• Journal of Photoscience
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• 제12권3호
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• pp.119-122
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• 2005

The photophysical properties of coumarin 6 laser dye have been studied in two solvents; ethanol and acetonitrile using steady-state fluorescence depolarization technique. The experimentally measured reorientation time of coumarin 6 is more or less the same in given solvents at particular temperature. It is found that coumarin 6 rotates slower in acetonitrile than in ethanol especially at higher values of viscosity over temperature. We also measure the ground and excited state dipole moments of coumarin 6 by solvent perturbation method. The results found that excited state dipole moment is greater than ground state dipole moment, which indicates that excited state is more polar than the ground state.

• 한국자기학회지
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• 제18권2호
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• pp.54-57
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• 2008

Magnetic torquer하는 인공위성의 초기 자세제어에 사용 되는 부품으로 지구자기장하에서 자기 쌍극자 모멘트가 받는 비틀림력을 이용하여 인공위성의 회전을 방지하고 특정 방향으로 인공위성의 자세가 안정되게 한다. 본 연구에서 개발 한 magnetic torque는 소형위성에 사용되는 것으로, magnetic torque거 자기적 특성뿐만 아니라 위성 발사 시 및 인공위성 궤도에서의 환경에서도 그 특성이 보장될 수 있게 환경시험을 하였다. 개발한 magnetic torquer는 포화 자기 쌍극자 모멘트가 $15Am^2$, 선형도 특성을 보이는 구간이 ${\pm}12Am^2$이고 선형도가 0.3% 미만이면서 질량이 0.46 kg이고 소비전력이 자기 쌍극자 모멘트가 $10Am^2$에 1 Watt 이였다.

• Bulletin of the Korean Chemical Society
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• 제6권1호
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• pp.3-7
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• 1985

The general formulas for SCF atomic orbitals |5s > and |6p > have been derived separately by expressing the spherical harmonics part in terms of the coordinate($r_1,\;$r_2$) of the reference point, and by translating the exponential part, $r^4\;exp\;(-{\beta}r)$), in terms of $r_1,\;and\;r_2$ and the modified Bessel functions. Master formulas for overlap and dipole moment matrix elements are derived. The computed values of overlap and dipole moment matrix elements for hypothetical NO molecule are exactly in agreement with those for the previous methods.

• 한국전자파학회논문지
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• 제14권11호
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• pp.1207-1215
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• 2003

본 논문에서는 대수주기 다이폴 안테나(LPDA: Log-Periodic Dipole Antennas)의 크기를 줄이기 위해 다이폴 소자를 벤트 다이폴 소자로 대체한 대수주기 벤트 다이폴 안테나(LPBDA: Log-Periodic Bent Dipole Antennas)를 제안하였다. 1 ㎓∼3 ㎓ 사이에서 동작하는 LPBDA를 설계하고 모멘트법을 이용하여 복사특성을 해석하여 LPDA의 특성과 비교 검토하였다. 그 결과 본 논문에서 제시한 LPBDA는 다이폴 소자의 길이를 약 20% 줄이면서도 복사특성이 LPDA와 비교하여 거의 차이가 없는 것으로 나타났으며, 제작 측정한 LPBDA의 특성도 계산 결과에 근접했다.

• 대한화장품학회지
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• 제40권4호
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• pp.383-390
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• 2014

기질 분자로서 2-[(2,6-dioxocyclohexyl)methyl]cyclohexane-1,3-dione 유도체(1-23)들의 분자 내 치환기($R_1$ 및 $R_2$)가 변화함에 따른 tyrosinase 수용체의 저해활성에 관한 2D-QSAR 모델로부터 다음과 같은 결론을 얻었다. 유도된 최적의 2D-QSAR 모델은 $Obs.pI_{50}=-0.295({\pm}0.031)TDM$ $-0.120({\pm}0.014)DMZ+0.135({\pm}0.050)DMX$. $R_2+6.382({\pm}0.17)$이었으며, 예측성($q^2=0.843$)보다는 상관성($r^2=0.905$)이 큰 모델이었다. Tyrosinase 저해활성은 TDM > $DMX.R_2{\geq}DMZ$ 순으로 영향을 미치었으며, 기질분자의 소수성(ClogP > 0)이 크고, $R_1$-치환기의 입체적 크기가 클수록 더욱 증가하는 경향을 나타내었다. 모델을 분석한 결과, 분자 내 $R_2$-치환기 상 X-축 성분의 쌍극자능률($DMX.R_2$)이 클수록, 그리고 분자 전체의 쌍극자능률(TDM; Total Dipole Moment)과 Z-성분의 쌍극자능률(DMZ; Dipole Moment of Z-Component)이 작을수록 기질분자의 tyrosinase 저해활성이 높아짐을 암시하였다. 따라서 tyrosinase 저해활성은 기질분자 및 $R_2$-치환기의 전자 친화력에 기인한 것으로 예상되었다. 그러므로 저해활성을 증가시키려면 분자 내 극성 그룹을 소수성에 기여하는 비극성 작용기로 대체함이 바람직할 것으로 예측되었다.

• Bulletin of the Korean Chemical Society
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• 제8권3호
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• pp.174-179
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• 1987

The results of an ab initio (6-31G) molecular orbital calculations of the dipole moment derivatives and gas phase IR intensities in $CH_3F$ and $CF_4$ are reported. The results are compared with corresponding values obtained from a CNDO calculation. We have also analyzed the theoretical polar tensors into the charge, charge flux, and overlap contributions. The effective term charges of hydrogen atom appeared to be transferable among the fluoromethane molecules.

• 자연과학논문집
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• 제17권1호
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• pp.31-37
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• 2006

We have found that the polarization mode coupling between the orthogonally linearly polarized dual mode laser results from the anisotropy of dipole moments. Rate equation analysis demonstrated that high anisotropy in dipole moment components can give rise to law intrinsic mode coupling constants while isotropic dipole moment components give high intrinsic mode coupling constant. The populations at active ion sites are shown to self-organize the populations such that laser mode gain is constant adove threshold while the gain contributions from the each site adjust themselves with pump power.

• 대한전기학회논문지:전력기술부문A
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• 제54권1호
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• pp.31-37
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• 2005

With biological effects by ELF(Extremely Low Frequency) magnetic field generated from power system, the transient magnetic field from electric appliances is a major issue presently. In this paper, we measured magnetic field distributions around electric appliances in view of harmonics and analyzed them by the use of an equivalent magnetic dipole moment method. This method was applied to 19 types of appliances, and their equivalent magnetic dipole moments and harmonic components were determined. The results show that this method is applicable to many appliances and the higher frequency magnetic field may induce higher current inside living bodies.

• 한국전기전자재료학회논문지
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• 제27권12호
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• pp.847-851
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• 2014

The characteristics of dielectric constant and $tan{\delta}$ of low viscosity silicone oils with changing degree of polymerization were investigated. The result shows dipole loss mechanism at low temperature range. The dielectric loss in the range of low frequencies are predominantly of ionic nature with temperature increase. The peak of dielectric loss is the detrapping of the electrons which is were trapped in the localized level of the silicone oils at the frequency of 30 kHz. The increase of ionic conduction is attributed to the presence of ionizable oxidation products and their increased dissociation feature. The activation energy ${\Delta}H$ and dipole moment ${\mu}_d$ were increased whit increasing degree of polymerization.

• Bulletin of the Korean Chemical Society
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• 제7권4호
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• pp.299-304
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• 1986

Master formulas for overlap integrals and the dipole moments involving |4p > atomic orbitals have been derived by the expansion method for spherical harmonics. The radial integrals for the hyperfine interaction have also been derived for |4p > atomic orbitals. The calculated values of the overlap integrals and dipole moment matrix elements by the expansion method for spherical harmonics for a hypothetical NO molecule are exactly in agreement with those of Mulliken's method. The radial integrals for the hyperfine interaction may be used to calculate the chemical shift for |4p > atomic orbitals.