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Effect of KOH Concentrations and Pyrolysis Temperatures for Enhancing NH4-N Adsorption Capacity of Rice Hull Activated Biochar (KOH 농도 및 탄화온도가 왕겨 활성 바이오차의 NH4-N 흡착능 향상에 미치는 영향)

  • Kim, HuiSeon;Yun, Seok-In;An, NanHee;Shin, JoungDu
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.171-177
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    • 2020
  • BACKGROUND: Recently, biomass conversion from agricultural wastes to carbon-rich materials such as biochar has been recognized as a promising option to maintain or increase soil productivity, reduce nutrient losses, and mitigate greenhouse gas emissions from the agro-ecosystem. This experiment was conducted to select an optimum conditions for enhancing the NH4-N adsorption capacity of rice hull activated biochar. METHODS AND RESULTS: For deciding the proper molarity of KOH for enhancing its porosity, biochars treated with different molarity of KOH (0, 1, 2, 4, 6, 8) were carbonized at 600℃ in the reactor. The maximum adsorption capacity was 1.464 mg g-1, and an optimum molarity was selected to be 6 M KOH. For the effect of adsorption capacity to different carbonized temperatures, 6 M KOH-treated biochar was carbonized at 600℃ and 800℃ under the pyrolysis system. The result has shown that the maximum adsorption capacity was 1.76 mg g-1 in the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis temperature, while its non-treated biochar was 1.17 mg g-1. The adsorption rate in the rice hull activated biochar treated with 6 M KOH at 600℃ was increased at 62.18% compared to that of the control. Adsorption of NH4-N in the rice hull activated biochar was well suited for the Langmuir model because it was observed that dimensionless constant (RL) was 0.97 and 0.66 at 600℃ and 800℃ of pyrolysis temperatures, respectively. The maximum adsorption amount (qm) and the bond strength constants (b) were 0.092 mg g-1 and 0.001 mg L-1, respectively, for the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis. CONCLUSION: Optimum condition of rice hull activated biochar was 6M KOH at 600℃ of pyrolysis temperature.

Derivation of the Synthetic Unit Hydrograph at Ungaged Small Watershed (미계측 소하천수계의 합성단위도 유도)

  • 안상진;이억한
    • Water for future
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    • v.19 no.2
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    • pp.157-166
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    • 1986
  • The objective of this study was to determine the best representative synthetic unit hydrograph that is applicable to ungaged small watershed. A typical unit hydrograph was established with the actual data from a small watershed. Four currently well-known methods for analyzing ungaged small watershed, including Snyder's, Clark's S.C.S. and Nash methods, were evaluated with the data from the same small watershed. The following observations were noted from the analysis of four methods. The Snyder's method yielded the similar peak discharge value as the typical unit hydrograph. With co-ordinates of three discharge values, i.e. 25%, 50% and 75% of peak discharge, were not adequate for deriving a typical unit hydrograph in ungaged small watershed. With Clark's method there shall be some way of obtaining the exact base length of time area diagram and isochrone of each reach of the stream. With Nash method peak discharge and base flow time are affected by the storage constant and gamma function argument; therefore, for deriving a more reliable and workable unit hydrograph one needs to select for the better estimation of storage constant and gamma function argument. In S.C.S. method peak discharge is directly related to the watershed area and inversely related to the time of peak diacharge. Therefore area with faster peak discharge yielded the higer peak discharge value. Although the peak discharge value obtained frome the S.C.S. method higher than the value obtained from the unit hydrograph developed from the actual data, this method contains a number of advantageous factors. The peak discharge value and the time of peak discharge can be claculated easity from the morphological characteristics of the watershed, and in S.C.S method co-ordinates of the unit hydrograph can be calculated easily from that of the dimensionless unit hydrograph. When the four currently used methods were evaluated with a typical unit hydrograph obtained from the actual data, the S.C.S method was show to be the best method in deriving a synthetic unit hydrograph for ungaged small watershed.

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Effective Method for Analysis of Heterogeneous Porous Media (비균질 다공성 매질의 효율적 해석 방법)

  • Park, Chang-Geun
    • Journal of Korea Water Resources Association
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    • v.31 no.4
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    • pp.459-467
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    • 1998
  • The existing methods to analyze the heterogeneous porous media based on the similar media concept are the microscopic Miller similitude(MiS), the macroscopic Miller similitude(MaS) and the Warrick similitude(WS). The inter-relationship is found such that MiS ⊂ MaS ⊂ (⊂:subset). The proposed method is based ont eh assumption that the scale variables $\alpha$=w and the moisture content is dimensionless by introducing the effective degree of saturation instead of the degree of saturation into WS. The method, without the loss of generality in view of the inspectional analysis, can explain the heterogeneity of the media by using the scale variable $\alpha$ only. The media of $\alpha$=1 (average of $\alpha$) means the equivalent media corresponding to the heterogeneous media, while the standard deviation of $\alpha$ may explain the degree of the heterogeneity of the media under consideration. The hydraulic conductivity of the media with $\alpha$>1 is greater than that of the equivalent media, and the effective moisture content of the media with $\alpha$>1 is also greater. Based on these properties of the scale variable $\alpha$, the ideal vertical one-dimensional heterogeneous porous media is generated by using the technique of random number generation.

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Unsteady 2-D flow field characteristics for perforated plates with a splitter

  • Yaragal, Subhash C.
    • Wind and Structures
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    • v.7 no.5
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    • pp.317-332
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    • 2004
  • Wind tunnel experiments were conducted under highly turbulent and disturbed flow conditions over a solid/perforated plate with a long splitter plate in its plane of symmetry. The effect of varied level of perforation of the normal plate on fluctuating velocities and fluctuating pressures measured across and along the separation bubble was studied. The different perforation levels of the normal plate; that is 0%, 10%, 20%, 30%, 40% and 50% are studied. The Reynolds number based on step height was varied from $4{\times}10^3$ to $1.2{\times}10^4$. The shape and size of the bubble vary with different perforation level of the normal plate that is to say the bubble is reduced both in height and length up to 30% perforation level. For higher perforation of the normal plate, bubble is completely swept out. The peak turbulence value occurs around 0.7 to 0.8 times the reattachment length. The turbulence intensity values are highest for the case of solid normal plate (bleed air is absent) and are lowest for the case of 50% perforation of the normal plate (bleed air is maximum in the present study). From the analysis of data it is observed that $\sqrt{\overline{u^{{\prime}2}}}/(\sqrt{\overline{u^{{\prime}2}}})_{max}$, (the ratio of RMS velocity fluctuation to maximum RMS velocity fluctuation), is uniquely related with dimensionless distance y/Y', (the ratio of distance normal to splitter plate to the distance where RMS velocity fluctuation is half its maximum value) for all the perforated normal plates. It is interesting to note that for 50% perforation of the normal plate, the RMS pressure fluctuation in the flow field gets reduced to around 60% as compared to that for solid normal plate. Analysis of the results show that the ratio [$C^{\prime}_p$ max/$-C_{pb}(1-{\eta})$], where $C^{\prime}_p$ max is the maximum coefficient of fluctuating pressure, $C_{pb}$ is the coefficient of base pressure and ${\eta}$ is the perforation level (ratio of open to total area), for surface RMS pressure fluctuation levels seems to be constant and has value of about 0.22. Similar analysis show that the ratio $[C^{\prime}_p$ max/$-C_{pb}(1-{\eta})]$ for flow field RMS pressure fluctuation levels seems to be constant and has a value of about 0.32.

A Study on Heat Transfer According to Inclined Angle and Surface Performance Using Turbulent Impingement Jet with a Liquid Crystal Transient Method (형상 및 경사 각도에 따른 난류 충돌 제트에 의한 과도 액정 기법을 이용한 열전달 특성에 대한 연구)

  • Lim, Kyoung-Bin;Lee, Chang-Hee;Lee, Sang-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.12 s.255
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    • pp.1164-1172
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    • 2006
  • Measurements of the local heat transfer coefficients on hemispherical convex and concave surfaces with a turbulent impinging jet were made. The Reynolds number used was 11000, 23000, 50000 and the nozzle- to- surface distance was L/d=2, 4, 6, 8, and 10 and the jet angle was a = $0^{\circ}$, $15^{\circ}$, $30^{\circ}$ and $40^{\circ}$. In case of concave surface, the Nusselt number at the stagnation point decreases as the jet angle increases and has the maximum value for L/d=6. The X-axis Nusselt number distributions exhibit secondary maxima at $0^{\circ}$ $\leq$ a $\leq$ $15^{\circ}$, L/d $\leq$ 4 for X/d<0(upstream) and at $0^{\circ}$ $\leq$ a $\leq$ $40^{\circ}$, L/d $\leq$ 4 and at $30^{\circ}$ $\leq$ a $\leq$ $40^{\circ}$, 4 < L/d $\leq$ 6 for X/d<0(downstream). The secondary maximum occurs at long distance from the stagnation point as the jet angle increases or the nozzle-to-surface distance decreases. In case of convex, correlations of the stagnation point Nusselt number according to Reynolds number, jet-to-surface distance ratio and dimensionless surface angle are presented. In the stagnation point, in term of Ren, n ranges from 0.43 in case of 2 $\leq$ L/d $\leq$ 6 to 0.45 in case of 6 < L/d $\leq$ 10, there agrees roughly appears to be laminar boundary layer result. The maximum Nusselt number, in this experiment, occurred in the direction of upstream. The displacement of the maximum Nusselt number from the stagnation point increases with increasing surface angle or decreasing nozzle-to-surface distance. On this condition about surface curvature D/d=10, the maximum displacement is about 0.7 times of the jet nozzle diameter. The ratio of the maximum Nusselt number to the stagnation Nusselt number increases as the jet angle increases.

Analysis of Whole Grains Extrusion by Response Surface Methodology (반응표면분석법에 의한 전곡립의 압출성형공정 분석)

  • Shin, Hae-Hun;Park, Bo-Sun;Lee, Hye-Lim;Choi, Moon-Jung;Hwang, Jae-Kwan
    • Korean Journal of Food Science and Technology
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    • v.33 no.6
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    • pp.686-692
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    • 2001
  • The effects of extrusion on solubilization of brown rice, glutinuous rice, barley and job's tear were analyzed by response surface methodology (RSM). Solubilization of whole grains by extrusion was characterized in terms of water solubility index (WSI), concentration of water soluble polysaccharides (C) and intrinsic viscosity $([\eta])$. Considering both concentration and intrinsic viscosity, a dimensionless target parameter $([\eta])$ was also included for analysing the extrusion effects on cereal extrusion. Response surface methodology analysis showed that the moisture content was the most significant contributor among screw speed, temperature and moisture content affecting the solubilizing phenomena of cereals processed with extrusion. Brown rice was not showed the significant relationship on $([\eta])$ because $([\eta])$ was more affected by intrinsic viscosity. The critical point of whole grains extrusion except brown rice was corresponded to screw speed of 300 rpm, moisture content of 20% and temperature of $120^{\circ}C$.

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A Numerical Study on Characteristics of Solute Transport in a Rough Single Fracture with Spatial Correlation Length and Effect of Effective Normal Stress (공간적 상관길이와 유효수직응력의 효과에 따른 거친 단일 균열내의 용질이동특성에 관한 수치적 연구)

  • Jeong, Woochang
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.1
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    • pp.5-14
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    • 2009
  • This study is to analyze numerically the spatial behaviors of the solute transport in a spatially correlated variable-aperture fracture under the effective normal stress conditions. Numerical results show that the solute transport in a fracture is strongly affected by the spatial correlation length of apertures and applied effective normal stress. According to increasing spatial correlation length, the mean residence time of solute is decreased and the tortuosity and Peclet number (is a dimensionless number relating the rate of advection of a flow to its rate of diffusion) is also decreased. These results mean that the geometry of the aperture distribution is favorable to the solute transport as the spatial correlation length is increased. However, according to the applied effective normal stress is increased, the mean residence time and tortuosity have a tendency to increase but the Peclet number is decreased. The main reason that the Peclet number is decreased, is that the solute is displaced by one or two channels with relatively higher local flow rate due to the increment of contact areas by increasing effective normal stress. Moreover, based on numerical results of the solute transport in this study, the exponential-type correlation formulae between the mean residence time and the effective normal stress are proposed.

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HALO SPIN PARAMETER IN COSMOLOGICAL SIMULATIONS

  • Ahn, Jieun;Kim, Juhan;Shin, Jihye;Kim, Sungsoo S.;Choi, Yun-Young
    • Journal of The Korean Astronomical Society
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    • v.47 no.2
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    • pp.77-86
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    • 2014
  • Using a cosmological ${\Lambda}CDM$ simulation, we analyze the differences between the widely-used spin parameters suggested by Peebles and Bullock. The dimensionless spin parameter ${\lambda}$ proposed by Peebles is theoretically well-justified but includes an annoying term, the potential energy, which cannot be directly obtained from observations and is computationally expensive to calculate in numerical simulations. The Bullock's spin parameter ${\lambda}^{\prime}$ avoids this problem assuming the isothermal density profile of a virialized halo in the Newtonian potential model. However, we find that there exists a substantial discrepancy between ${\lambda}$ and ${\lambda}^{\prime}$ depending on the adopted potential model (Newtonian or Plummer) to calculate the halo total energy and that their redshift evolutions differ to each other significantly. Therefore, we introduce a new spin parameter, ${\lambda}^{\prime\prime}$, which is simply designed to roughly recover the value of ${\lambda}$ but to use the same halo quantities as used in ${\lambda}^{\prime}$. If the Plummer potential is adopted, the ${\lambda}^{\prime\prime}$ is related to the Bullock's definition as ${\lambda}^{\prime\prime}=0.80{\times}(1+z)^{-1/12}{\lambda}^{\prime}$. Hence, the new spin parameter ${\lambda}^{\prime\prime}$ distribution becomes consistent with a log-normal distribution frequently seen for the ${\lambda}^{\prime}$ while its mean value is much closer to that of ${\lambda}$. On the other hand, in case of the Newtonian potential model, we obtain the relation of ${\lambda}^{\prime\prime}=(1+z)^{-1/8}{\lambda}^{\prime}$; there is no significant difference at z = 0 as found by others but ${\lambda}^{\prime}$ becomes more overestimated than ${\lambda}$ or ${\lambda}^{\prime\prime}$ at higher redshifts. We also investigate the dependence of halo spin parameters on halo mass and redshift. We clearly show that although the ${\lambda}^{\prime}$ for small-mass halos with $M_h$ < $2{\times}10^{12}M_{\odot}$ seems redshift independent after z = 1, all the spin parameters explored, on the whole, show a stronger correlation with the increasing halo mass at higher redshifts.

Effects of Liquid Surface Tension on the Heat Transfer Coefficient in a Three-Phase Slurry Bubble Column (삼상슬러리 기포탑에서 액상의 표면장력이 열전달 계수에 미치는 영향)

  • Lim, Ho;Lim, Dae Ho;Jin, Hae-Ryong;Kang, Yong;Jung, Heon
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.499-504
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    • 2012
  • Characteristics of overall heat transfer were investigated in a three-phase slurry bubble column with relatively low surface tension media, which has been frequently encountered in the fields of industry. The heat transfer phenomena was examined in the system which was composed of a coaxial vertical heater and a proper of bubble column. The heat transfer coefficient was estimated from the measured mean value of temperature difference between the heater surface and the column proper at the steady state condition. Effects of gas velocity ($U_G$), solid fraction in the slurry phase ($C_S$) and surface tension (${\sigma}_L$) of continuous liquid media on the overall heat transfer coefficient (h) in the bubble column were determined. The mean value of temperature difference was estimated from the data of temperature difference fluctuations with a variation of time. The amplitude and mean value of temperature difference fluctuations with respect to the elasped time appeared to decrease with decreasing the surface tension of liquid phase. The overall heat transfer coefficient between the immersed heated and the bubble column increased with an increase in the gas velocity or solid fraction in the slurry phase, but it decreased with an increase in the surface tension of continuous liquid media. The overall heat coefficient in the slurry bubble column with relatively low surface tension media was well correlated in term of operating variables and dimensionless groups within this experimental conditions.

Characteristics of Heat Transfer in Three-Phase Swirling Fluidized Beds (삼상 Swirling 유동층에서 열전달 특성)

  • Son, Sung-Mo;Shin, Ik-Sang;Kang, Yong;Cho, Yong-Jun;Yang, Hee-Chun
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.56-62
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    • 2008
  • Characteristics of heat transfer were investigated in a three-phase swirling fluidized bed whose diameter was 0.102 m and 2.5 m in height. Effects of gas and liquid velocities, particle size and liquid swirling ratio ($R_S$) on the immersed heater-to-bed overall heat transfer coefficient were examined. The heat transfer characteristics between the immersed heater and the bed was well analyzed by means of phase space portraits and Kolmogorov entropy(K) of the time series of temperature difference fluctuations. The phase space portraits of temperature difference fluctuations became stable and periodic and the value of Kolmogorov entropy tended to decrease with increasing the value of liquid swirling ratio from 0.1 to 0.4. The value of Kolmogorov entropy exhibited its minimum with increasing liquid swirling ratio. The value of overall heat transfer coefficient (h) showed its maximum with the variation of liquid velocity, bed porosity or liquid swirling ratio, but it increased with increasing gas velocity and particle size. The value of K exhibited its maximum at the liquid velocity at which the h value attained its maximum. The overall heat transfer coefficient and Kolmogorov entropy were well correlated in terms of dimensionless groups and operating variables.