• 제목/요약/키워드: direct limit

검색결과 475건 처리시간 0.026초

Direct Electrochemistry and Electrocatalysis of Myoglobin with CoMoO4 Nanorods Modified Carbon Ionic Liquid Electrode

  • Zhao, Zengying;Cao, Lili;Hu, Anhui;Zhang, Weili;Ju, Xiaomei;Zhang, Yuanyuan;Sun, Wei
    • Bulletin of the Korean Chemical Society
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    • 제34권2호
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    • pp.475-481
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    • 2013
  • By using ionic liquid 1-hexylpyridinium hexafluorophosphate ($HPPF_6$) based carbon ionic liquid electrode (CILE) as the substrate electrode, a $CoMoO_4$ nanorods and myoglobin (Mb) composite was casted on the surface of CILE with chitosan (CTS) as the film forming material to obtain the modified electrode (CTS/$CoMoO_4$-Mb/CILE). Spectroscopic results indicated that Mb retained its native structures without any conformational changes after mixed with $CoMoO_4$ nanorods and CTS. Electrochemical behaviors of Mb on the electrode were carefully investigated by cyclic voltammetry with a pair of well-defined redox peaks from the heme Fe(III)/Fe(II) redox center of Mb appeared, which indicated that direct electron transfer between Mb and CILE was realized. Electrochemical parameters such as the electron transfer number (n), charge transfer coefficient (${\alpha}$) and electron transfer rate constant ($k_s$) were estimated by cyclic voltammetry with the results as 1.09, 0.53 and 1.16 $s^{-1}$, respectively. The Mb modified electrode showed good electrocatalytic ability toward the reduction of trichloroacetic acid in the concentration range from 0.1 to 32.0 mmol $L^{-1}$ with the detection limit as 0.036 mmol $L^{-1}$ ($3{\sigma}$), and the reduction of $H_2O_2$ in the concentration range from 0.12 to 397.0 ${\mu}mol\;L^{-1}$ with the detection limit as 0.0426 ${\mu}mol\;L^{-1}$ ($3{\sigma}$).

전단동축형인젝터를 통해 분사된 메탄-산소 이원추진제의 연소특성 (Combustion Characteristics of the Methane-Oxygen Bipropellant Injected by a Shear-coaxial Injector)

  • 홍준열;배성훈;배대석;김정수
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.787-790
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    • 2017
  • 본 연구는 이원추진제 추력기(thruster)에 사용되는 메탄-산소 연소특성규명의 선행연구로서 모델연소실 내 전단동축형인젝터를 통해 분사된 기체메탄-기체산소 비예혼합화염의 연소안정한계 및 화염형상을 도출하기 위한 실험적 연구가 수행되었다. DSLR 카메라를 이용하여 화염 직접이미지(direct image)를 촬영하였고, 이미지 후처리(post-processing)를 통해 연소특성파악 및 화염길이 정량화를 수행하였다. 그 결과, 산화제 레이놀즈 수($Re_o$)가 증가함에 따라 이론반응비(stoichiometric ratio)에서 안정된 화염이 발생하였고, 동일 인젝터직경 조건에서 난류화염의 길이가 늘어남을 확인하였다.

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직접전단을 받는 보강점토의 거동에 관한 연구 (A Study on the Behavior of Reinforced Clay Subjected to Direct Shear)

  • 유한규
    • 한국지반공학회지:지반
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    • 제10권4호
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    • pp.67-82
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    • 1994
  • 본 연구에서는 강 함유재에 의한 점토에서의 전단강도 증가를 예측하기 위하여 직접전단하에서 힘의 한계평형에 근거한 보강점토 모델이 제안되었다. 본 모델은 함유재의 방향과 길이, 함유재와 점토사이 부착응력 및 함유재의 이동에 따른 흙의 수동저항력이 보강점토의 거동에 미치는 영향을 고려하였다. 이론적인 예측과 비교검토하기 위하여 개폐된 전단박스로 구성된 직접전단 장치를 이용하여 직접전단시험을 실시하였다. 또한 함유재와 점토사이의 부착응력을 산정하기 위하여 인발실험을 실시하였다. 시험결과 보강점토의 전단응력의 증가 또는 감소는 함유재의 방향과 점토의 함수비와 관련되어 있음을 알았다. 이론적인 예측과 시험결과를 비교한 결과 본 이론적인 모델은 함유재의 방향과 함유재의 이동에 따른 흙의 수동 저항력이 보강점토의 역학적인 거동에 미치는 영향을 비교적 잘 예측 해주고 있음을 알 수 있었다.

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막 기반 직접공기포집: 총설 (Membrane-Based Direct Air Capture: A Review)

  • 양성백;임광섭;니키타 쿠마리;남상용
    • 공업화학
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    • 제35권2호
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    • pp.85-95
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    • 2024
  • 직접공기포집 기술은 기후 변화 완화에서 중요한 역할을 하고 있다. 국제에너지기구와 기후변화에 관한 보고서에서는 이러한 중요성을 강조하고 있고, 탄소의 지속적인 배출에도 불구하고 이를 감소시킴으로써 지구 온난화를 1.5 ℃로 제한하는 것을 목표로 한다. 직접공기포집 기술은 초기 비용에도 불구하고 연구 및 개발, 운영 학습 및 규모의 경제를 통한 비용 절감의 가능성을 보여주고 있다. 최근 고투과도를 갖춘 고분자 막의 발전은 막 기반 직접공기포집 기술에 대한 잠재력을 제시하고 있으나, 효과적인 대기 중 CO2 분리를 위해서는 CO2에 대한 높은 선택성과 투과성을 갖춘 막을 필요로 한다. 현재 연구는 막 최적화 연구를 다수의 연구팀에 의하여 연구되고 있으며, CO2 포집 효율을 향상시키는 데 중점을 두고 있다. 본 연구에서는 직접공기포집의 중요성, 발전 중인 비용 동향 및 기후 변화 완화에 있어서 막의 발전이 중요한 역할을 강조하고 있고, 덧붙여서 이 연구에서는 막 기반 DAC에서의 permeance와 selectivity의 이론적 배경, 조건, 구성, 장단점에 대해 알아보았다.

Development of the remote control system for Internet-based mobile robot using Embedded Linux and Qt

  • Park, Tae-Gyu;Jeon, Jae-Wook
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2003년도 ICCAS
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    • pp.622-627
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    • 2003
  • The existing remote control system have some inherent disadvantage of direct control in the limit range. In some special cases, for example, a power apparatus, an unmanned factory, a nuclear factory, a security management system, the tele-operation is needed to control remote robot without limit space. This field is based on the Internet communication. Because the Internet is constructed all over the world. And it is possible that we control remote mobile robot in the long distance. In this paper, we developed a remote control system. This system is divided into two primary parts. These are local site and remote site. There are the moving robot and web server in the remote site and there is the robot control device in local site. The moving robot is moved by two stepper motors and the robot control device consists of SA-1100 micro controller and embedded Linux. And this controller is an embedded system. Public personal computer which is connected the Internet is used for the web server. The web server provides the mobile robot control interface program to the remote controller and captures the image for feedback information. In the whole system, a robot control device is connected with moving robot and web server through the Internet. So the operator can control the moving robot in the distance through the Internet.

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A dual approach to perform geometrically nonlinear analysis of plane truss structures

  • Habibi, AliReza;Bidmeshki, Shaahin
    • Steel and Composite Structures
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    • 제27권1호
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    • pp.13-25
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    • 2018
  • The main objective of this study is to develop a dual approach for geometrically nonlinear finite element analysis of plane truss structures. The geometric nonlinearity is considered using the Total Lagrangian formulation. The nonlinear solution is obtained by introducing and minimizing an objective function subjected to displacement-type constraints. The proposed method can fully trace the whole equilibrium path of geometrically nonlinear plane truss structures not only before the limit point but also after it. No stiffness matrix is used in the main approach and the solution is acquired only based on the direct classical stress-strain formulations. As a result, produced errors caused by linearization and approximation of the main equilibrium equation will be eliminated. The suggested algorithm can predict both pre- and post-buckling behavior of the steel plane truss structures as well as any arbitrary point of equilibrium path. In addition, an equilibrium path with multiple limit points and snap-back phenomenon can be followed in this approach. To demonstrate the accuracy, efficiency and robustness of the proposed procedure, numerical results of the suggested approach are compared with theoretical solution, modified arc-length method, and those of reported in the literature.

직접분사식 가솔린엔진의 분사 비율에 따른 연소특성에 관한 연구 (A Study on the Characteristics of Combustion according to Injection Strategy in DISI Engine)

  • 인병덕;박상기;이기형
    • 한국자동차공학회논문집
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    • 제20권1호
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    • pp.68-76
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    • 2012
  • Recently, the important issues of gasoline engine are to reduce the fuel consumption and emission. Thus, many researchers are studying the technology to solve these problems. One approach of these issues is to achieve homogeneous charge combustion and stratified change combustion with various injection strategy. In this study, the combustion characteristics of DISI engine accrding to injection strategy were examined. The effect of injection timing on lean limit A/F were investigated using dual DISI single cylinder. The results show that the engine operation region of dual DISI type engine is larger than that of PFI and DISI type engine cases. Especially, late injection is very effective to extend the operation region more than any other injection timings. In addition, the results show that when the DISI injection ratio is increase, leam limit A/F is improved. It means that the dual injection system car meet with emission regulations and reduce the fuel consumption. Also, combustion pressure of dual injection system is much higher than PFI and DISI injection.

유동응력, 마찰, 온도, 속도 등이 단조 중 단류선의 유한요소예측에 미치는 영향 (Effect of Flow Stress, Friction, Temperature, and Velocity on Finite Element Predictions of Metal Flow Lines in Forgings)

  • 최무호;진호태;전만수
    • 소성∙가공
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    • 제24권4호
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    • pp.227-233
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    • 2015
  • In this paper, the effect of flow stress, friction, temperature, and velocity on finite element predictions of metal flow lines after cylindrical upsetting is presented. An actual three-stage hot forging process involving an upsetting step is utilized and experimental metal flow lines are measured to study the effect of the various process variables. It was found that temperature and velocity for reasonable values of friction have little influence on metal flow lines especially those located deep within the cylinder but that flow stress has a direct influence on the flow lines. It was shown that a pure power law material model cannot reflect the real flow stress of hot material because it underestimates the flow stress especially around the dead-metal zone for the upsetting of a cylindrical specimen. It is thus recommended that a proper lower limit of flow stress be assumed to alleviate this issue.

철근콘크리트 합성 H-Pile의 휨성능 (Flexural Capacity of RC Composited H-Pile)

  • 김민준;신근옥;정제평
    • 콘크리트학회논문집
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    • 제28권5호
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    • pp.563-570
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    • 2016
  • 서로 다른 응력-변형률 구성관계를 갖는 2가지 이상의 재료로 구성된 합성구조부재의 사용이 크게 증가하고 있다. 본 연구에서는 철근 및 콘크리트로 보강한 합성 H-Pile의 휨성능을 평가하고자 8개의 실험체를 제작하여 휨실험을 실시하였다. 실험결과 합성H-Pile의 휨성능이 무보강 H-Pile보다 10~30%정도 크게 나타났고, 연성능력은 2배 이상, 에너지소산능력은 3배 이상 증가하였다. 한계상태해석 결과는 실험보다 보수적인 강도예측을 하였다.

가스설비의 신뢰도데이터 수집방법에 관한 연구 (A Study on the Collecting Method of Reliability Database for Gas Facilities)

  • 이광원;윤익근;한상태;오신규;김태훈
    • 한국안전학회지
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    • 제23권2호
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    • pp.37-44
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    • 2008
  • The safety assessment for facility industry is now being periodically performed. For the purpose of scientific safety management, QRA(Quantitative Risk Assessment) is also being performed, and reliability data of the facilities is essential to perform the assessment. Generally, the existing safety assessment is performed by using the values announced in other industry processes, which result in the drop of reliability. In order to solve this problem, there is an urgent need to establish reliability database for the facilities. The most appropriate method is to perform a direct reliability analysis towards the facilities undergoing safety assessment. In this study, in compliance with the assessment method and procedure of OREDA-2002 handbook, the facility reliability data are collected, which include the calendar time and operational time in terms of different facility items, the number of failures in terms of different failure mode, the mean, standard deviation, lower limit and upper limit of failure rate, and the failure rate. And the data process method for this special occasion is also proposed when the number of failure is 0.