• 한국안전학회지
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• 제19권3호
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• pp.89-94
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• 2004

Most reinforcements in concrete are constructed by steel. Corrosion of reinforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly professed by the chloride ingress. In general, chloride in concrete can be discriminated by two components, total chloride and fire chloride. This paper provides a testing method on the coefficient of chloride diffusion in concrete and the relationship between total chloride and free chloride in concrete for the composition of predicting model on diffusion rate of chloride. In order to complete this predicting model, this study will use chloride penetration characteristic, diffusion coefficient and experiment of color change on silver nitrate solution. This predicting model is going to help that grasp special quality on salt content inclusion of concrete structure that is exposed in chloride environment. Accurate predicting model can be effectively used not only in selecting of repair time but also in preventing from various deteriorations.

• Computers and Concrete
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• 제34권2호
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• pp.169-178
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• 2024

To circumvent the constraints of time-consuming experimental methods, numerical simulation can be one of the most effective approaches to investigating chloride diffusion behaviors in concrete. However, except for the effect of the external environments, the transport direction of the chloride cannot be neglected when the concrete is exposed to the marine tidal zone, especially in certain areas of concrete members. In this study, based on Fick's second law, considering the effects of timevarying, chloride binding capacity, concrete stress state, ambient temperature, and relative humidity on chloride diffusion coefficient, the modified one-dimensional, two-dimensional, and three-dimensional novel modified chloride diffusion theoretical models were established through defining the current boundary conditions. The simulated results based on the novel modified multi-dimensional model were compared with the experimental results obtained from some previous pieces of literature. The comparing results showed that the modified multi-dimensional model was well-fitted with experimental data, confirming the high accuracy of the novel modified model. The experimental results in literature showed that the chloride diffusion in the corner area of the concrete structure cannot be simulated by a simple one-dimensional diffusion model, where it is necessary to select a suitable multi-dimensional chloride diffusion model for simulation calculation. Therefore, the novel modified multi-dimensional model established in this study has a stronger applicability for practical engineering.

• 한국대기환경학회지
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• 제26권1호
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• pp.77-84
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• 2010

The diffusion and partition coefficients of polyurethane foam (PUF) are estimated using a microbalance experiment and small chamber test. The microbalance is used to measure sorption/desorption kinetics and equilibrium data. When the diffusion condition is controlled in the chamber of the sample, interactions between volatile organic compounds (VOCs) and PUF can lead to the estimation of a relatively homogenous rate of mass transfer in the interiors and surfaces of PUF. The estimates of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) are shown to be independent of the concentrations of VOCs. This approach, if applied to a diffusion-controlled or physically-based model, can facilitate more precise prediction of their source/sink behavior. Although further research and more rigorous validation is needed, an emission model applied with the diffusion and partition coefficients from this research holds promise for the improvement of reliability in predicting the behavior of VOCs emitted from porous building materials by D and K.

• 경영과학
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• 제22권1호
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• pp.179-197
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• 2005

This study examines market acceptance for DMB service, one of the touted new business models in Korea's next-generation mobile communications service market, using adoption end diffusion of innovation as the theoretical framework. Market acceptance for DMB service was assessed by predicting the demand for the service using the Bass model, and the demand variability over time was then analyzed by integrating the innovation adoption model proposed by Rogers (2003). In our estimation of the Bass model, we derived the coefficient of innovation and coefficient of imitation, using actual diffusion data from the mobile telephone service market. The maximum number of subscribers was estimated based on the result of a survey on satellite DMB service. Furthermore, to test the difference in diffusion pattern between mobile phone service and satellite DMB service, we reorganized the demand data along the diffusion timeline according to Rogers' innovation adoption model, using the responses by survey subjects concerning their respective projected time of adoption. The comparison of the two demand prediction models revealed that diffusion for both took place forming a classical S-curve. Concerning variability in demand for DMB service, our findings, much in agreement with Rogers' view, indicated that demand was highly variable over time and depending on the adopter group. In distinguishing adopters into different groups by time of adoption of innovation, we found that income and lifestyle (opinion leadership, novelty seeking tendency and independent decision-making) were variables with measurable impact. Among the managerial variables, price of reception device, contents type, subscription fees were the variables resulting in statistically significant differences. This study, as an attempt to measure the market acceptance for satellite DMB service, a leading next-generation mobile communications service product, stands out from related studies in that it estimates the nature and level of acceptance for specific customer categories, using theories of innovation adoption and diffusion and based on the result of a survey conducted through one-to-one interviews. The authors of this paper believe that the theoretical framework elaborated in this study and its findings can be fruitfully reused in future attempts to predict demand for new mobile communications service products.

• 설비공학논문집
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• 제26권8호
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• pp.366-374
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• 2014

Experimental mass transfer data, which were obtained for the $CO_2$-water slug flows in vertical tubes with 2, 5, and 8mm diameters, were analyzed in comparison with the penetration theory. It was found that a penetration model with molecular diffusion coefficient cannot predict the experimental data accurately. An effective diffusion coefficient, which considers enhancement effect of interfacial waves, was suggested to improve prediction. Another empirical factor was also suggested to consider the effect of non-uniform interface velocity. A modified penetration model was found to be capable of predicting the experimental data reasonably well.

• Advances in concrete construction
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• 제8권1호
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• pp.55-64
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• 2019

Chloride corrosion has become the main factor of reducing the service life of reinforced concrete structures. The object of this paper is to propose a theoretical model that predicts the service life of chloride-corrosive concrete under fatigue load. In the process of modeling, the concrete is divided into two parts, microcrack and matrix. Taking the variation of mcirocrack area caused by fatigue load into account, an equation of chloride diffusion coefficient under fatigue load is established, and then the predictive model is developed based on Fick's second law. This model has an analytic solution and is reasonable in comparison to previous studies. Finally, some factors (chloride diffusion coefficient, surface chloride concentration and fatigue parameter) are analyzed to further investigate this model. The results indicate: the time to pit-to-crack transition and time to crack growth should not be neglected when predicting service life of concrete in strong corrosive condition; the type of fatigue loads also has a great impact on lifetime of concrete. In generally, this model is convenient to predict service life of chloride-corrosive concrete with different water to cement ratio, under different corrosive condition and under different types of fatigue load.

• 한국구조물진단유지관리공학회 논문집
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• 제28권5호
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• pp.20-29
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• 2024

염화물 확산계수는 해양환경에 위치한 콘크리트 교량의 내구성 평가를 위한 중요한 지표 중 하나이다. 본 논문에서는 기존 연구에서 고려하지 않았던 해양 노출 환경(대기중, 비말대, 간만대)과 공용 중인 콘크리트 교량의 데이터를 활용해 염화물 확산계수 예측 모델을 개발하였다. 이를 위해 교량 하부구조에서 취득한 염화물 프로파일 데이터를 활용하였고 데이터 전처리 후 기계학습 모델인 RF, GBM, KNN을 하이퍼파라미터 튜닝을 통해 최적화 하였다. 콘크리트 물성치를 포함한 6개 변수(W/B, 시멘트 종류, 굵은골재 부피 비율, 공용연수, 강도, 노출 환경) 모델과 노출 환경을 고려하지 않은 5개 변수 모델, 정밀안전진단에서 취득 가능한 3개 변수(공용연수, 강도, 노출 환경) 모델을 개발하여 성능을 비교·검토 하였다. 그 결과 해양 환경에 위치한 콘크리트 교량의 경우 노출 환경을 고려함에 따라 염화물 확산계수 예측 모델의 성능을 향상시킬 수 있음을 확인하였으며, 또한 정밀안전진단 데이터만으로도 염화물 확산계수를 효과적으로 예측할 수 있음을 확인하였다.

• 산업식품공학
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• 제14권4호
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• pp.354-358
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• 2010

The methods for determining the diffusion parameters for the diffusion of d-limonene, a major volatile compound of orange juice, through a multi-layered food packaging material and predicting its absorption into the packaging material have been investigated. The packaging material used was the 1.5-mm thick multi-layered packaging material composed of high impact polystyrene (HIPS), polyvinylidene chloride (PVDC), and low density polyethylene (LDPE). Orange juice was placed in a cell where volatiles were absorbed in the sample package and kept at $23{\pm}2^{\circ}C$ for 72 hr. The d-limonene absorbed in a 1.5-mm thick multi-layered food packaging material was analyzed by a solid phase micro-extraction (SPME). The absorption parameters for the absorption of d-limonene in the packaging material were determined and absorption of d-limonene into the packaging material was predicted using absorption storage data. The SPME desorption at $60^{\circ}C$ for 1 hr resulted in the most sensitive and reproducible results. The diffusion coefficients of d-limonene in the packaging material and the partition coefficient at $23{\pm}2^{\circ}C$ were approximately $1-2{\times}10^{12}m^2$/s and 0.03, respectively. The absorption profile no earlier than 30 hr was fit well by a model derived from the Fick's law.

• Journal of the Korean Wood Science and Technology
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• 제17권3호
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• pp.67-81
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• 1989

This experiment was carried out to know the mothod of changing the step of moisture content schedule with time in conventional kiln drying. For the purpose of this object. we made drying model by applying the moisture diffusion model by J.FSiau(1984) to average moisture content equation by J.Crank(1956) derived it from Fick's second law. And to verify this method of drying model. 2.5cm-thick boards and 5.0cm-thick dimension lumbers of Pinus densiflora were kiln-dried with the schedule of T11-C3 and T10-C4, respectively. And then the drying rates were investigated and compared with those calculated from drying model. The results obtained were as follows 1. Average drying rate and total drying time of board to dry to 6.5% moisture content were 0.64%/hr and 109hr., and those of dimension lumber to dry to 8.3% moisture content were 0.4%/hr. and 162hr., respectively. 2. The moisture content of shell and core decreased by equalizing treatment and increased by conditioning treatment both on board and dimension lumber. But the moisture gradient was lower after conditioning than after equalizing. 3. As the drying was proceeded, the transverse bound water diffusion coefficient all but linearly decreased, the water vapor diffusion coefficient abruptly curvilinearly increased, while the transverse diffusion coefficient curvilinearly decreased both on board and dimension lumber. But each of diffusion coefficients on board was larger than that on dimension lumber. 4. Compared to experimential drying rate of board. theoretical drying rate was larger at 30.0%-21.8% moisture content range and was similiar at 21.8%-5.4% moisture content. And in case of dimension lumber, the drying rate was similiar at 30.0%-16.1% moisture content range but theoretical drying rate was much lower at 16.1%-8.3% moisture content range. 5. The possibility of adapting this drying model to changing the moisture content schedule step with time was in the range of 21.8%-5.4% moisture content on board. And in the case of dimension lumber that was in the range of 30.0%-16.1% moisture content.

• 한국구조물진단유지관리공학회 논문집
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• 제8권3호
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• pp.169-176
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• 2004

황산염에 의한 원전 콘크리트 구조물의 침식을 예측하기 위하여 경과시간에 따른 팽창응력, 확산계수 등을 종합적으로 고려할 수 있는 Mechanistic 모델을 적용하였다. 적용배합은 원전 구조물 건설에 사용되었던 설계기준강도 385, 280 및 $210kgf/cm^2$의 3종으로 하였으며, 1종과 5종 포틀랜드시멘트를 시용하였다. 또한 시멘트 종류 및 설계기준강도별 로 1년간 10% 황산나트륨 용액에서 침지실험을 실시하여 각 배합별 확산계수 및 압축강도를 구하였으며, 그 결과를 예측모델식에 사용하여 원전 콘크리트 구조물의 황산염 침식을 예측하였다. 대상 배합의 황산염 확산계수는 $0.5763{\sim}3.9002{\times}10^{-12}m^2/sec.$였으며, 원전 콘크리트 구조물의 황산염 침식속도는 0.1~7.1 mm/year로 예측되었다.