed was the underestimation of the oscillatory behavior of the temperature. In the present work, we propose a comprehensive approach able to correctly reproduce the root mean square (RMS) of the temperature directly downstream of the T-junction for cases where buoyancy is not present.

III-V/Si Optical Communication Laser Diode Technology (광통신 III-V/Si 레이저 다이오드 기술 동향)

  • Kim, H.S.;Kim, D.J.;Kim, D.C.;Ko, Y.H.;Kim, K.J.;An, S.M.;Han, W.S.
    • Electronics and Telecommunications Trends
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    • v.36 no.3
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    • pp.23-33
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    • 2021
  • Two main technologies of III-V/Si laser diode for optical communication, direct epitaxial growth, and wafer bonding were studied. Until now, the wafer bonding has been vigorously studied and seems promising for the ideal III-V/Si laser. However, the wafer bonding process is still complicated and has a limit of mass production. The development of a concise and innovative integration method for silicon photonics is urgent. In the future, the demand for high-speed data processing and energy saving, as well as ultra-high density integration, will increase. Therefore, the study for the hetero-junction, which is that the III-V compound semiconductor is directly grown on Si semiconductor can overcome the current limitations and may be the goal for the ideal III-V/Si laser diode.

Labor Market Regulation and MNE's Production: Evidence from OECD Countries

  • Choi, Hyelin
    • Journal of Korea Trade
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    • v.23 no.4
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    • pp.115-130
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    • 2019
  • Purpose - This paper examines the impact of labor market regulations on FDI and the production of foreign firms. Design/methodology - We use an index of employment protection along with data on the FDI and production of foreign affiliates that are provided by the OECD. Findings - The empirical results show that strict employment protection discourages both the production and initial entry of foreign firms, with its impact on production being larger than that on the initial entry decision. The result is robust to various specifications in which instrumental variable estimations are used by applying a unionization rate and a severance pay for redundancy dismissal as instruments, respectively. Therefore, policymakers should not limit their focus to tax incentives, cash grants, and relaxation of market regulations, but they should also extend their attention to labor market deregulation and decreasing non-wage cost to attract more foreign firms into their countries. Originality/value - This paper attempts to answer the question on the impact of employment protection rules on the foreign firm's decisions regarding production as well as initial entry.