• Bulletin of the Korean Chemical Society
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• v.5 no.1
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• pp.3-16
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• 1984

The effect of solvent on the dipole moments for (chloromethyl) stannanes has been investigated by applying EHT calculation for the isomers of trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ and $Cl_n$Sn(Ⅳ) $(CH_2Cl)_{4-n}$, octahedral Sn(Ⅳ)$Cl_42X$ and $Cl_nSn$(Ⅳ)$(CH_2Cl)_{4-n}$ 2X type complexes in dioxane and ethylacetate solutions (X: dioxane or ethylacetate). For Sn(Ⅳ)$Cl_4$ in dioxane solution, the calculated dipole moment for the trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ type complex [isomer (b)] is closer to the experimental dipole moment than octahedral Sn(Ⅳ)$Cl_4X$2X type complexes. This calculated dipole moment suggests that Sn(Ⅳ)$Cl_4X$ may have the trigonal bipyramidal structure in dioxane solution. However, the calculated dipole moment for octahedral $Cl_3$Sn(Ⅳ) ($CH_2$Cl)2X type complex [Isomer (d)], ClSn(Ⅳ)(CH2Cl)32X type complex [Isomer(k)] and Cl2Sn(Ⅳ)(CH2Cl)22X type complex [Isomer(h)] are closer to the experimental dipole moments than other isomers for octahedral complexes and trigonal bipyramidal complexes. Such theoretical results indicate that $Cl_3Sn$(Ⅳ )($CH_2Cl$), ClSn(Ⅳ)$(CH_2Cl)_3$ and $Cl2Sn$(Ⅳ)$(CH_2Cl)_2$ complexes may have octahedral structures, Isomer(d), (k) and (h) in ethylacetate solution, respectively.

• Journal of Mechanical Science and Technology
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• v.20 no.10
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• pp.1691-1701
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• 2006

The scan type magnetic camera is proposed to improve the limited spatial resolution due to the size of the packaged magnetic sensor. An image of the scan type magnetic camera, ${\partial}B/{\partial}x$ image, is useful for extracting the crack information of a specimen under a large inclined mag netic field distribution due to the poles of magnetizer. The ${\partial}B/{\partial}x$ images of the cracks of different shapes and sizes are calculated by using the improved dipole model proposed in this paper. The improved dipole model uses small divided dipole models, the rotation and relocation of each dipole model and the principle of superposition. Also for a low carbon steel specimen, the experimental results of nondestructive testing obtained by using multiple cracks are compared with the modeling results to verify the effectiveness of ${\partial}B/{\partial}x$ modeling. The improved dipole model can be used to simulate the LMF and ${\partial}B/{\partial}x$ image of a specimen with complex cracks, and to evaluate the cracks quantitatively using magnetic flux leakage testing.

• Journal of Photoscience
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• v.12 no.2
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• pp.57-61
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• 2005

The ground and excited state dipole moments of Coumarin 450 (C 450) laser dye were measured at room temperature in several solvents of varying dipole moments. The ground state dipole moment (${\mu}_g$) is estimated by using the modified Onsagar model and the excited state dipole moments (${\mu}_e$) were estimated by the method of solvatochromism as well as by utilizing the microscopic solvent polarity parameter ($E^N_T$). Further, the deviation of some of the points from the linearity of the $E^N_T$ versus Stokes shift indicates the existence of specific type of solute-solvent interaction. The excited state dipole moment of C 450 were found to be higher than those of the ground state and is interpreted in terms of the resonance structure of the molecule. A reasonable agreement has been observed between the values obtained by the method of solvatochromism and modified Onsagar model. It is observed that, corresponding to cyclohexane solution, the fluorescence maxima shift towards the red region with increasing the polarity of the solvents, hence the transition involved are of ${\pi}-{\pi}^*$ type.

• Journal of electromagnetic engineering and science
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• v.2 no.1
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• pp.45-49
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• 2002

This paper presents the basic characteristics of a forced resonant type EMI dipole antennas for frequencies below 80 MHz in which two reactance elements are used for the impedance matching at the fined point. The input impedance of the short dipole less than half-wavelength is controlled by the properly determined loading position and the value of loading reactance. The numerical results show that the small-sized EMI dipole antenna with loller antenna factors for frequencies below 80 MHz can be realized by the reactance loading. In case tole proposed center driven forced resonant type EMI dipole antenna with 0.3 λ length is loaded from the center, the input impedance is matched at feed line with 50 $\Omega$, and hence the antenna has lower factors in the frequency range of 30 to 80 MHz.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.64 no.3
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• pp.116-120
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• 2015

In this paper, a step type driver dipole antenna with a tapered balance and unbalance (balun) by a coplanar waveguide (CPW) to coplanar strip (CPS) transition is proposed. The proposed antenna consisted of step type driver, a CPW to CPS transition and tapered balun. The proposed antenna is realized the multi and wide resonate frequency band to introduce the step type driver and tapered balun. The step type driver is acted as a director too. This antenna could be more easily designed than the conventional printed quasi-Yagi dipole antenna. The operating frequency bandwidth was 650 [MHz] (2.65~3.3 GHz), 900 [MHz] (4.7~5.6 GHz) under a return-loss criterion of less than 10 dB. The measurements of the proposed antenna exhibited good results in the wideband operating frequency and radiation pattern. The proposed antenna can support wireless communications applications.

• Bulletin of the Korean Chemical Society
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• v.2 no.3
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• pp.79-82
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• 1981

A calculation method of the dipole moments for square planar and tetrahedral complexes by the valence bond method has been developed and an example calculation was carried out choosing the square planar and tetrahedral $[M(Ⅱ)N_2Se_2]$ type complexes. The calculated values of the dipole moments by the valence bond method are higher than those of the approximate orbital method. We found that we may predict the geometric structure of the transition metal complexes comparing the calculated values of the dipole moments with the experimental values. A new method for definition of C' parameter has also developed on the basis of extended Huckel theory.

• Journal of the Korean Chemical Society
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• v.26 no.5
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• pp.265-273
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• 1982

The effect of ${\pi}$ bonds on the calculated dipole moments for square planar and tetrahedral [M(II)$O_2S_2$]] type complexes has been investigated by two different approaches. One is the approximate molecular orbital method based on the assumption that the mixing coefficient CM of the valence basis sets for the central metal ion and the appropriate ligand orbitals is equal for all ${\sigma}$ and ${\pi}$ bonding molecular orbitals. The other is the more refined calculation based on the semiempirical LCAO-MO method. If ${\sigma}$ bonds only are assumed to be formed, the calculated dipole moments for square planar and tetrahedral complexes are lower than those of the experimental values. If the contribution of ${\pi}$ bonds to the calculated dipole moments are fully considered, the calculated dipole moments for both square planar and tetrahedral [M(II)$O_2S_2$]] type complexes are higher than the experimental values. However if ${\pi}$ bonds are assumed to be delocalzed, the calculated dipole moments for tetrahedral [M(II$O_2S_2$]] type complexes fall in the range of the experimental values, but those for square planar complexes deviate from the experimental values. These results suggest that [M(II)$O_2S_2$]] type complexes may have the tetrahedral structure in inert solvent solution. This structure is in agreement with the experimental one. The calculated dipole moments for tetrahedral [M(II)$O_2S_2$]] type complexes indicate that the contribution of ${\pi}$ bonds to the calculated dipole moments may not be neglected.

• Proceedings of the KSME Conference
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• 2005.11a
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• pp.130.1-130.1
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• 2005

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.15 no.5
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• pp.467-472
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• 2004

This paper presents the normalized site attenuation characteristics for frequencies below 80 ㎒ using forced resonant type EMI dipole antennas. The coupled integral equations for unknown current distribution are solved by the Galerkin's method of moments with piecewise sinusoidal functions. The results show that the forced resonant type EMI dipole antenna for frequencies below 80 ㎒ can be used effectively for the measuring normalized site attenuation. The calculated normalized site attenuation curves for the forced resonant type EMI dipole antenna are useful in determining the suitability of open area test sites.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.25 no.3A
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• pp.435-442
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• 2000

In this paper, we analyzed RF-DC conversion efficiency for the dual -polarization rectenna and the antenna position changing. Dual-Polarization rectenna consist of a two major parts, receiving antenna and rectifying circuits. We made dual-polarization 2.45GHz rectenna using the two dipole antennas and patch antenna. Rectifying circuit is consisted by a Schottky-Barrier diode with a large forward current and reverse breakdown voltage. The results of RF-DC conversion efficiency for the each of designed dual-polarization rectenna has 69.1% with 360$\Omega$(dipole type) and 75.4% with 340$\Omega$(patch type ) optimum load resistor. When the each of dual-polarization rectenna has optimal load resistor, it's conversion efficiency shows of $\pm$20% in dipole type and $\pm$5 in patch type at 0~180。position.