• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2021-2025
• /
• 2007

Performance of single cell at solid oxide fuel cell (SOFC) system is largely affected by electrocatalytic and thermal properties of cathode. Samarium-based perovskite oxide material is recently recognized as promising cathode material for intermediate temperature-operating SOFC due to its high electrocatalytic property. Perovskite structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ and its composite material, $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/Sm_{0.2}Ce_{0.8}O_{1.9}$ were investigated in terms of area specific resistance (ASR), thermal expansion coefficient (TEC), thermal cycling and long term performance. $Sm_{0.2}Ce_{0.8}O_{1.9}$ was used as electrolyte material. Electrochemical ac impedance spectroscopy (EIS) and dilatometer were used to measure the cathodic properties. Composite cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$: $Sm_{0.2}Ce_{0.8}O_{1.9}$ = 6:4) showed a good ASR of 0.13${\Omega}$ $cm^2$ at 650$^{\circ}C$ and its TEC value was 12.3${\times}$10-6/K at 600$^{\circ}C$ which is similar to the value of ceria-based electrolyte of 11.9${\times}$10-6/K. Performance of composite cathode was maintained with no degradation even after 13 times thermal cycle test.

• Journal of the Korean Geotechnical Society
• /
• v.23 no.1
• /
• pp.67-76
• /
• 2007

Flat DMT penetration was analyzed using a finite element model based on a large strain formulation. The ABAQUS/Explicit, a commercial finite element method, was used to study the flat DMT penetration in soils. Then, because the very large mesh distortion occurred due to the penetration of flat DMT, the adaptive meshing technique was utilized to maintain a high quality mesh configuration. The undrained shear strength obtained from the flat DMT is estimated using only the horizontal stress index ($K_{D}$) and so it became necessary to examine using the analysis results obtained from the penetration of the flat DMT. Analysis results show that in normally consolidated region of $K_{D}=2$, the results obtained from the correlations proposed by Marchetti show good agreement with those estimated from the finite element method. The present analysis also shows that in overconsolidated region of $K_{D}>2$, the results obtained from the relationships proposed by Kamei and Iwasaki show good agreement with those provided by the penetration analysis.

• Journal of the Korean Geotechnical Society
• /
• v.25 no.6
• /
• pp.5-16
• /
• 2009

The is study is to evaluate the small strain shear modulus ($G_{max}$) of Busan clay using in-situ penetration tests. A series of dilatometer tests (DMT) and piezocone penetration tests (CPTu) are performed at Busan newport and Noksan sites, and hybrid oedometer tests are also carried out on the specimens obtained from both sites. The $G_{max}$ is evaluated from the shear wave velocity ($V_s$) measured by the bender elements installed at the boundary of oedometer cell. By analyzing these data, the relationship of $G_{max}$ and state variables, such as confined stress and void ratio, is developed. The analysis of lab and in-situ test results reveals that the ratio of $G_{max}$ to $q_t$ is inversely proportional to the plasticity index while the ratio of $G_{max}$ to $E_D$ has a linear relationship with ($I/I_D$)$(p_a/{\sigma}'_v)^{0.5}$. Two correlations suggested in this study, based on CPT and DMT results, appear to provide reasonable predictions of the small strain shear modulus.