• Title/Summary/Keyword: direct dye

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Template-directed Atomic Layer Deposition-grown $TiO_2$ Nanotubular Photoanode-based Dye-sensitized Solar Cells

  • Yu, Hyeon-Jun;Panda, Sovan Kumar;Kim, Hyeon-Cheol;Kim, Myeong-Jun;Yang, Yun-Jeong;Lee, Seon-Hui;Sin, Hyeon-Jeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.239.1-239.1
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    • 2011
  • Dye sensitized solar cells (DSC) are promising devices for inexpensive, nontoxic, transparent, and large-scale solar energy conversion. Generally thick $TiO_2$ nanoporous films act as efficient photoanodes with their large surface area for absorbing light. However, electron transport through nanoparticle networks causes the slowdown and the loss of electron transport because of a number of interparticle boundaries inside the conduction path. We have studied DSCs with precisely dimension-controlled $TiO_2$ nanotubes array as photoanode. $TiO_2$ nanotubes array is prepared by template-directed fabrication method with atomic layer deposition. Well-ordered nanotubes array provides not only large surface area for light absorbing but also direct pathway for electrons with minimalized grain boundaries. Large enlongated anatase grains in the nanotubes could enhance the conductivity of electrons, but also suppress the recombination with holes through defect sites during diffusion into the electrode. To study the effect of grain boundaries, we fabricated two kinds of nanotubes which have different grain sizes by controlling deposition conditions. And we studied electron conduction through two kinds of nanotubes with different grain structures. The solar cell performance was studied as a function of thickness and grain structures. And overall solar-to-electric energy conversion efficiencies of up to 7% were obtained.

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The Fabrication and Characteristics of Dye-sensitized Solar Cells (DSSCs) Using the Patterned TiO2 Films

  • Choe, Eun-Chang;Seo, Yeong-Ho;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.445.1-445.1
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    • 2014
  • Dye-sensitized solar cells (DSSCs) have been widely investigated as a next-generation solar cell because of their simple structure and low manufacturing cost. The $TiO_2$ film with thickness of $8{\sim}10{\mu}m$, which consists of nanoparticles, acts as both a scaffold with a high surface-to-volume ratio for the dye loading and a pathway to remove the electrons. However, charge carriers have to move across many particle boundaries by a hopping mechanism. So, one dimensional nanostructures such as nanotubes, nanorods and nanowires should improve charge carrier transportation by providing a facile direct electron pathway and lowering the diffusion resistance. However, the efficiencies of DSSCs using one dimensional nanostructures are less than the $TiO_2$ nanoparticle-based DSSCs. In this work, the patterned $TiO_2$ film with thickness of $3{\mu}m$ was deposited using photolithography process to decrease of electron pathway and increase of surface area and transmittance of $TiO_2$ films. Properties of the patterned $TiO_2$ films were investigated by various analysis method such as X-ray diffraction, field emission scanning electron microscopy (FESEM) and UV-visible spectrophotometer.

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Cationization of Cotton with Reactive Diallylamine Polymer (알릴아민계 고분자를 이용한 면직물의 캐티온화 및 그의 항균특성(Ⅰ))

  • Yun, Nam Sik;Gwak, Dong Jin;Son, Yeong A
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.94-94
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    • 2002
  • A number of studies have been introduced on the use of quaternary cationic agents having various reactive groups, which can improve the substantivity of anionic dyes, specially direct dyes, towards cotton. In the case of direct dyes, it is well known that they are widely used due to their convenience to apply and low cost, whilst they display poor levels of fastness properties to washing. Thus many applications using direct dyes in the textile fields have been still enjoyed in the areas where a higher level of wet fastness is specially not required. This work herein comprises that in order to improve the substantivity of direct dyes towards cotton, cellulose-reactive allylamine polymer namely, triazinyl N,N′-dimethyl-N,N′-diallyl ammonium chloride was prepared and treated onto cotton to provide cationic properties within substrates. This application showed that even low concentration of electrolytes being present, the direct dyes were exhausted well on the cationized cotton and that the rate of dye uptake by treated cotton was faster than that of untreated sample. Furthermore the antimicrobial properties were observed from the cationized samples.

Recovery of Sodium Sulfate from Farm Drainage Salt and Using It in Direct Dyeing of Cotton - Analysis of Color Difference -

  • Jiyoon Jung
    • The International Journal of Costume Culture
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    • v.4 no.1
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    • pp.18-24
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    • 2001
  • Agricultural drainage salt generated during irrigation of crops in San Joaquin Valley, California, exceeds 600,000 tons annually and cumulates in the field in a rapid rate. As a result, the waste is taking out more farmlands for salt storage and disposal, imposing serious concerns to environment and local agricultural industry. In searching for a potential solution to reduce or eliminate the waste, this research explored feasibility of producing a value -added product, sodium sulfate, from the waste and utilizing the product in textile dyeing. The results indicated that sodium sulfate could be produced from the salt and could be purified by a recrystalization method in a temperature range within the highest and lowest daily temperatures in summer in the alley. The recovered sodium sulfate samples, with purities ranging from 67% to 99.91, were compared with commercially available sodium sulfate in direct dyeing of cotton fabrics. The salt samples recovered from Mendata, California (〉98.8% sodium sulfate) cause little color difference in the dyeing with selected direct dyes, and the purified salt (Ⅲ) (99.91% sodium sulfate) is more applicable for direct dyeing of cotton fabrics if it has no other toxic effects. The recovered sodium sulfate from certain areas in the valley could not be employed in direct dyeing due to the high level of impurities in it.

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A Study on the Physical Properties and Color of the Mercerized Cotton Dyed by Gardenia (머서화가공면직물(加工綿織物)의 치자염료(梔子染料)에 의한 염색성 연구(染色性 硏究))

  • Choi, Jeong-Im;Kim, Jong-Jun
    • Journal of Fashion Business
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    • v.10 no.5
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    • pp.180-189
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    • 2006
  • Mercerization of cotton fabrics affects their various properties including physical properties and dyeing behavior. In this study, the concentration levels of NaOH solution, with 18% and 25%, and the mercerization temperature levels, $22^{\circ}C,\;10^{\circ}C$, and $5^{\circ}C$, were changed in order to investigate the physical properties and dyeing behavior using Gardenia, a natural dyestuff, and direct dyes. The effect of tension during the mercerization was also investigated. In order to investigate the dyeing behavior of Gardenia, a direct dyestuff was employed as a comparative material for better objective analysis and evaluation. It was found that the mercerization condition of 18% NaOH concentration at $10^{\circ}C$, without tension, resulted in the highest ${\Delta}E$ value, when dyed with Gardenia.

Dyeing Properties and colorfastness of Direct Dyed-Ramie, Flax, and Cotton (모시, 아마, 면의 직접염료 염색에서 염색성과 염색 견뢰도에 대한 연구)

  • 방혜경;최인려
    • Journal of the Korean Society of Costume
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    • v.18
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    • pp.283-289
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    • 1992
  • In this paper, dyeing properties and colorfastness of ramie, flax, and cotton fabrics for direct dyes were compared. When dyed in a same liquor-goods ratio, in case of green dyes, colorfastness to light was similar for three fibers but in case of red dyes, cotton had a lower level. For colorfastness to laundering, there fibers were similar and three were no consistent differences. The degree of stain about white cotton fabric was higher in case of red dyes and it showed the difference of dye's properties. The degree of stain about white wool fabric showed the highs resistance or stain and little stain was seen. This result represented that the dyes. used were proper direct dyes for cellulosic fibers. For the difference of shade, the cotton was consistently brighter and the shade of ramie was darker than that of cotton and flax. This might mean that optical effects arose from the comparatively large cross-sectional size of the ramie fiber and its highly oriented structure.

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Design of Floating Type Wave Energy Convertor with Direct Drive Turbine (파랑을 이용한 부유식 직접 구동 터빈의 설계)

  • Choi, HyenJun;Choi, JongWoong;Kim, ChangGoo;Lee, YoungHo
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.165.2-165.2
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    • 2011
  • Dye to recent development such as increasing price of fossil fuels and energy offers such a solution. Wave energy supplies. Weve energy offers such a solution. Wave energy is the most consistent of all the intermittent renewable energy sources. In addition to this, very large energy fluxes occur in the ocean waves and by using appropriate wave energy converters the energy can be harnessed. The present study looks at utilizing a direct drive turbine of cross flow type to extract energy from ocean waves indirectly. This novel design incorporates a turbine in an enclosed in a closed tank. utilizing the energy generated from sloshing.

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A Versatile Method for DNA Sequencing of Unpurified PCR Products using an Automated DNA Sequencer and Tailed or Nested Primer Labeled with Near-infrared Dye: A Case Study on the Harmful Dinoflagellate Alexandrium

  • Ki Jang-Seu;Han Myung-Soo
    • Fisheries and Aquatic Sciences
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    • v.9 no.2
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    • pp.70-74
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    • 2006
  • DNA sequence-based typing is considered a robust tool for the discrimination of dinoflagellate species because of the availability of extensive rDNA sequences. Here, we present a rapid, cost-effective DNA-sequencing technique for various PCR products. This sequencing strategy relies on 'nested' or 'tailed' primer labeled with near-infrared dye, and uses a minimal volume of unpurified PCR product (ca. $5{\mu}L$) as the DNA template for sequencing reactions. Reliable and accurate base identification was obtained for several hundred PCR fragments of rRNA genes. This quick, inexpensive technique is widely applicable to sequence-based typing in clinical applications, as well as to large-scale DNA sequencing of the same genomic regions from related species for studies of molecular evolution.

Physical Properties and Dyeing Behaviors of Cotton Fabric Treated with Low Temperature Plasma and/or Cellulase (저온플라즈마 및 효소처리한 면의 물성 및 염색성)

  • Yoon, Nam Sik;Lim, Yong Jin
    • Textile Coloration and Finishing
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    • v.8 no.3
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    • pp.59-65
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    • 1996
  • Cotton fabrics were treated by low temperature plasma and/or cellulase, and its physical and dyeing properties were investigated. All the pretreatments of the cotton with low temperature plasma of oxygen, nitrogen and argon slowed down the rate of weight loss of cotton in cellulase solution. Plasma pretreatment did not show any strength retention effect on cotton fiber in the subsequent cellulase treatment. Pretreatment of cotton with low temperature oxygen plasma decreased the rate of dyeing in direct dye bath, while cellulase or plasma/cellulase pretreatment increased the rate. Equilibrium dye uptake of cotton was not changed greatly by the pretreatments except the normal untreated cotton showed more or less high uptake. The pretreatment of cellulase with a water-soluble carbodiimide reduced the enzymatic activity, and did not show any strength retention of cotton in enzymatic weight loss.

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A comparative study of three different viability tests for chemically or thermally inactivated Escherichia coli

  • Park, Seon Yeong;Kim, Chang Gyun
    • Environmental Engineering Research
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    • v.23 no.3
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    • pp.282-287
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    • 2018
  • Three different methods of bacterial viability monitoring were compared to detect chemically or thermally inactivated Escherichia coli. Direct colony enumeration, live/dead bacterial cell staining with a fluorescent dye, and the dehydrogenase activity assay were compared with respect to their ease of use and time required to perform the three different tests. The green (live cell)/red (dead cell) ratio obtained from the fluorescent bacterial cell staining approach showed a linear relationship with the colony forming units; the result obtained with dehydrogenase was similar to those. The sensitivity of the monitoring methods to detect bacterial deactivation varied with different disinfection conditions. After thermal treatment, the sensitivity of the staining approach was lower, while that of the dehydrogenase activity assay was the highest. After chemical treatment, the sensitivity of detection for both methods was similar.