• 대한화학회지
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• 제37권9호
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• pp.806-812
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• 1993

Cu(I)(${\beta}$-diketonate) 착화합물로서 $Cu(I)(hfac)PR_3$(P는 phosphine, R은 Me, Et, Bu를 나타낸다) 착물들을 비수용매에서 유리질 탄소전극과 탄소 microelectrode를 사용하여 이들 착물들의 전기화학적 성질을 조사하였다. 아세토니트릴 용액에서 순환 전압-전류법에 의한 $Cu(I)(hfac)PR_3$ 착물들의 환원과정은 최종생성물이 Cu(0)로 가는 1전자 반응으로 진행되었다. 탄소 microelectrode를 이용한 대시간-전류법에 의해서 이들 착물들이 1전자 반응으로 진행됨을 확인하였으며, 확산계수는 $4.5{\sim}6.7{\times} 10^{-6}cm^2$/sec값으로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1480-1484
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• 2012

We report a series of novel imidazolium iodides based ionic liquids (NMIPHI, NAIPHI, and NBIPHI) with different functional groups for the development of a quasi-solid type electrolyte for dye-sensitized solar cells (DSSCs). The diffusion coefficients of redox ions ($I^-$ and $I_3{^-}$) are dependent on the molecular weight and it was higher for lighter salts. Among the three ionic liquids, NMIPHI showed highest efficiency of 4.18% when it was used in a liquid electrolyte of a DSSC with $ca$. 6 ${\mu}m$ thick $TiO_2$ mesoporous film. Even though the efficiency was $ca$. 19% lower than that obtained from a liquid electrolyte composed of PMII. When NMIPHI was mixed with PMII with a molar ratio of 1:1 in a solvent free electrolyte, the efficiency of the DSSCs was enhanced compared to that based on pristine PMII.

• 한국응용과학기술학회지
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• 제28권1호
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• pp.102-108
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• 2011

The study of wave propagation and scattering in biological media has become increasingly important in recent years. The propagation of light within tissues is an important problem that confronts the dosimetry of therapeutic laser delivery and the development of diagnostic spectroscopy. In the clinical application of photodynamic therapy(PDT) and in photobiology, the photon deposition within a tissue determines the spatial distribution of photochemical reactions. Scattered light is measured as a function of the distance (r) between the axis of the incident beam and the detection spot. Consequently, knowledge of the photosensitizer(Chlorophyll-a) function that characterizes a phantom is measured. To obtain the results of scattering coefficients(${\mu}s$) of a turbid material from diffusion described by experimental approach. It was measured the energy fluency of photon radiation at the position of penetration depth. From fluorescence experimental method obtained the analytical expression for the scattered light as the values of $(I/I_o)_{wavelength}$ vs the distance between the center of the incident beam and optical fiber in terms of the condition of "in situ spectroscopy(optically thick)" and real time by fluorometric measurements. The result was compromised with transport of intensities though a random distribution of scatters.

• 한국환경과학회지
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• 제11권1호
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• pp.75-83
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• 2002

The removal performance of copper ion was studied using Na-P1 zeolites synthesized from Jeju scoria. The scoria which is found in large amounts in Jeju Island, was sampled at four regions, Jeju-shi Bonggae-dong(A). Pukcheju-gun Hanlim-eup Sangmyong-ri Mangoreum(B), Pukcheju-gun Hanlim-eup Keumag-ri(C) and Namcheju-gun Andeok-myun Dongkwang-ri(D). Synthetic Na-P1 zeolites used in this study were more effective than natural zeolite and scoria for the removal of copper ion. The removal performances of copper ion decreased in the order of Na-P1(D) > Na-P1(C) > Na-P1(B) > Na-P1(A) among Na-P1 synthesized from the scoria according to region. These results showed the same trend with cation exchange capacity(CEC) for each synthetic zeolite, i.e., the synthetic Na-P1 zeolite with a higher CEC showed a higher removal performance. The effective diffusion coefficients of copper ion by synthetic Na-P1 zeolites were one hundred and ten times higher than those by a pure zeolite 4A and the zeolite A synthesized from coal fly ash, respectively.

• 조명전기설비학회논문지
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• 제18권1호
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• pp.9-14
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• 2004

본 논문에서는 내부 입자의 반경방향 분포와 구동회로를 고려한 형광램프 모델링을 수행하였다. 모델링에서 전자에너지 분포는 Maxwellian으로 가정하였으며, 전자 이동도와 유극성 확산계수는 상수를 사용하였다. 방전 중 수은원자는 6가지 에너지레벨을 갖는다고 가정하였다. 모델을 사용하여 4개의 편미분 2개의 상미분 연립방정식을 FDM과 2계 Runge-Kutta 방법을 사용하여 수치적으로 해를 구하였다. 개발한 모델을 실제 형광램프와 LR안정기 회로에 적용하여 실험적으로 측정한 전압, 전류 파형과 수치해석적으로 구한 전압, 전류 파형을 비교하여, 본 형광램프 모델링의 타당성을 보였다.

• Applied Biological Chemistry
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• 제31권1호
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• pp.21-25
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• 1988

쌀보리(무안보리, 송학, 새쌀보리 및 늘쌀보리)의 주된 입자(7mesh)를 도정수율 65%로 도정하고 $40^{\circ}C$에서의 수분 흡수 속도 및 침지 중 경도의 변화를 조사하였다. 쌀보리쌀은 침지 시간 7시간에 평형 수분 함량에 도달하였으며, 확산계수 값은 쌀보리에 비하여 $3{\sim}4$배 높았다. 쌀보리쌀의 침지 중 부피 증가량은 수분 증가량과 직선적인 관계를 보였으며, 쌀보리쌀의 부피 증가 속도 상수 값은 쌀보리에 비하여 약 2.2배 높았다. 쌀보리쌀의 침지 중 경도 변화는 대수적으로 감소하였으며 감소속도 상수 값은 송학이 가장 컸으며 무안보리쌀이 가장 작았다.

• 한국응용과학기술학회지
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• 제22권2호
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• pp.182-190
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• 2005

The propagation of light radiation within tissues is an important problem that confronts the dosimetry of therapeutic laser delivery and the development of diagnostic spectroscopy. In the clinical application of photodynamic therapy(PDT) and in photobiology, the photon deposition within a tissue determines the spatial distribution of photochemical reactions. Scattered light is measured as a function of the distance (r) between the axis of the incident beam and the detection spot. Consequently, knowledge of the photosensitizer(Chlorophyll-a) function that characterizes a phantom is important. To obtain the results of scattering coefficients(${\mu}s$) of a turbid material from diffusion described by experimental approach. It was measured the energy fluency of photon radiation at the position of penetration depth. From fluorescence experimental method obtained the analytical expression for the scattered light as the values of $(I\;/I_o)_{wavelength}$ vs the distance between the center of the incident beam and optical fiber in terms of the condition of "in situ spectroscopy(optically thick)" and real time by fluorometric measurements.

• 한국수산과학회지
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• 제25권5호
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• pp.359-370
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• 1992

To investigate the flow pattern and mixing process in Suyoung Bay, field observations and data analyses of tidal current, salinity and suspended sediment (SS) were carried out. Ebb flow is stronger than flood flow, and duration of ebb tide is longer than that of flood tide. Semi-diurnal component of tidal current is predominant, and current rotating clockwise occurs in the central part of the bay. The direction of the residual currents in the central part of the bay and offshore is almost N to WNW, and the speed is 4-14cm/s. Eulerian diffusion coefficients estimated from the current data have the range of $6.2\times10^4-4.2\times10^6\;cm^2/s,$ Salinity structure in Suyoung River estuary during flood tide is of partially mixed type, but is of stratified type during ebb tide. Salinity fluctuation is large at the surface, and the fluctuation decreases with depth. SS concentration in Suyoung River estuary has a higher value during ebb tide than that during flood tide. Salinity and 55 concentrations in the estuary appeared to be very sensitive to the change of river flow.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.58-59
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• 2006

Less than a decade ago, most alternate membrane materials for fuel cells relied upon a post-sulfonation process to generate ionic groups capable of transporting protons from the anode to the cathode. These random post sulfonations showed some promise, but in general they produced materials that were not sufficiently stable or protonically conductive at ion exchange capacities where aqueous swelling could be restricted. Our group began to synthesize disulfonated monomers that could be used to incorporate into random copolymer proton exchange membranes. The expected limitation was that the aromatic polymers might not be stable enough to withstand fuel cell conditions. However, this was mostly based upon an accelerated test known was the Fenton's Reagent Test, which did not seem to this author as being a reliable predictor of performance. A much better approach has been to evaluate the open circuit voltage (OCV) for alternate membranes, as well as the benchmark perfluorosulfonic acid systems. When this is done, the aromatic ionomers of this study, primarily based upon disulfonated polyarylene ether sulfones, show up quite well. Real time 3000 hours DMFC results have also been generated. Obtaining conductive materials at low humidities is another major issue where alternate membranes have not been particularly successful. In order to address this problem, multiblock copolymers with relatively high water diffusion coefficients have been designed, which show promise for conductivity at lowered humidity.

• 멤브레인
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• 제9권3호
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• pp.141-150
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• 1999

비다공성막을 통한 기체 투광성분의 투과 transient와 투과 조성을 on-line 방식으로 측정할 수 있는 기체 투과장치를 개발하였다. 측정은 연속흐름방식으로 이루어지며 측정한 투과 transien로부터 여러 가지의 투과특성, 즉, 투과계수, 확산계수, 용해계수 등을 동시에 평가할 수 있다. 잘 알려진 유리상 고분자인 두 가지 폴리이드막과 고무상의 고분자인 실리콘막을 선택하여 여러 가지의 기체투과 특성들을 측정하여 문헌치와 비교함으로써 투과장치 및 측정방법에 대한 신뢰성, 정확성을 확인하였다. 또한 측정한 투과 transient를 분석함으로써 막을 통한 기체 투과거동을 좀더 자세하게 다양하게 분석할 수가 있다.