• Title/Summary/Keyword: direct Dye

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A Study on the One Bath Two Step Dyeing of Nylon/ Cationized Cotton Blends with Acid Dye/Direct Dye (나일론/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕 2단 염색에 관한 연구)

  • 성우경
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.44-51
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    • 2000
  • The conventional one bath exhaust dyeing system of nylon]/cotton blends with acid dye/direct dye involves a lot of neutral salt which affect dyeability of acid dyes. Because of conventional one bath exhaust dyeing system of nylonl/cotton blends with acid dye/direct dye needs acid dyes adjusted at a neutral liquor, suitable acid dye is limited. To improve dyeing property of nylon/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of nylon/cationized cotton blends with acid dye/direct dye in a non-neutral salt dyebath by one bath two step method. The concentration of direct dye was 1.0%, 0.7%, 0.3%o.w.f. respectively at a non, 1%, 3%owf of reserving agent for being almost equal color strength between nylon and 3% cationized cotton when nylon/3% cationized cotton blends was dyed with acid dye/direct dye at concentration of acid dye(1%o.w.f.) by one bath two step method.

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Decoloration in Dyebath by Dye Absorption of Chitin(Part I) (키틴의 염료 흡착에 의한 염액의 색소제거에 관한 연구(제1보))

  • 유혜자;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.3
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    • pp.385-392
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    • 2000
  • The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous HCI solution and deproteination in dilute aqueous NaOH solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chitin were measured in varieties of dye concentration and dipping periods. Four kinds of dyestuffs were used, C.I.Acid Blue 29. C.I.Direct Blue 6, C.I.Reactive Orange 12 and C.I.Basic Red 18. When chtin 1g was dipped in 0.05% of dyebath with stirring, maximum adsorption ratio of each kind of dyes was exhibited as 91.6% for C.I.Acid Blue 29, 95% for C.I.Direct Blue 6, 58.2% for C.I.Reactive Orange 13 and 75.8% for C.I.Basic Red 19. It shows that chitin has better adsorption abilities of ionic dyes of acid, direct and basic dye than non-ionic reactive dye. And chitin has better adsorption abilities of anionic acid direct dyes than cationic basic dye because of the presence of nitrogen atoms. All kinds of dyestuffs used showed speedy absorption effects by chitin, so chitin can absorb much amount of dyes in 5 mimutes reach to equilibrium of adsorption in 2 hours after dipping. Basic dye was absorbed the most speedily in 5 minutes, although maximum adsorption ratio is not high. That reason can be thought that chitin surface is essentially negatively charged due to polar funtional groups.

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A Study on the One Bath Two Step Dyeing of Wool/Cationized Cotton Blends With Acid Dye/Direct Dye (양모/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕2단 염색에 관한 연구)

  • Sung, Woo-Kyung;Lee, Choon-Gil
    • Fashion & Textile Research Journal
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    • v.3 no.2
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    • pp.168-173
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    • 2001
  • In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

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Decolorization in Dyebath by Dye Adsorption of Chitin -Effects on the Adsorption in Direct Dyebath- (키틴의 염료 흡착에 의한 염액의 색도제거에 관한 연구 -직접염료의 염액을 중심으로-)

  • 유혜자;김정희;이혜자;이전숙
    • Textile Coloration and Finishing
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    • v.13 no.1
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    • pp.38-44
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    • 2001
  • The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous hydrochloric acid solution and deproteination in dilute aqueous sodium hydroxide solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chtin were measured in varieties of dye concentration and dipping periods. Three kinds of Direct dyes -C.I. Direct Red 81 (red 81), C.I. Direct Brown l(brown 1) and C.I. Direct Green 26(green 26) - were used. Red 81 and brown 1 have smaller molecular weight than green 26. The results from experimentals were of]tamed as follows: 1) Adsorption of green 26 was improved in dyebath by addition of salt, but red 81 and brown 1 were not found any improvements. 2) Smaller size of chitin particles could be absorbed much more speedy. In this experiments, the smallest range of chitin particle size was $250\mu{m}$ and less. 3) The most efficient amount of chitin for 20m1 of dyebath was 0.2g, 4) Both of red 81 and brown 1 showed good and speedy adsorption abilities as dyestuffs of over 90 percent in just one minute in dyebath of 0.01% dye concentration. But green 26 was absorbed slowly because of its large molecular weight. It took 40minutes to absorb dyestuffs of over 90 percent in dyebath of 0.01% dye concentration.

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The Dyeing on the Cotton and Silk fabrics using Dylon hand dyes (Dylon hand dyes를 이용한 면과 견직물의 염색)

  • 이정순
    • Journal of the Korean Home Economics Association
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    • v.30 no.2
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    • pp.45-52
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    • 1992
  • The dyeing characteristics of Dylon hand dyes on the cotton & silk fabric were studied, and the fastnesses of Dylon hand dyes were compared with those of direct & acid dyes. The results are as follows. 1. Dye adsorption of Dylon hand dyes increased as the concentration of dye increased. 2. Dye adsorption was increased as treatment time increased, and reached to eqilibrium after forty minutes treatment. 3. The temperature at mixiumum adsorption was 6$0^{\circ}C$, in the range of lower temperature than 6$0^{\circ}C$ color was changed, in the range of higher temperature adsorption of dye was decreased. 4. Dye adsorption was increased in direct proprotion to NaCl concentration and reached to equilibrium. But NaCl concentration of even and maximum adsorption was 5%. 5. Wash fastness of Dylon hand dyes was better than direct & acid dyes, but light fastness was worse.

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Study for the separation and comparison of azo dyes and their diazo components (아조염료와 디아조 성분의 분리 및 비교에 관한 연구)

  • Jeong, Hyuk
    • Analytical Science and Technology
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    • v.19 no.1
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    • pp.50-57
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    • 2006
  • Well known environmental wastes from dye industry were separated by the micellar electrokinetic capillary chromatography(MECC). These wastes include H-acid modifier and 2-naphthylamine-1,5-disulfonic acid, and are known to be the diazo components of the azo dye. The results of the separation were compared with the result obtained by the HPLC using ion-pairing mechnism. MECC method was also applied to separate a few direct dyes including Direct Blue 2, Direct Blue 6 and Direct Blue 15, and reactive dye such as Reactive Orange 4. Informations about the diazo components of any azo dye could be obtained by comparison of electropherogram of the reduction solution of given dye with those obtained from standard materials such as H-acid, J-acid, ${\gamma}$-acid, orthanilic acid, sulfanilic acid and 2-naphthylamine-1,5-disulfonic acid which are used as diazo components of the typical azo dyes. It has been concluded that MECC and HPLC with ion-pairing mechanism could be successfully applied for the analysis of unknown dyes and their diazo components.

Elimination of COD and Color of Dye by UV/H2O2, UV/TiO2 System (UV/H2O2, UV/TiO2 시스템에서 염료의 색도 및 COD 제거)

  • Kim, Kei-Woul;Park, Joung Mi;Sim, Su-Jin;Yee, Hi-Joung;Rhee, Dong Seok
    • Journal of Industrial Technology
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    • v.20 no.A
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    • pp.51-56
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    • 2000
  • The Photocatalytic decolorization and degradation of commercial dyes were studied using a batch reactor. Degussa P25 titanium dioxide and $H_2O_2$ were used as the photocatalyst and proved to be effective for dyes degradation when they were irradiated with UV light. The light source was a 20W low pressure mercury lamp. Three different kinds of dyes, such as direct dye(congo red), acid dye (acid black) and disperse dye(disperse blue) were tested. Extending the UV only treatment up to 120min, direct dye was decolorized to 60% and degraded to 30% as COD. On the other side, acid and disperse dyes were eliminated less than 10% as color and COD. But, color and COD were eliminated about 90% for all of the three dyes by $UV/H_2O_2$ system. And then the most effective decolorization was done for direct dye with 96% removal efficiency by $UV/TiO_2$ system at 120min with 500mg/L of $TiO_2$.

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Simple Method to Correct Gene-Specific Dye Bias from Partial Dye Swap Information of a DNA Microarray Experiment

  • KIM BYUNG SOO;KANG SOO-JIN;LEE SAET-BYUL;HWANG WON;KIM KUN-SOO
    • Journal of Microbiology and Biotechnology
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    • v.15 no.6
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    • pp.1377-1383
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    • 2005
  • In a cDNA microarray experiment using Cy3 and Cy5 as labeling agents, particularly for the direct design, cDNAs from some genes incorporate one dye more efficiently than the other, which is referred to as the gene-specific dye bias. Dye-swaps, in which two dyes are switched on replicate arrays, are commonly used to control the gene-specific dye bias. We developed a simple procedure to extract the gene-specific dye bias information from a partial dye swap experiment. We detected gene-specific dye bias by identifying outliers in an X-Y plane, where the X axis represents the average log-ratio from two sets of dye swap pairs and the Y axis exhibits the average log ratio of four forward labeled arrays. We used this information for detecting differentially expressed genes, of which the additionally detected genes were validated by real-time RT-PCR.

Dye Penetration into Xylem of Pinus koraiensis and Larix leptolepis by Transpiration Method (증산법에 의한 잣나무와 일본잎갈나무의 목부내 염료침투)

  • 전수경
    • Journal of the Korea Furniture Society
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    • v.12 no.1
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    • pp.1-9
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    • 2001
  • This study was carried out to elucidate the relationship between wood anatomy and the water flow path in P. koraiensis and L. leptolepis. through the experiment of penetration of the dye solution. The experiment was performed by permeating 1% acid, alkali and direct solution into the xylem just after being cut. The results obtained were summarized as follows : 1. In P. koraiensis and L. leptolepis, the dye solution penetrated into sapwood and annual rings adjacent to cambial zone were only dyed according to ascent of tree height. 2. The penetrability of latewood was better than that of earlywood. 3. In P. koraiensis and L. leptolepis, the main water flow path in longitudinal direction was the trachied and that in transverse direction was ray trachied and ray parenchyma. Also, the dye solution was found in resin canal. 4. P. koraiensis was more permeable than L. leptolepis. 5. Among the acid, alkali and direct dye solution, the acid dye solution was the most permeable.

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Dyeing of Cellulose Fabric with C. I. Direct Blue 15 by Redox System (직접 염료 Direct Sky Blue 5B(C. I. Direct Blue 15)의 면에 대한 레독스계에서의 염색)

  • 김광오;김정구;이영희;김경환
    • Textile Coloration and Finishing
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    • v.5 no.3
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    • pp.173-181
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    • 1993
  • Dyeing cotton fabric with direct dye (C. I. Direct Blue 15) by redox sytem of ammonium persulfate as an oxidant and glucose as reductant was studied. It was found that covalent bond between dye and cellulose molecule can be formed by free radical produced by the redox system in the dye bath, which enhanced significantly the color strength. The retained color strength after DMF extraction was much better in the presence than in the absence of the redox sytem. The optimum dyeing condition was 0.028 mol/$\ell$(APS/Glucose each) of redox concentration, 65$^{\circle}C$ of dyeing temperature and 60min of dyeing time. The color variation on the dyed sample had not been observed as a result of fixed ${\lambda}_max$.

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